6-t-butoxyhexyl chloride | 1001-73-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6-t-butoxyhexyl chloride
• 英文别名: 1-tert-butoxy-6-chlorohexane；t-butoxyhexyl chloride；1-chloro-6-[(2-methylpropan-2-yl)oxy]hexane
• CAS: 1001-73-6
• 化学式: C₁₀H₂₁ClO
• 分子量: 192.729
• InChiKey: CLILMZOQZSMNTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2909199090

反应信息

• 作为反应物：
  描述：

  6-t-butoxyhexyl chloride 在 四氢吡咯 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 生成 2-(6-tert-butoxyhexyl)-5-(propan-2-ylidene)cyclopenta-1,3-diene
  参考文献：
  名称：

  The effect that 6-tert-butoxyhexyl functionalization has on ethylene polymerization in ansa-zirconocene dichlorides

  摘要：

  New ansa-zirconocene dichloride derivatives have been prepared, which have a 6-t-butoxyhexyl pendant introduced either on a Cp-ring-carbon or at the silicon and carbon ansa-bridging atom. Ethylene polymerization studies have been carried out with novel precatalysts of the type: [(eta(5)-C13H8)-X(t-BuOC6H12)Me-(eta(5)-C5H4)]ZrCl, [X=C [1a], Si [2a]], [(eta(5)-C13H8)-XMe2-(eta(5)-(t-BuOC6H12C5H3))] ZrCl, [X = C [3a], Si [4a]] in the presence of excess methylalumoxane (MAO) to compare their catalytic activity and to delineate the effect of the 6-t-butoxyhexyl functionality on ethylene polymerization. The precatalysts [1a] and [2a] with the bridge functionality showed higher activity in ethylene polymerization than the corresponding complexes [3a] and [4a] which have it on the Cp ring moiety. On the other hand the silyl bridged complexes [2a] and [4a] produced a higher molecular weight polyethylene than the carbon-bridged one, regardless of the location of functional group. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.10.006
• 作为产物：
  描述：

  6-氯-1-己醇 、 异丁烯 在 Amberlyst H-15 作用下， 以 正己烷 为溶剂， 生成 6-t-butoxyhexyl chloride
  参考文献：
  名称：

  Mild protection and deprotection of alcohols as ter-butyl ethers in the field of pheromone synthesis

  摘要：

  DOI：

  10.1016/0040-4039(88)85055-x

文献信息

• Preparation method of catalyst for polyolefin polymerization and preparation method of polyolefin
  申请人：LG CHEM, LTD.

  公开号：US09447211B2

  公开（公告）日：2016-09-20

  A preparation method of a catalyst for polyolefin polymerization capable of polymerizing low-density polyethylene in a single reactor without separately injecting a comonomer to thereby prepare a final product with a low cost through a more simplified process, a catalyst obtained by the preparation method, and a preparation method of a polyolefin using the catalyst are provided.

  提供一种用于聚烯烃聚合的催化剂的制备方法，能够在单个反应器中聚合低密度聚乙烯，无需单独注入共聚单体，从而通过更简化的工艺制备成本较低的最终产品，提供了通过该制备方法获得的催化剂以及使用该催化剂的聚烯烃制备方法。
• Transition metal compound, catalyst composition comprising same, and method for producing olefin polymer using same
  申请人：LG CHEM, LTD.

  公开号：US10280238B2

  公开（公告）日：2019-05-07

  The present invention provides a transition metal compound, a catalyst composition comprising the same, and a method for producing an olefin polymer using the catalyst composition, the transition metal compound being capable of exhibiting high activity in olefin polymerization reaction, and also being capable of easily controlling the physical properties of an olefin polymer. When the transition metal compound is used, it is possible to provide an olefin polymer having an excellent energy-saving effect at the time of processing or molding.

  本发明提供了一种过渡金属化合物，包括该化合物的催化剂组合物，以及使用该催化剂组合物制备烯烃聚合物的方法。该过渡金属化合物能够在烯烃聚合反应中表现出高活性，并且能够轻松控制烯烃聚合物的物理性质。当使用该过渡金属化合物时，可以在加工或成型时提供具有优秀节能效果的烯烃聚合物。
• 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조 방법
  申请人：LG CHEM, LTD. 주식회사 엘지화학(120010134563) Corp. No ▼ 110111-2207995BRN ▼107-81-98139

  公开号：KR20170075529A

  公开（公告）日：2017-07-03

  본 발명에 따르면, 올레핀 중합 반응에서 높은 활성을 나타낼 수 있을 뿐만 아니라, 합성되는 올레핀 중합체의 물성을 용이하게 조절할 수 있는 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 상기 촉매 조성물을 이용한 올레핀 중합체의 제조 방법이 제공될 수 있다. 상기 전이 금속 화합물을 이용하면 높은 촉매 활성을 나타내면서 다양한 분자량 범위 내에서 높은 겉보기 밀도를 갖는 올레핀 중합체를 제공할 수 있다.

  根据本发明，不仅可以在烯烃聚合反应中表现出高活性，还可以方便地调节合成的烯烃聚合物的特性的过渡金属化合物，包括该过渡金属化合物的催化剂组合物以及可以提供使用该催化剂组合物制备烯烃聚合物的方法。利用上述过渡金属化合物，可以提供具有高催化活性并且在各种分子量范围内具有高表观密度的烯烃聚合物。
• 7-Vinyldecyl acetate, novel inhibitor of pheromonal attraction in the false codling moth, cryptophlebia leucotreta
  作者：B.V. Burger、M. le Roux、W.M. Mackenroth、H.S.C. Spies、J.H. Hofmeyr

  DOI：10.1016/s0040-4039(00)97954-1

  日期：1990.1

  It was found that 7-vinyldecyl acetate, a by-product of the synthesis of one of the constituents of the sex attractant of the false codling moth, Cryptophlebia leucotreta, effectively disrupts the attraction of male moths to virgin females or to synthetic lures.

  已发现，乙酸-乙烯基癸酯是假co蛾性诱饵的一种成分的合成，其副产物白隐隐孢子虫（Cryptophlebia leucotreta）有效地破坏了雄蛾对初生雌性或合成诱剂的吸引力。
• 인덴 유도체의 제조 방법, 이를 이용한 메탈로센 촉매 제조방법 및 올레핀 중합체 제조방법
  申请人：LG CHEM, LTD. 주식회사 엘지화학(120010134563) Corp. No ▼ 110111-2207995BRN ▼107-81-98139

  公开号：KR20200069042A

  公开（公告）日：2020-06-16

  본 발명은 특정 촉매하에, 7이상의 탄소수를 갖는 긴 사슬에 아이오딘이 결합한 반응물을 인덴계 화합물과 반응시킨 인덴 유도체의 제조 방법과 이를 이용한 촉매 제조방법, 및 올레핀 중합체 제조방법에 관한 것이다.

  该发明涉及在特定催化剂的作用下，制备与长链中具有7个或更多碳原子的链相结合的离子液体反应物与印地安衍生物反应的方法，以及使用此方法制备催化剂和制备聚烯烃的方法。