3,3-Dimethyl-2-exo-norbornyl-acetaldehyd | 39850-66-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3,3-Dimethyl-2-exo-norbornyl-acetaldehyd
• 英文别名: 2-[(1S,2R,4R)-3,3-dimethyl-2-bicyclo[2.2.1]heptanyl]acetaldehyde
• CAS: 39850-66-3；101372-40-1；113104-73-7；130857-68-0；130857-69-1
• 化学式: C₁₁H₁₈O
• 分子量: 166.263
• InChiKey: ZIIKSEQIKREAGR-IVZWLZJFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  Isocamphenilanylessigsaeure 在 lithium aluminium tetrahydride 、 N,N'-羰基二咪唑 作用下， 以 乙醚 为溶剂， 以82.9%的产率得到3,3-Dimethyl-2-exo-norbornyl-acetaldehyd
  参考文献：
  名称：

  δ-Santalolanaloga I Synthesen in der Isocamphanreihe, 27. Mitt.

  摘要：

  DOI：

  10.1007/bf00809950

文献信息

• Rhodium-catalyzed hydroformylation of olefins: Effect of [bis(2,4-di-tert-butyl) pentaerythritol] diphosphite (alkanox P-24) on the regioselectivity of the reaction
  作者：Jimoh Tijani、Bassam El Ali

  DOI：10.1016/j.jorganchem.2007.04.022

  日期：2007.7

  pentaerythritol] diphosphite (I) as a ligand represents an active catalyst system for highly regioselective hydroformylation of various alkenes. The commercially available bis(2,4-di-tert-butyl)pentaerythritol diphosphite (alkanox P-24) (I), which has been used so far as an antioxidant in the stabilization of polymers, was used as a diphosphite ligand for the selective hydroformylation reaction of olefins

  铑（I）与相关联的[双（2,4-二-叔丁基）季戊四醇]亚磷酸酯（我）作为配位体表示关于各种烯烃的高度选择性加氢甲酰基化的活性催化剂体系。迄今为止，作为抗氧化剂用于稳定聚合物的市售双（2,4-二叔丁基）季戊四醇二亚磷酸酯（alkanox P-24）（I）被用作二亚磷酸酯配体。烯烃的选择性加氢甲酰化反应。在烯烃的加氢甲酰化中，获得了对线性醛的优异选择性和出色的转化率。将加氢甲酰化反应应用于包括内部烯烃在内的各种烯烃底物。
• Cationic rhodium(I) complexes containing 4,4′-disubstituted 2,2′-bipyridines: A systematic variation on electron density over the metal centre
  作者：Paulo E.A. Ribeiro、Claudio L. Donnici、Eduardo N. dos Santos

  DOI：10.1016/j.jorganchem.2005.12.049

  日期：2006.4

  A series of [Rh(COD)(X-2-bipy)]BF4 complexes (COD = 1,5-cyclooctadiene; X-2-bipy = 4,4'-disubstituted 2,2'-bipyridines; X = OCH3, CH3, H, Cl or NO2) has been prepared from [Rh(COD)Cl](2). The complexes for X = OCH3, Cl and NO2 have not been described previously in the literature. All complexes have been characterised by elemental analysis, IR, H-1 NMR and UV-Vis spectrometry. This series of complexes presents a wide variation on electron density over the metal centre with virtually no variation on its steric environment which discloses interesting possibilities for catalytic and electro-catalytic studies. A preliminary evaluation of these complexes on the hydroformylation of camphene and beta-pinene showed that under the rather drastic conditions employed the complexes acted as a precursor for (Rh(CO)(3)H], which accounts for most of the catalytic activity. (c) 2006 Elsevier B.V. All rights reserved.
• δ-Santalolanaloga I Synthesen in der Isocamphanreihe, 27. Mitt.
  作者：Gerhard Buchbauer、Gabriele Püspök、Adelheid Angermayer、Elisabeth Silbernagel、Marisa Manz

  DOI：10.1007/bf00809950

  日期：1987.3