(1R,3R,6R,8R)-1,2,3,4,5,5a,6,7-octahydro-2,2,7,7-tetramethyl-1,3:6,8-dimethano-1H-fluorene | 1016607-62-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (1R,3R,6R,8R)-1,2,3,4,5,5a,6,7-octahydro-2,2,7,7-tetramethyl-1,3:6,8-dimethano-1H-fluorene
• 英文别名: (1R,5R,7R,12R)-6,6,13,13-tetramethylpentacyclo[10.1.1.15,7.02,10.04,9]pentadeca-2,4(9)-diene
• CAS: 1016607-62-7
• 化学式: C₁₉H₂₆
• 分子量: 254.415
• InChiKey: RSCXQQNQLKIDHL-FIVOFWMMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  盐酸 、 (1R,3R,6R,8R)-1,2,3,4,5,5a,6,7-octahydro-2,2,7,7-tetramethyl-1,3:6,8-dimethano-1H-fluorene 、 十二羰基三钌 在 O₂ 作用下， 以 乙醚 、 癸烷 、 氯仿 为溶剂， 以33%的产率得到(1R,3R,6R,8R)-1,2,3,4,5,5a,6,7-octahydro-2,2,7,7-tetramethyl-1,3:6,8-dimethano-1H-fluorenyl dicarbonyl ruthenium(II) chloride
  参考文献：
  名称：

  Synthesis of chiral highly hindered cyclopentadienylruthenium compounds

  摘要：

  Optically active highly hindered half-sandwich ruthenium(II) compounds with C(2)-symmetric cyclopentadienyl ligands were synthesized from the ligand precursors, 4 and 5, which were derived from (-)-beta-pinene. Thus, the reaction of the ligands with triruthenium dodecacarbonyl produced ruthenium compounds, 10 and 11, after oxidative treatment. These compounds were characterized by single crystal X-ray crystallography. (c) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.12.005
• 作为产物：
  描述：

  bis[(1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methanol 在 硫酸 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以60%的产率得到(1R,3R,6R,8R)-1,2,3,4,5,5a,6,7-octahydro-2,2,7,7-tetramethyl-1,3:6,8-dimethano-1H-fluorene
  参考文献：
  名称：

  Synthesis of chiral highly hindered cyclopentadienylruthenium compounds

  摘要：

  Optically active highly hindered half-sandwich ruthenium(II) compounds with C(2)-symmetric cyclopentadienyl ligands were synthesized from the ligand precursors, 4 and 5, which were derived from (-)-beta-pinene. Thus, the reaction of the ligands with triruthenium dodecacarbonyl produced ruthenium compounds, 10 and 11, after oxidative treatment. These compounds were characterized by single crystal X-ray crystallography. (c) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.12.005

文献信息

• Synthesis of chiral highly hindered cyclopentadienylruthenium compounds
  作者：Byung Soo Kang、Dae Sung Lim、Woo Sung Ahn、Ho-jae Lee、Jahyo Kang

  DOI：10.1016/j.jorganchem.2007.12.005

  日期：2008.2

  Optically active highly hindered half-sandwich ruthenium(II) compounds with C(2)-symmetric cyclopentadienyl ligands were synthesized from the ligand precursors, 4 and 5, which were derived from (-)-beta-pinene. Thus, the reaction of the ligands with triruthenium dodecacarbonyl produced ruthenium compounds, 10 and 11, after oxidative treatment. These compounds were characterized by single crystal X-ray crystallography. (c) 2007 Elsevier B. V. All rights reserved.