Argosmin C (1,10-Dimethyl-1(9)-octalin) | 5173-65-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: Argosmin C (1,10-Dimethyl-1(9)-octalin)
• 英文别名: 4a,8-dimethyl-2,3,4,5,6,7-hexahydro-1H-naphthalene
• CAS: 5173-65-9
• 化学式: C₁₂H₂₀
• 分子量: 164.291
• InChiKey: FLHPWJRCDFBGBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Argosmin C (1,10-Dimethyl-1(9)-octalin) 在 溶剂黄146 、 xylene 作用下， 生成 1-Methylen-cis-10-methyl-dekalin
  参考文献：
  名称：

  Photosensitized isomerization of 10-methyl-1(9)-octalins

  摘要：

  DOI：

  10.1021/ja01031a023
• 作为产物：
  描述：

  吉马酮 在 aluminum oxide 、 苯甲酸 作用下， 反应 4.0h， 生成 Argosmin C (1,10-Dimethyl-1(9)-octalin)
  参考文献：
  名称：

  分子和二氢geijeren-Reihe中的热解和水合大肠菌

  摘要：

  Abstract The pyrolysis of elemol (1) in the presence of benzoic or p‐nitrobenzoic acid, and of elemyl‐p‐nitrobenzoate (3) was studied. From the many products formed, the compounds 6, 7, 8, 10, 11, 14, 15 and 18 were isolated and identified. On the basis of systematic experiments in the elemol (1) and dihydrogeijerene (26) series the sequence of the formation of these products could be determined. Several factors influencing the compositions of the pyrolysis mixtures are discussed. The products of pyrolysis of both series [elemol (1) and dihydrogeijerene (26), respectively] were catalytically hydrogenated, yielding the saturated hydrocarbons 34, 35–37, and 38–40, respectively. The synthesis of racemic dihydrogeijerene (26) was achieved starting from germacrone (41).

  DOI：

  10.1002/hlca.19710540117

文献信息

• Oxygenation of 1,10-Dimethyl-1(9)-octalin
  作者：James A. Marshall、Alan R. Hochstetler

  DOI：10.1021/jo01342a008

  日期：1966.4
• Pyrolysen- und Hydrierungsversuche in der Elemol- und Dihydrogeijeren-Reihe
  作者：C. Ganter、Frau B. Keller-Wojtkiewicz

  DOI：10.1002/hlca.19710540117

  日期：——

  Abstract The pyrolysis of elemol (1) in the presence of benzoic or p‐nitrobenzoic acid, and of elemyl‐p‐nitrobenzoate (3) was studied. From the many products formed, the compounds 6, 7, 8, 10, 11, 14, 15 and 18 were isolated and identified. On the basis of systematic experiments in the elemol (1) and dihydrogeijerene (26) series the sequence of the formation of these products could be determined. Several factors influencing the compositions of the pyrolysis mixtures are discussed. The products of pyrolysis of both series [elemol (1) and dihydrogeijerene (26), respectively] were catalytically hydrogenated, yielding the saturated hydrocarbons 34, 35–37, and 38–40, respectively. The synthesis of racemic dihydrogeijerene (26) was achieved starting from germacrone (41).
• Photosensitized isomerization of 10-methyl-1(9)-octalins
  作者：James A. Marshall、Alan R. Hochstetler

  DOI：10.1021/ja01031a023

  日期：1969.1