1-(6-((2,3-dihydrothieno[3,4-b][1,4]dioxin-2-yl)methoxy)hexyl)-1,4,8,11-tetraazacyclotetradecane | 1262103-11-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(6-((2,3-dihydrothieno[3,4-b][1,4]dioxin-2-yl)methoxy)hexyl)-1,4,8,11-tetraazacyclotetradecane
• 英文别名: (6-((2,3-dihydrothieno[3,4-b][1,4]dioxin-2-yl)methoxy)hexyl)1,4,8,11-tetraazacyclotetradecane；1-[6-(2,3-Dihydrothieno[3,4-b][1,4]dioxin-3-ylmethoxy)hexyl]-1,4,8,11-tetrazacyclotetradecane；1-[6-(2,3-dihydrothieno[3,4-b][1,4]dioxin-3-ylmethoxy)hexyl]-1,4,8,11-tetrazacyclotetradecane
• CAS: 1262103-11-6
• 化学式: C₂₃H₄₂N₄O₃S
• 分子量: 454.677
• InChiKey: CXQWRMQNYKHQEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  31
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  95.3
• 氢给体数：
  3
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  copper(II) tetrafluroborate hexahydrate 、 1-(6-((2,3-dihydrothieno[3,4-b][1,4]dioxin-2-yl)methoxy)hexyl)-1,4,8,11-tetraazacyclotetradecane 以 甲醇 为溶剂， 以54.4%的产率得到((6-((2,3-dihydrothieno[3,4-b][1,4]dioxin-2-yl)methoxy)hexyl)1,4,8,11-tetraazacyclotetradecane)copper(II) tetrafluoroborate
  参考文献：
  名称：

  Synthesis and characterization of monomeric and polymeric Cu(II) complexes of 3,4-ethylenedioxythiophene-functionalized with cyclam ligand

  摘要：

  A functionalized EDOT derivative with 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand pendant to the ethylene bridge (4) and its complexes [M(4)(BF4)(2)], where M(II)=Cu(II), was prepared and characterized. Their electrochemical copolymerization with EDOT was studied. The electro-co-polymerized films were characterized by electrochemical methods, X-ray photoelectron spectroscopy and by X-ray fluorescence spectroscopy. The co-polymerization method was found to afford a good control of the metal concentration in the polymer matrix and represents a good technique for preparing electronically conductive polymers containing redox-active metal complexes. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2010.08.075
• 作为产物：
  描述：

  1,6-二溴己烷 在 吡啶 、 4-二甲氨基吡啶 、 sodium hydride 、 对甲苯磺酸 作用下， 以 四氢呋喃 、 水 、 甲苯 、 苯 为溶剂， 反应 16.0h， 生成 1-(6-((2,3-dihydrothieno[3,4-b][1,4]dioxin-2-yl)methoxy)hexyl)-1,4,8,11-tetraazacyclotetradecane
  参考文献：
  名称：

  Synthesis and characterization of monomeric and polymeric Cu(II) complexes of 3,4-ethylenedioxythiophene-functionalized with cyclam ligand

  摘要：

  A functionalized EDOT derivative with 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand pendant to the ethylene bridge (4) and its complexes [M(4)(BF4)(2)], where M(II)=Cu(II), was prepared and characterized. Their electrochemical copolymerization with EDOT was studied. The electro-co-polymerized films were characterized by electrochemical methods, X-ray photoelectron spectroscopy and by X-ray fluorescence spectroscopy. The co-polymerization method was found to afford a good control of the metal concentration in the polymer matrix and represents a good technique for preparing electronically conductive polymers containing redox-active metal complexes. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2010.08.075

文献信息

• Synthesis and characterization of monomeric and polymeric Cu(II) complexes of 3,4-ethylenedioxythiophene-functionalized with cyclam ligand
  作者：Kuhamoorthy Velauthamurty、Simon J. Higgins、R.M. Gamini Rajapakse、H.M.N. Bandara、Masaru Shimomura

  DOI：10.1016/j.electacta.2010.08.075

  日期：2010.12

  A functionalized EDOT derivative with 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand pendant to the ethylene bridge (4) and its complexes [M(4)(BF4)(2)], where M(II)=Cu(II), was prepared and characterized. Their electrochemical copolymerization with EDOT was studied. The electro-co-polymerized films were characterized by electrochemical methods, X-ray photoelectron spectroscopy and by X-ray fluorescence spectroscopy. The co-polymerization method was found to afford a good control of the metal concentration in the polymer matrix and represents a good technique for preparing electronically conductive polymers containing redox-active metal complexes. (C) 2010 Elsevier Ltd. All rights reserved.