anhydrous sodium undec-10-enoate - CAS号 3398-33-2

物化性质

沸点：

239.88℃ at 101.325kPa
密度：

0.62 at 20℃
LogP：

4.1 at 25℃

计算性质

辛醇/水分配系数(LogP)：

-0.95
重原子数：

14
可旋转键数：

9
环数：

0.0
sp3杂化的碳原子比例：

0.73
拓扑面积：

40.1
氢给体数：

0
氢受体数：

2

安全信息

WGK Germany：

3
海关编码：

2916190090
储存条件：

-20°C

SDS

SDS：d16d7be52d8cd06fe9e1011d33b20157

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Section 1. Chemical Product and Company Identification
Sodium Undecylenate
Common Name/
Trade Name
Manufacturer
Commercial Name(s)
Synonym
Chemical Name
Chemical Family
Sodium Undecylenate

Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Get medical attention if irritation occurs.
Skin Contact Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact Not available.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation Not available.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious Ingestion Not available.

Section 5. Fire and Explosion Data
Flammability of the Product May be combustible at high temperature.
Auto-Ignition Temperature Not available.
Flash Points Not available.
Flammable Limits Not available.
Products of Combustion These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Slightly flammable to flammable in presence of heat.
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
and Instructions LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Not available.
Special Remarks on
Fire Hazards
Special Remarks on Explosion Not available.
Hazards

Section 6. Accidental Release Measures
Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system.
Sodium Undecylenate

Section 7. Handling and Storage
Precautions Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
breathe dust. Keep away from incompatibles such as oxidizing agents.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 0°C (32°F).
Freeze.

Section 8. Exposure Controls/Personal Protection
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection
Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spill to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits Not available.

Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (Powdered solid.) Odor Not available.
Taste Not available.
Molecular Weight 206.3 g/mole
Color Not available.
pH (1% soln/water) Not available.
Boiling Point Not available.
Melting Point Not available.
Critical Temperature Not available.
Not available.
Specific Gravity
Vapor Pressure Not applicable.
Vapor Density Not available.
Volatility Not available.
Odor Threshold Not available.
Not available.
Water/Oil Dist. Coeff.
Ionicity (in Water) Not available.
Not available.
Dispersion Properties
Solubility Not available.

Section 10. Stability and Reactivity Data
Stability The product is stable.
Not available.
Instability Temperature
Conditions of Instability Excess heat, incompatible materials
Incompatibility with various Reactive with oxidizing agents.
substances
Corrosivity Not available.
Sodium Undecylenate
Special Remarks on Sensitive to light. Protect from light.
Reactivity
Special Remarks on Not available.
Corrosivity
Polymerization Will not occur.

Section 11. Toxicological Information
Routes of Entry Inhalation. Ingestion.
Toxicity to Animals LD50: Not available.
LC50: Not available.
Chronic Effects on Humans Not available.
Other Toxic Effects on Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Humans
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on
Not available.
Chronic Effects on Humans
Special Remarks on other Acute Potential Health Effects:
Toxic Effects on Humans Skin: May cause skin irritation.
Eyes: Dust May cause eye irritation.
Inhalation: Dust may cause respiratory tract irritation.
Ingestion: May cause gastrointestinal tract irritation with nausea, vomiting.

Section 12. Ecological Information
Ecotoxicity Not available.
BOD5 and COD Not available.
Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the Products The product itself and its products of degradation are not toxic.
of Biodegradation
Special Remarks on the Not available.
Products of Biodegradation

Section 13. Disposal Considerations
Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental
control regulations.

Section 14. Transport Information
DOT Classification Not a DOT controlled material (United States).
Identification Not applicable.
Special Provisions for Not applicable.
Transport
Sodium Undecylenate
DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
No products were found.
Federal and State
Regulations
California California prop. 65: This product contains the following ingredients for which the State of California has found
to cause cancer which would require a warning under the statute: No products were found.
Proposition 65
Warnings
California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: No products were found.
Other Regulations EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
222-264-8).
Canada: Not listed on Canadian Domestic Substance List (DSL) or Canadian Non-Domestic Substances List
(NDSL)
China: Not listed on National Inventory.
Japan: Not listed on National Inventory (ENCS).
Korea: Listed on National Inventory (KECI).
Philippines: Not listed on National Inventory (PICCS).
Australia: Not listed on AICS.
WHMIS (Canada) Not controlled under WHMIS (Canada).
Other Classifications
DSCL (EEC) This product is not classified according Not applicable.
to the EU regulations.
Health Hazard
HMIS (U.S.A.) 2 National Fire Protection
1 Flammability
1 Association (U.S.A.)
Fire Hazard
2 0 Reactivity
Health
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment
Gloves.
Sodium Undecylenate
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent.

SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

十一碳烯酸钠是一种生物化学试剂，可用于生物材料或有机化合物的相关研究，在生命科学领域具有重要应用价值。

反应信息

作为反应物：

描述：

anhydrous sodium undec-10-enoate 在 hydrogen tetrachloroaurate(III) 、水作用下，反应 0.25h，生成十一烷二酸

参考文献：

名称：

HAuCl4与N-乙烯基吡咯烷酮反应在水溶液中轻松合成二十面体金

摘要：

在本文中，我们描述了一种通过简单地将HAuCl 4和N-乙烯基吡咯烷酮的水溶液混合而以高收率生成金二十头蛇的方案。我们的机理研究表明，水在该合成过程中起着重要作用：作为亲核试剂，它会攻击金-乙烯基络合物，从而导致生成基于醇的Au I中间体。然后，该中间体经历氧化还原反应，其中Au I还原为Au 0，导致形成Au原子，然后形成约18nm尺寸的Au二十面体，产率为94％，以及最终产物中的羧酸。该新方案也已用于制备多对孪生的Ag纳米颗粒（尺寸为15–20 nm），Pd纳米颗粒的球形聚集体（尺寸为25–30 nm）和非常小的Pt纳米颗粒（尺寸为2 nm）。由于所有这些合成均不需要有机溶剂，表面活性剂或聚合物稳定剂，因此该方案可以为具有各种组成和形态的贵金属纳米粒子提供一种简单，通用且对环境无害的途径。

DOI：

10.1002/chem.200901440
作为产物：

描述：

2-十一烯酸在碳酸氢钠作用下，以乙醇、水为溶剂，以100%的产率得到anhydrous sodium undec-10-enoate

参考文献：

名称：

新型水溶性三苯膦改性的β-环糊精的合成，铑配合物及其催化应用

摘要：

合成了一种基于β-环糊精骨架的新三苯基膦（PM-β-CD-OTPP）。可以通过使用纳米沉淀法将该配体分散在水中。透射电子显微镜和NMR光谱表明PM-β-CD-OTPP聚集在水中并形成稳定的分散体。在存在选定的水溶性客体的情况下，通过形成包合物可以显着提高其水溶性。与铑前体有关，PM-β-CD-OTPP能够在水中生成可溶性铑。此外，NMR实验表明，即使PM-β-CD-OTPP与铑配位，客人仍可进入环糊精腔。最后，该配体对于在水性介质中进行铑催化的加氢和加氢甲酰化反应非常有效。

DOI：

10.1002/adsc.201000917
作为试剂：

描述：

3,3-dimethyl-1,2-diphenyl-1-cyclopropene 在 HMn(CO)5 、一氧化碳、 anhydrous sodium undec-10-enoate 作用下，以水为溶剂，反应 15.0h，生成 cis-1,2-diphenyl-3,3-dimethylcyclopropane 、 2,2-Dimethyl-1,3-diphenyl-cyclopropanecarbaldehyde

参考文献：

名称：

与HMn（CO）5的烯烃反应：胶束螯合的产物选择性

摘要：

在洗涤剂介质中进行的HMn（CO）5与某些环丙烯的反应与在均相介质中进行的相同反应得到的氢甲酰化产物和氢化产物的混合物不同。这些结果与笼形的自由基自由基对的中间相一致，这些自由基对从笼中的逃逸被胶束螯合所阻止。

DOI：

10.1016/0022-328x(83)80045-x

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文献信息

MUCOUS LAYER-ADHESIVE POLY-r-GLUTAMIC ACID NANOMICELLES AND DRUG DELIVERY SYSTEM USING SAME

申请人：BIOLEADERS CORPORATION

公开号：US20160193348A1

公开（公告）日：2016-07-07

The present invention relates to nanomicelles composed of a complex of a lipophilic compound and a poly-gamma-glutamic acid wherein a portion of carboxyl groups are substituted with an amine group, and more particularly, to nanomicelles composed of a complex of a lipophilic compound and a poly-gamma-glutamic acid wherein a portion of carboxyl groups are substituted with an amine group, a preparation method thereof, and a drug delivery system employing the mucous membrane-adhesive property of the nanomicelles. According to the present invention, the nanomicelle drug delivery system based on poly-gamma-glutamic acid that is a natural biopolymer can be used for the delivery of a drug to mucous membranes to thereby increase the in vivo stability and effectiveness of the drug.

本发明涉及由脂溶性化合物和聚γ-谷氨酸复合物组成的纳米胶束，其中部分羧基被胺基取代，更具体地，涉及由脂溶性化合物和聚γ-谷氨酸复合物组成的纳米胶束，其中部分羧基被胺基取代，以及其制备方法和利用纳米胶束的粘膜粘附性质的药物传递系统。根据本发明，基于天然生物聚合物聚γ-谷氨酸的纳米胶束药物传递系统可用于将药物传递至粘膜，从而增加药物在体内的稳定性和有效性。
BITTER TASTE MODIFIERS INCLUDING SUBSTITUTED 1-BENZYL-3-(1-(ISOXAZOL-4-YLMETHYL)-1H-PYRAZOL-4-YL)IMIDAZOLIDINE-2,4-DIONES AND COMPOSITIONS THEREOF

申请人：SENOMYX, INC.

公开号：US20160376263A1

公开（公告）日：2016-12-29

The present invention includes compounds and compositions known to modify the perception of bitter taste, and combinations of said compositions and compounds with additional compositions, compounds, and products. Exemplary compositions comprise one or more of the following: cooling agents; inactive drug ingredients; active pharmaceutical ingredients; food additives or foodstuffs; flavorants, or flavor enhancers; food or beverage products; bitter compounds; sweeteners; bitterants; sour flavorants; salty flavorants; umami flavorants; plant or animal products; compounds known to be used in pet care products; compounds known to be used in personal care products; compounds known to be used in home products; pharmaceutical preparations; topical preparations; cannabis-derived or cannabis-related products; compounds known to be used in oral care products; beverages; scents, perfumes, or odorants; compounds known to be used in consumer products; silicone compounds; abrasives; surfactants; warming agents; smoking articles; fats, oils, or emulsions; and/or probiotic bacteria or supplements.

本发明涵盖已知用于改变苦味感知的化合物和组合物，以及所述组合物和化合物与额外的组合物、化合物和产品的组合。示例组合物包括以下一种或多种：冷却剂；无活性药物成分；活性药用成分；食品添加剂或食品；调味剂或调味增强剂；食品或饮料产品；苦味化合物；甜味剂；苦味剂；酸味调味剂；咸味调味剂；鲜味调味剂；植物或动物产品；已知用于宠物护理产品中的化合物；已知用于个人护理产品中的化合物；已知用于家用产品中的化合物；制药制剂；局部制剂；大麻衍生或与大麻相关的产品；已知用于口腔护理产品中的化合物；饮料；香味、香水或除臭剂；已知用于消费品中的化合物；硅化合物；磨料；表面活性剂；发热剂；吸烟物品；脂肪、油脂或乳化剂；和/或益生菌或补充剂。
COMPOUNDS USEFUL AS MODULATORS OF TRPM8

申请人：Senomyx, Inc.

公开号：US20170096418A1

公开（公告）日：2017-04-06

The present disclosure relates to compounds which are useful as cooling sensation compounds.

本公开涉及作为冷感化合物有用的化合物。
Compositions comprising low-DP polymerized surfactants and methods of use thereof

申请人：Fevola J. Michael

公开号：US20070259797A1

公开（公告）日：2007-11-08

Provided are low-irritation personal care compositions comprising a low-DP polymerized surfactants. Also provided are methods of making and using such compositions.

提供了低刺激性个人护理配方，其中包括低DP聚合表面活性剂。还提供了制备和使用这种配方的方法。
Ester-Functional Silanes And The Preparation And Use Thereof; And Use Of Iminium Compounds As Phase Transfer Catalysts

申请人：Dow Corning Corporation

公开号：US20150126676A1

公开（公告）日：2015-05-07

A method for producing a reaction product comprising an ester-functional silane, the method comprising: i) reacting a composition comprising: a) a haloorganosilane, b) a metal salt of a carboxy-functional compound, c) a phase transfer catalyst comprising a bicyclic amidine, an iminium compound, or a mixture thereof, provided that the iminium compound is not an acyclic guanidinium compound or pyridinium compound, and d) a co-catalyst, provided that the co-catalyst is optional when the phase transfer catalyst comprises the iminium compound.

一种生产酯基硅烷反应产物的方法，该方法包括：i）反应包含以下成分的组合物：a）卤代有机硅烷，b）羧基功能化合物的金属盐，c）相转移催化剂，包括二环脲、亚胺化合物或其混合物，但是当亚胺化合物不是无环鸟氨基化合物或吡啶化合物时，d）协同催化剂，当相转移催化剂包括亚胺化合物时，协同催化剂是可选的。

anhydrous sodium undec-10-enoate | 3398-33-2

物质功能分类

分子结构分类

物化性质

计算性质

安全信息

SDS

制备方法与用途

反应信息

文献信息

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