(2R,6R)-tert-butyl-[2-(6-{4-[(2S)-3-(4-methoxybenzyloxy)-2-methoxymethoxy-propyl]-[(2S)-2-methylpent-4-enyl]}-5,6-dihydro-2H-pyran-2-yl)-ethoxy]-dimethylsilane | 385809-16-5

分子结构分类

有机化合物 - 苯类化合物 - 苯和取代衍生物

中文名称

——

中文别名

——

英文名称

(2R,6R)-tert-butyl-[2-(6-{4-[(2S)-3-(4-methoxybenzyloxy)-2-methoxymethoxy-propyl]-[(2S)-2-methylpent-4-enyl]}-5,6-dihydro-2H-pyran-2-yl)-ethoxy]-dimethylsilane

英文别名

tert-butyl-[2-[(2R,6R)-2-[(2S,6S)-6-(methoxymethoxy)-7-[(4-methoxyphenyl)methoxy]-2-methyl-4-methylideneheptyl]-3,6-dihydro-2H-pyran-6-yl]ethoxy]-dimethylsilane

(2R,6R)-tert-butyl-[2-(6-{4-[(2S)-3-(4-methoxybenzyloxy)-2-methoxymethoxy-propyl]-[(2S)-2-methylpent-4-enyl]}-5,6-dihydro-2H-pyran-2-yl)-ethoxy]-dimethylsilane化学式

CAS

385809-16-5

化学式

C₃₂H₅₄O₆Si

mdl

——

分子量

562.863

InChiKey

YRXIRULCYGBUPK-OVOJMXFRSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

7.69
重原子数：

39
可旋转键数：

19
环数：

2.0
sp3杂化的碳原子比例：

0.69
拓扑面积：

55.4
氢给体数：

0
氢受体数：

6

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol	312695-81-1	C₃₀H₅₀O₅Si	518.809
——	(2R,6S)-tert-butyl-(2-{6-[(2R)-3-(4-methoxybenzyloxy)-2-methylpropyl]-5,6-dihydro-2H-pyran-2-yl}-ethoxy)-dimethylsilane	445306-73-0	C₂₅H₄₂O₄Si	434.692
——	(2R,6S)-(2-{6-[(2R)-3-benzyloxy-2-methyl-propyl]-5,6-dihydro-2H-pyran-2-yl}-ethoxy)-tert-butyl-dimethyl-silane	312695-77-5	C₂₄H₄₀O₃Si	404.665
——	(2S,4RS,6R)-4-benzenesulfonyl-7-{(2R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxybenzyloxy)-6-methylheptan-2-ol	385809-14-3	C₃₅H₅₄O₇SSi	646.961
——	{(2R)-6-[3-(4-methoxybenzyloxy)-2-methyl-propyl]-(2R,6S)-5,6-dihydro-2H-pyran-2-yl}acetaldehyde	259199-01-4	C₁₉H₂₆O₄	318.413
——	(2R)-3-{(2S,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-2-methylpropan-1-ol	312695-90-2	C₁₇H₃₄O₃Si	314.541
——	(2S,6RS)-7-ethoxy-2-[(2R)-3-(4-methoxybenzyloxy)-2-methylpropyl]-3,6-dihydro-2H-pyran	259199-00-3	C₁₉H₂₈O₄	320.429

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	[(2S),(2S,6S,7E,10S,11S,12E),(2R,6R)]-tert-butyl-(2-{6-[10-(4-methoxybenzyloxy)-6,11-bismethoxymethoxy-2-methyl-13-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylenetrideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}ethoxy)-dimethylsilane	385809-24-5	C₄₆H₇₄O₉Si	799.174
——	(1E,3S,4S,6E,8S,12S)-13-[(2R,6R)-6-[2-[tert-butyl(dimethyl)silyl]oxyethyl]-3,6-dihydro-2H-pyran-2-yl]-8-(methoxymethoxy)-3-[(4-methoxyphenyl)methoxy]-12-methyl-1-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-10-methylidenetrideca-1,6-dien-4-ol	312695-83-3	C₄₄H₇₀O₈Si	755.12
——	(2S)-4-(3-{(2R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-(2S)-2-methylpropyl)-2-methoxymethoxy-pent-4-en-1-ol	312695-91-3	C₂₄H₄₆O₅Si	442.712
——	[(2R,6R),(2S),2S]-4-(3-{6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-2-methylpropyl)-2-methoxymethoxypent-4-enal	312695-75-3	C₂₄H₄₄O₅Si	440.696
——	2-[(2R,6R)-2-[(2S,6S,7E,10S,11S,12E)-6-(methoxymethoxy)-11-[(4-methoxyphenyl)methoxy]-2-methyl-13-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-4-methylidene-10-(oxan-2-yloxy)trideca-7,12-dienyl]-3,6-dihydro-2H-pyran-6-yl]ethanol	349539-69-1	C₄₃H₆₄O₉	724.976
——	(2S)-2-[(1E,3S,4S,6E,8S,12S)-13-[(2R,6R)-6-(3,3-dibromoprop-2-enyl)-3,6-dihydro-2H-pyran-2-yl]-8-(methoxymethoxy)-3-[(4-methoxyphenyl)methoxy]-12-methyl-10-methylidene-4-(oxan-2-yloxy)trideca-1,6-dienyl]-4-methyl-3,6-dihydro-2H-pyran	394657-63-7	C₄₄H₆₂Br₂O₈	878.779
——	(1R,3E,7S,9E,11S,15S,17R)-11-(methoxymethoxy)-7-[(E,1S)-1-[(4-methoxyphenyl)methoxy]-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]prop-2-enyl]-15-methyl-13-methylidene-6,21-dioxabicyclo[15.3.1]henicosa-3,9,19-trien-5-one	312695-86-6	C₄₀H₅₄O₈	662.864
——	(1R,3Z,7S,9E,11S,15S,17R)-11-(methoxymethoxy)-7-[(E,1S)-1-[(4-methoxyphenyl)methoxy]-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]prop-2-enyl]-15-methyl-13-methylidene-6,21-dioxabicyclo[15.3.1]henicosa-3,9,19-trien-5-one	312695-87-7	C₄₀H₅₄O₈	662.864
——	(1R,3E,7S,9E,11S,15S,17R)-11-(methoxymethoxy)-7-[(E,1S)-1-[(4-methoxyphenyl)methoxy]-3-[(6R)-4-methyl-3,6-dihydro-2H-pyran-6-yl]prop-2-enyl]-15-methyl-13-methylidene-6,21-dioxabicyclo[15.3.1]henicosa-3,9,19-trien-5-one	1026853-78-0	C₄₀H₅₄O₈	662.864
——	(1R,3Z,7S,9E,11S,15S,17R)-11-hydroxy-7-{(1S,2E)-1-(4-methoxybenzyloxy)-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]allyl}-15-methyl-13-methylene-6,21-dioxabicyclo[15.3.1]henicosa-3,9,19-trien-5-one	312695-96-8	C₃₈H₅₀O₇	618.811
——	4-[(2R,6R)-2-[(2S,6S,7E,10S,11S,12E)-10-hydroxy-6-(methoxymethoxy)-11-[(4-methoxyphenyl)methoxy]-2-methyl-13-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-4-methylidenetrideca-7,12-dienyl]-3,6-dihydro-2H-pyran-6-yl]but-2-ynoic acid	349539-73-7	C₄₀H₅₄O₉	678.863
——	methyl 4-[(2R,6R)-2-[(2S,6S,7E,10S,11S,12E)-6-(methoxymethoxy)-11-[(4-methoxyphenyl)methoxy]-2-methyl-13-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-4-methylidene-10-(oxan-2-yloxy)trideca-7,12-dienyl]-3,6-dihydro-2H-pyran-6-yl]but-2-ynoate	349539-71-5	C₄₆H₆₄O₁₀	777.008
——	(1R,7S,9E,11S,15S,17R)-11-(methoxymethoxy)-7-[(E,1S)-1-[(4-methoxyphenyl)methoxy]-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]prop-2-enyl]-15-methyl-13-methylidene-6,21-dioxabicyclo[15.3.1]henicosa-9,19-dien-3-yn-5-one	349539-76-0	C₄₀H₅₂O₈	660.848
——	(1R,3S,7S,8S,10S,12S,15Z,18R)-7-hydroxy-12-[(E,1S)-1-[(4-methoxyphenyl)methoxy]-3-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]prop-2-enyl]-3-methyl-5-methylidene-9,13,22-trioxatricyclo[16.3.1.08,10]docosa-15,19-dien-14-one	312695-97-9	C₃₈H₅₀O₈	634.81
——	[(1E,3S,4S,6E,8S,12S)-8-(methoxymethoxy)-3-[(4-methoxyphenyl)methoxy]-12-methyl-1-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-10-methylidene-13-[(2R,6R)-6-(2-oxoethyl)-3,6-dihydro-2H-pyran-2-yl]trideca-1,6-dien-4-yl] 2-[bis(2,2,2-trifluoroethoxy)phosphoryl]acetate	312695-95-7	C₄₄H₅₉F₆O₁₂P	924.909

反应信息

作为反应物：

描述：

(2R,6R)-tert-butyl-[2-(6-{4-[(2S)-3-(4-methoxybenzyloxy)-2-methoxymethoxy-propyl]-[(2S)-2-methylpent-4-enyl]}-5,6-dihydro-2H-pyran-2-yl)-ethoxy]-dimethylsilane 在 titanium(IV) isopropylate 、叔丁基过氧化氢、