6-chloro-p-mentha-1,8-diene | 71305-95-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 6-chloro-p-mentha-1,8-diene
• 英文别名: 6-Chlor-p-mentha-1,8-dien；2-Chlor-Δ^1,6Δ^8,9-menthadien；6-Chlor-p-mentha-1,8-dien；Carvylchlorid；6-Chloro-1-methyl-4-prop-1-en-2-ylcyclohexene
• CAS: 71305-95-8；71305-98-1；83867-60-1；98975-99-6；30808-80-1
• 化学式: C₁₀H₁₅Cl
• 分子量: 170.682
• InChiKey: GRROGOVISQZGNO-UHFFFAOYSA-N

物化性质

• 沸点：
  57-58 °C(Press: 0.35 Torr)
• 密度：
  1.009 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  6-chloro-p-mentha-1,8-diene 在 xylene 作用下， 生成 5-isopropenyl-2-methyl-cyclohex-2-enecarboxylic acid
  参考文献：
  名称：

  Local and landscape-level influences on wetland bird communities of the prairie pothole region of Iowa, USA

  摘要：

  Bird species richness and individual species densities were measured in wetland complexes in 1998. These values were then related to habitat variables within the complexes and to area of wetland habitat in the surrounding landscape. The percentage of wetland area within a complex that was covered with emergent vegetation and the total area of wetland habitat in the 3 km surrounding each complex were significant predictors of species richness. A perimeter-to-area ratio was the most frequently selected variable for inclusion in species-density models, being selected for 8 of 15 models. Five species' densities were related to the percentage of the wetland area that was covered by emergent vegetation, and 4 densities were related to the area covered by weak-stemmed wet-meadow vegetation. Densities of 5 species, as well as the overall species richness, were associated with a measure of the amount of wetland habitat within a 3-km buffer surrounding the wetland complexes. This indicates that the presence and abundance of some wetland bird species may be influenced by the amount of wetland habitat nearby. Thus, programs that encourage restoration of tracts of land that contain multiple wetland basins should be emphasized to maximize benefits to the wetland bird community.

  DOI：

  10.1672/0277-5212(2001)021[0041:lallio]2.0.co;2
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 aluminum isopropoxide 、 异丙醇 作用下， 生成 6-chloro-p-mentha-1,8-diene
  参考文献：
  名称：

  Dupont; Kergomard, Bulletin de la Societe Chimique de France, 1951, p. 561

  摘要：

  DOI：

文献信息

• Copper(II) catalyzed allylic amination of terpenic chlorides in water
  作者：Brahim Boualy、Mohamed Anouar Harrad、Soufiane El Houssame、Larbi El Firdoussi、Mustapha Ait Ali、Abdallah Karim

  DOI：10.1016/j.catcom.2011.12.019

  日期：2012.3

  A highly efficient method for the synthesis of allylic amines from terpenic chlorides by cheap copper (II) as catalyst in water has been developed. Allylic chlorides react with high regioselectivity in the presence of secondary amines, under mild conditions to give N-allylic amines in excellent yields.

  已经开发出一种高效的方法，该方法通过廉价的铜（II）作为催化剂在水中从三氯化碳合成烯丙基胺。在仲胺存在下，在温和的条件下，烯丙基氯以高的区域选择性反应，以优异的收率得到N-烯丙基胺。
• Kergomard, Annales de Chimie (Cachan, France), 1953, vol. <12> 8, p. 153,193
  作者：Kergomard

  DOI：——

  日期：——
• Tischtschenko; Foliadow, Zhurnal Obshchei Khimii, 1950, vol. 20, p. 905,907; engl. Ausg. S. 941, 943
  作者：Tischtschenko、Foliadow

  DOI：——

  日期：——
• The Action of t-Butyl Hypochlorite on α-Pinene^1,2
  作者：John J. Ritter、David Ginsburg

  DOI：10.1021/ja01162a009

  日期：1950.6
• Tischtschenko; Foliadow, Zhurnal Obshchei Khimii, 1952, vol. 22, p. 945,948; engl. Ausg. S. 999, 1001
  作者：Tischtschenko、Foliadow

  DOI：——

  日期：——