(E)-3-(3,5-ditert-butylphenyl)-1-(2-methoxyphenyl)prop-2-en-1-one | 1421789-50-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: (E)-3-(3,5-ditert-butylphenyl)-1-(2-methoxyphenyl)prop-2-en-1-one
• CAS: 1421789-50-5
• 化学式: C₂₄H₃₀O₂
• 分子量: 350.501
• InChiKey: RNLLIYSHLLONFZ-OUKQBFOZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (E)-3-(3,5-ditert-butylphenyl)-1-(2-methoxyphenyl)prop-2-en-1-one 在 ammonium acetate 、 吡啶盐酸盐 作用下， 以 甲醇 、 melt 、 氯仿 、 溶剂黄146 为溶剂， 反应 48.0h， 生成
  参考文献：
  名称：

  具有四齿O ^ N ^ C ^ N配体的坚固的磷光铂（II）配合物：具有出色效率稳定性的高效OLED。

  摘要：

  具有四齿O 2 N 2 C 3 N配体的Pt（II）配合物（1-3）显示出高发射量子产率（0.76-0.90）和良好的热稳定性（T（d）＞ 400℃）。配合物是一种用于OLED的出色绿色磷光掺杂剂，具有出色的效率和低效率的衰减（eta（L），eta（Ext）（max）= 66.7 cd A（-1），18.2％; eta（L），eta（ Ext）（1000 cd m（-2））= 65.1 cd A（-1），17.7％）。

  DOI：

  10.1039/c2cc37862k
• 作为产物：
  描述：

  2'-甲氧基苯乙酮 、 3,5-双(叔丁基)苯甲醛 在 potassium hydroxide 作用下， 以 甲醇 为溶剂， 反应 24.0h， 以88%的产率得到(E)-3-(3,5-ditert-butylphenyl)-1-(2-methoxyphenyl)prop-2-en-1-one
  参考文献：
  名称：

  具有四齿O ^ N ^ C ^ N配体的坚固的磷光铂（II）配合物：具有出色效率稳定性的高效OLED。

  摘要：

  具有四齿O 2 N 2 C 3 N配体的Pt（II）配合物（1-3）显示出高发射量子产率（0.76-0.90）和良好的热稳定性（T（d）＞ 400℃）。配合物是一种用于OLED的出色绿色磷光掺杂剂，具有出色的效率和低效率的衰减（eta（L），eta（Ext）（max）= 66.7 cd A（-1），18.2％; eta（L），eta（ Ext）（1000 cd m（-2））= 65.1 cd A（-1），17.7％）。

  DOI：

  10.1039/c2cc37862k

文献信息

• [EN] PLATINUM(II) COMPLEXES FOR OLED APPLICATIONS<br/>[FR] COMPLEXES DE PLATINE (II) POUR APPLICATIONS OLED
  申请人：UNIV HONG KONG

  公开号：WO2013152727A1

  公开（公告）日：2013-10-17

  The current invention relates to novel platinum(II) based organometallic materials. These materials show high emission quantum efficiencies and low self-quenching constant. Also provided are high efficiency, green to orange emitting organic light-emitting diode (OLED) that are fabricated using platinum(II) based organometallic materials as the light-emitting material. The organometallic materials of the invention are soluble in common solvents; therefore, solution process methods such as spin coating and printing can be used for device fabrication. The devices fabricated from these materials show low efficiency roll-off.

  当前的发明涉及新型的基于铂(II)的有机金属材料。这些材料显示出高发射量子效率和低自猝灭常数。此外，还提供了高效率、绿色至橙色发光的有机发光二极管(OLED)，这些OLED是使用基于铂(II)的有机金属材料作为发光材料制备而成的。该发明的有机金属材料可溶于常见溶剂；因此，可以使用旋涂和印刷等溶液法工艺用于器件制备。使用这些材料制备的器件显示出低效率衰减。
• Platinum(II) complexes for OLED applications
  申请人：Versitech Limited

  公开号：US10008681B2

  公开（公告）日：2018-06-26

  The current invention relates to novel platinum(II) based organometallic materials. These materials show high emission quantum efficiencies and low self-quenching constant. Also provided are high efficiency, green to orange emitting organic light-emitting diode (OLED) that are fabricated using platinum(II) based organometallic materials as the light-emitting material. The organometallic materials of the invention are soluble in common solvents; therefore, solution process methods such as spin coating and printing can be used for device fabrication. The devices fabricated from these materials show low efficiency roll-off.

  本发明涉及新型铂（II）基有机金属材料。这些材料显示出较高的发射量子效率和较低的自淬火常数。本发明还提供了使用铂（II）基有机金属材料作为发光材料制造的高效率、绿色至橙色发光的有机发光二极管（OLED）。本发明的有机金属材料可溶于普通溶剂，因此可采用旋涂和印刷等溶液工艺方法制造器件。用这些材料制造的器件显示出较低的效率滚降。
• PLATINUM(II) COMPLEXES FOR OLED APPLICATIONS
  申请人：THE UNIVERSITY OF HONG KONG

  公开号：US20130274473A1

  公开（公告）日：2013-10-17

  The current invention relates to novel platinum(II) based organometallic materials. These materials show high emission quantum efficiencies and low self-quenching constant. Also provided are high efficiency, green to orange emitting organic light-emitting diode (OLED) that are fabricated using platinum(II) based organometallic materials as the light-emitting material. The organometallic materials of the invention are soluble in common solvents; therefore, solution process methods such as spin coating and printing can be used for device fabrication. The devices fabricated from these materials show low efficiency roll-off.
• ORGANIC LIGHT-EMITTING MATERIAL BASED ON A PLATINUM TETRADENTATE ONCN COMPLEX, PREPARATION METHOD AND APPLICATION THEREOF IN ORGANIC LIGHT-EMITTING DIODES
  申请人：GUANGDONG AGLAIA OPTOELECTRONIC MATERIALS CO., LTD

  公开号：US20210332290A1

  公开（公告）日：2021-10-28

  The present invention relates to an organic light-emitting material based on a platinum tetradentate ONCN complex, a preparation method and application thereof in organic light-emitting diodes, A platinum (II) tetradentate ONCN complex light-emitting material having the chemical structure of Formula I can be used for manufacturing organic light emitting diodes with pure greenemission. The material has been optimized in structure and has better anti-aggregation ability compared with the reported platinum (II) tetradentate ONCN complex light-emitting material. The emission spectrum of the material only slightly changes or even remains unchanged at high doping concentration, so the organic light-emitting diode made of this material obviously has higher emission efficiency. The preparation method for the complex light-emitting material is simple and does not require the use of highly toxic and harmful reagents, and is more suitable for industrial preparation systems.
• US9306178B2
  申请人：——

  公开号：US9306178B2

  公开（公告）日：2016-04-05