25,27-bis(2-bromoethoxy)-26,28-dihydroxy-5,11,17,23-tetra(tert-butyl)calixarene | 197228-58-3
中文名称
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中文别名
——
英文名称
25,27-bis(2-bromoethoxy)-26,28-dihydroxy-5,11,17,23-tetra(tert-butyl)calixarene
英文别名
32,72-Bis(2-bromoethoxy)-15,35,55,75-tetra-tert-butyl-1,3,5,7(1,3)-tetrabenzenacyclooctaphane-12,52-diol；26,28-bis(2-bromoethoxy)-5,11,17,23-tetratert-butylpentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-25,27-diol
CAS
197228-58-3
化学式
C48H62Br2O4
mdl
——
分子量
862.826
InChiKey
VSBHTLRRWGSVDO-UHFFFAOYSA-N
BEILSTEIN
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EINECS
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物化性质
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计算性质
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ADMET
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安全信息
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SDS
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制备方法与用途
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上下游信息
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文献信息
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表征谱图
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同类化合物
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相关功能分类
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相关结构分类
计算性质
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辛醇/水分配系数(LogP)：15.1
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重原子数：54
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可旋转键数：10
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环数：5.0
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sp3杂化的碳原子比例：0.5
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拓扑面积：58.9
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氢给体数：2
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氢受体数：4
上下游信息
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上游原料
中文名称 英文名称 CAS号 化学式 分子量 —— 5,11,17,23-tetra-t-butyl-25,26,27,28-tetrahydroxycalix-4-arene 288302-12-5 C44H56O4 648.926 -
下游产品
中文名称 英文名称 CAS号 化学式 分子量 —— 15,35,55,75-tetra-tert-butyl-32,72-bis(2-((2-hydroxyethyl)amino)ethoxy)-1,3,5,7(1,3)-tetrabenzenacyclooctaphane-12,52-diol 1245824-09-2 C52H74N2O6 823.169 —— p-t-butyl-25,27-bis-O-(2-bromoethoxy)-26,28-bis-O-benzyloxycalix[4]arene 1417341-09-3 C62H74Br2O4 1043.08 —— 5,11,17,23-tetra-tert-butyl-25,27-bis[(β-naphthoyl)ethoxy]-26,28-dihydroxycalix[4]arene —— C68H76O6 989.348 —— 25,27-dihydroxy-26,28-bis(2'-phenylthiaethoxy)-5,11,17,23-tetra-tert-butylcalix[4]arene —— C60H72O4S2 921.361 —— 22,28,34,39-Tetratert-butyl-43,44-dihydroxy-6,15-bis(2-hydroxyethyl)-3,18-dioxa-6,9,12,15-tetrazahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1,19,21,23,26(44),27,29,32,34,37,39,41(43)-dodecaene-8,13-dione 1251829-62-5 C58H82N4O8 963.311 —— 5,11,17,23-Tetratert-butyl-26,28-bis(2-diethoxyphosphorylethoxy)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-25,27-diol 460728-37-4 C56H82O10P2 977.209 —— 5,11,17,23-Tetratert-butyl-26,28-bis[2-(pyridin-2-ylmethylamino)ethoxy]pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-25,27-diol 1314475-39-2 C60H76N4O4 917.288 —— 24,30,36,41-Tetratert-butyl-45,46-dihydroxy-6,17-bis(2-hydroxyethyl)-3,20-dioxa-6,8,15,17-tetrazahexacyclo[20.15.7.128,32.139,43.02,34.021,26]hexatetraconta-1,21,23,25,28(46),29,31,34,36,39,41,43(45)-dodecaene-7,16-dione 1251829-60-3 C60H86N4O8 991.365 —— 2,6-[4',4"-(5,11,17,23-tetra-tert-butyl-25,27-dihydroxycalix[4]arene-26,28-diyl)-di(oxy)-2',2"-di(oxa)]dibutylpyridine —— C55H69NO6 840.156 —— 1,2-[3',3"-(5,11,17,23-tetra-tert-butyl-25,27-dihydroxycalix[4]arene-26,28-diyl)-di(oxy)-1'-(aza)-1"-(oza)]dipropylbenzene —— C54H67NO5 810.13 —— 25,27-dihydroxy-26,28-bis(2'-(2'',5''-dichlorophenylthia)ethoxy)-5,11,17,23-tetra-tert-butylcalix[4]arene —— C60H68Cl4O4S2 1059.14 —— 1,1'-(((15,35,55,75-tetra-tert-butyl-32,72-dihydroxy-1,3,5,7(1,3)-tetrabenzenacyclooctaphane-12,52-diyl)bis(oxy))bis(ethane-2,1-diyl))bis(1-(2-hydroxyethyl)-3-phenylthiourea) 1251829-58-9 C66H84N4O6S2 1093.55 —— 19,25,31,36-Tetratert-butyl-40,41-dihydroxy-3,15-dioxa-6,8,10,12-tetrathiaheptacyclo[15.15.7.123,27.134,38.02,29.07,11.016,21]hentetraconta-1,7(11),16,18,20,23(41),24,26,29,31,34,36,38(40)-tridecaene-9-thione 863915-93-9 C51H62O4S5 899.381 —— 8,8'-[2",2'''-(5,11,17,23-tetra-tert-butyl-25,27-dihydroxycalix[4]arene-26,28-diyl)di(oxy)]diethoxy-diquinoline —— C66H74N2O6 991.323 —— 19,25,31,36-Tetratert-butyl-40,41-dihydroxy-3,15-dioxa-6,8,10,12-tetrathiaheptacyclo[15.15.7.123,27.134,38.02,29.07,11.016,21]hentetraconta-1,7(11),16,18,20,23(41),24,26,29,31,34,36,38(40)-tridecaen-9-one 197228-57-2 C51H62O5S4 883.314 —— N-benzyl-5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-(4'R,8'R-diphenyl-6'-aza-3',9'-dioxaundecane)-dioxycalix[4]arene 1148038-08-7 C71H85NO6 1048.46 —— 25,27-bis[(1-((R)-phenyl{[(1'R)-1'-phenylethyl]amino}-methyl)naphthalen-2-yloxy)ethoxy]-26,28-dihydroxy-5,11,17,23-tetra(tert-butyl)calix[4]arene 1266715-25-6 C98H106N2O6 1407.93 —— 25,27-bis[(1-((R)-(α-pyrrolidinylbenzyl))naphthalen-2-yloxy)ethoxy]-26,28-dihydroxy-5,11,17,23-tetra(tert-butyl)calix[4]arene 1266715-33-6 C90H102N2O6 1307.81 —— 25,27-bis[(1-((R)-phenyl{methyl[(1'R)-1'-phenylethyl]amino}-methyl)naphthalen-2-yloxy)ethoxy]-26,28-dihydroxy-5,11,17,23-tetra(tert-butyl)calix[4]arene 1266715-28-9 C100H110N2O6 1435.98 - 1
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反应信息
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作为反应物：描述：25,27-bis(2-bromoethoxy)-26,28-dihydroxy-5,11,17,23-tetra(tert-butyl)calixarene 在 sodium azide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 5.0h， 以85%的产率得到26,28-Bis(2-azidoethoxy)-5,11,17,23-tetratert-butylpentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-25,27-diol参考文献：名称：