(4S)-1-(Chloromethyl)-4-(3-chloroprop-1-en-2-yl)cyclohex-1-ene | 917987-33-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (4S)-1-(Chloromethyl)-4-(3-chloroprop-1-en-2-yl)cyclohex-1-ene
• 英文别名: (4S)-1-(chloromethyl)-4-(3-chloroprop-1-en-2-yl)cyclohexene
• CAS: 917987-33-8
• 化学式: C₁₀H₁₄Cl₂
• 分子量: 205.127
• InChiKey: YSFWVIVMRZBUEI-SNVBAGLBSA-N

物化性质

• 沸点：
  266.3±35.0 °C(Predicted)
• 密度：
  1.096±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  beta-pinene 在 sodium hypochlorite 、 五氯化钼 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 0.5h， 以62%的产率得到perillyl chloride
  参考文献：
  名称：

  Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl

  摘要：

  MoCl5 is applied as efficient agent in allylic chlorination of terpenic olefins in the presence of NaOCl as chlorine donor. Various terpenes are converted to the corresponding allylic chlorides in moderate to good yield under mild and optimized reaction conditions. Different molybdenum precursors are also studied. Among them, MoO3 gives good yield, but after a longer reaction time.

  DOI：

  10.1590/s0103-50532011000700010

文献信息

• A mild and efficient method for the synthesis of a new optically active diallyl selenide and its catalytic activity in the allylic chlorination of natural terpenes
  作者：Brahim Boualy、Soufiane El Houssame、Luca Sancineto、Claudio Santi、Mustapha Ait Ali、Helen Stoeckli-Evans、Larbi El Firdoussi

  DOI：10.1039/c5nj02797g

  日期：——

  An organoselenide compound was synthesized starting from β-pinene. The activity of this complex towards allylic chlorination has been studied.

  以β-蒎烯为原料合成有机硒化物。已经研究了这种配合物对烯丙基氯化的活性。
• Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl
  作者：Brahim Boualy、Larbi El Firdoussi、Mustapha Ait Ali、Abdellah Karim

  DOI：10.1590/s0103-50532011000700010

  日期：——

  MoCl5 is applied as efficient agent in allylic chlorination of terpenic olefins in the presence of NaOCl as chlorine donor. Various terpenes are converted to the corresponding allylic chlorides in moderate to good yield under mild and optimized reaction conditions. Different molybdenum precursors are also studied. Among them, MoO3 gives good yield, but after a longer reaction time.