1-dimethylphenylsilyl-3,7-dimethyl-2,6-octadiene | 560087-41-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1-dimethylphenylsilyl-3,7-dimethyl-2,6-octadiene
• 英文别名: (3,7-Dimethylocta-2,6-dien-1-yl)(dimethyl)phenylsilane；3,7-dimethylocta-2,6-dienyl-dimethyl-phenylsilane
• CAS: 560087-41-4
• 化学式: C₁₈H₂₈Si
• 分子量: 272.506
• InChiKey: GJASLNZKONWWOO-UHFFFAOYSA-N

物化性质

• 沸点：
  355.3±31.0 °C(Predicted)
• 密度：
  0.88±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.29
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  芳樟醇 、 potassium hydride 、 dimethyl-phenyl-(trimethylgermyl)-Silane 以 四氢呋喃 、 六甲基磷酰三胺 为溶剂， 以29%的产率得到1-trimethylgermyl-3,7-dimethyl-2,6-octadiene
  参考文献：
  名称：

  Reaction of Triorgano(Triorganogermyl)Silanes with Alkali-Metal Allyl Aicoholates

  摘要：

  Reaction of the lithium alcoholates of 1-vinylcyclohexanol (2a), (+/-)-linalool (2b), and 1-octen-3-ol (2c) with (dimethylphenylgermyl)trimethylsilane (3a) gave selectively the corresponding allyldimethylphenylgermane derivatives (5a,c,e). Similar treatment with dimethylphenyl(trimethylgermyl)silane (3b) gave mixtures of the allyltrimethylgermanes (5b,d,f) and allyldimethylphenylsilanes (7b,d,f), whereas use of the potassium alcoholates afforded selectively 5b,d,f.

  DOI：

  10.1080/00397919208055424

文献信息

• Reaction of Triorgano(Triorganogermyl)Silanes with Alkali-Metal Allyl Aicoholates
  作者：Mikio Kabaki、Sumie Inoue、Yoshiro Sato

  DOI：10.1080/00397919208055424

  日期：1992.1

  Reaction of the lithium alcoholates of 1-vinylcyclohexanol (2a), (+/-)-linalool (2b), and 1-octen-3-ol (2c) with (dimethylphenylgermyl)trimethylsilane (3a) gave selectively the corresponding allyldimethylphenylgermane derivatives (5a,c,e). Similar treatment with dimethylphenyl(trimethylgermyl)silane (3b) gave mixtures of the allyltrimethylgermanes (5b,d,f) and allyldimethylphenylsilanes (7b,d,f), whereas use of the potassium alcoholates afforded selectively 5b,d,f.