1-(2-chloro-1,1,2-trifluoroethyl)imidazole | 13616-06-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-(2-chloro-1,1,2-trifluoroethyl)imidazole
• 英文别名: N-(2-Chloro-1,1,2-trifluoroethyl)imidazole；1-(2-chloro-1,1,2-trifluoro-ethyl)-1H-imidazole；N-<1,1,2-Trifluor-2-chlor-ethyl>-imidazol
• CAS: 13616-06-3
• 化学式: C₅H₄ClF₃N₂
• mdl: MFCD15147148
• 分子量: 184.548
• InChiKey: CFEDCMOCDFMOPK-UHFFFAOYSA-N

物化性质

• 沸点：
  53-55 °C(Press: 10 Torr)
• 密度：
  1.49±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-(2-chloro-1,1,2-trifluoroethyl)imidazole 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以69%的产率得到2-bromo-1-(2-chloro-1,1,2-trifluoroethyl)imidazole
  参考文献：
  名称：

  Chemical properties of N-polyfluoroethylimidazole and -pyrrole derivatives

  摘要：

  研究了N原子上含有二氟亚甲基片段的咪唑和吡咯衍生物的溴化、酰化、硝化和金属化。使用1-(1,1,2,2-四氟乙基)吡咯、1-(1,1,2,2-四氟乙基)咪唑和1-(2-氯-1,1,2-三氟乙基)咪唑作为基材。获得1-烷基-3-(1,1,2,2-四氟乙基)-和1-烷基-3-(2-氯-1,1,2-三氟乙基)咪唑鎓碘化物。这些可用作制备咪唑系列新型离子液体和1-烷基-3-多氟乙基咪唑-2-硫酮的中间体。

  DOI：

  10.1007/s11172-005-0323-3
• 作为产物：
  描述：

  咪唑 、 三氟氯乙烯 在 氢氧化钾 作用下， 以 丙酮 为溶剂， 反应 1.0h， 以86%的产率得到1-(2-chloro-1,1,2-trifluoroethyl)imidazole
  参考文献：
  名称：

  Fluorine-containing azoles. 3. Reaction of imidazoles and perimidines with perfluoroalkenes

  摘要：

  DOI：

  10.1007/bf00513861

文献信息

• FLUORINE-CONTAINING POLYMER HAVING HETEROAROMATIC RING
  申请人：Komatsu Yuzo

  公开号：US20090105400A1

  公开（公告）日：2009-04-23

  There is provided a fluorine-containing polymer having an ionic group which has a heteroaromatic ring and is useful as a material comprising various heteroaromatic ring compounds having a stable fluorine-containing heteroaromatic ring, and further a fluorine-containing polymer having a heteroaromatic ring which is useful as a starting material of the above-mentioned polymer or a curing agent. Also, there is provided a fluorine-containing polymer having a heteroaromatic ring such as imidazole in its side chain, a polymer salt thereof, and a polymer composition comprising such a polymer and a polymer salt and a nano filler.

  提供了一种含氟聚合物，其具有带有杂环芳香环的离子基，并且可用作由稳定的含氟杂环芳香环化合物组成的材料，还提供了一种具有杂环芳香环的含氟聚合物，可用作上述聚合物或固化剂的起始材料。此外，还提供了一种具有杂环芳香环（如咪唑）的含氟聚合物及其聚合物盐，以及包含该聚合物、聚合物盐和纳米填料的聚合物组合物。
• FLUORINE-CONTAINING POLYMER CONTAINING HETEROAROMATIC RING
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1983008A1

  公开（公告）日：2008-10-22

  There is provided a fluorine-containing polymer having an ionic group which has a heteroaromatic ring and is useful as a material comprising various heteroaromatic ring compounds having a stable fluorine-containing heteroaromatic ring, and further a fluorine-containing polymer having a heteroaromatic ring which is useful as a starting material of the above-mentioned polymer or a curing agent. Also, there is provided a fluorine-containing polymer having a heteroaromatic ring such as imidazole in its side chain, a polymer salt thereof, and a polymer composition comprising such a polymer and a polymer salt and a nano filler.

  本发明提供了一种具有离子基团的含氟聚合物，该聚合物具有杂芳香族环，可用作由具有稳定的含氟杂芳香族环的各种杂芳香族环化合物组成的材料，还提供了一种具有杂芳香族环的含氟聚合物，该聚合物可用作上述聚合物的起始材料或固化剂。此外，还提供了一种在侧链中具有咪唑等杂芳环的含氟聚合物、其聚合物盐，以及包含这种聚合物和聚合物盐以及纳米填料的聚合物组合物。
• ACTUATOR ELEMENT
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1981034A1

  公开（公告）日：2008-10-15

  There is provided an actuator element which can be driven at low voltages, is operated stably in air and in vacuo with a quick response, exhibits a large degree of displacement and a large displacement force, has high mechanical strength including flexibility, thus giving long-term durability for repeated use, can be produced by a very simple method, can be formed into a small size because of a simple structure, and can be put into practical use in wide applications. The actuator element is comprised of an ion-conducting layer for an actuator element comprising (I) a fluorine-containing polymer having functional group and (II) an ionic liquid, in which the fluorine-containing polymer having functional group is a polymer having functional group selected from the group consisting of -OH, -COOH, -COOR, -CN, iodine atom, epoxy group and (meth)acryloyl group in a polymer side chain and/or at an end of a polymer trunk chain, and an electrode layer comprising (I) the fluorine-containing polymer having functional group, (II) an ionic liquid and (III) an electroconductive nano-filler.

  本发明提供了一种可在低电压下驱动的致动器元件，它可在空气和真空中稳定运行且反应迅速，具有较大的位移量和较大的位移力，具有较高的机械强度和柔韧性，因此可反复长期使用，可通过非常简单的方法生产，因结构简单而可制成较小的尺寸，并可在广泛的应用中投入实际使用。该致动器元件由用于致动器元件的离子传导层组成，该离子传导层由 (I) 具有官能团的含氟聚合物和 (II) 离子液体构成，其中具有官能团的含氟聚合物是具有选自 -OH、-COOH、-COOR、-CN、碘原子、环氧基和（甲基）丙烯酰基组成的聚合物侧链和/或聚合物主链的末端，以及电极层，电极层包括（I）具有官能团的含氟聚合物、（II）离子液体和（III）导电纳米填料。
• ELECTRODE FILM FOR POLYMER ACTUATOR ELEMENT, AND POLYMER ACTUATOR ELEMENT COMPRISING SAME
  申请人：Daikin Industries, Ltd.

  公开号：EP2416488A1

  公开（公告）日：2012-02-08

  Disclosed is an electrode film for a polymer actuator element, which has a large displacement amount, a high displacement rate, and generates a large force at the time of displacement. Specifically disclosed is an electrode film for a polymer actuator element, which contains a fluororesin (A), a fluorine rubber (B), an ionic liquid (C), and a conductive filler (D).

  本发明公开了一种用于聚合物致动器元件的电极薄膜，它具有较大的位移量、较高的位移速率以及在位移时产生较大的力。具体而言，本发明公开了一种用于聚合物致动器元件的电极薄膜，该薄膜包含氟树脂（A）、氟橡胶（B）、离子液体（C）和导电填料（D）。
• Direct Phosphorylation of<i>N</i>-Protected Imidazoles and Benzoimidazoles-A Route to 1<i>H</i>-Imidazol(benzoimidazol)-2-yl Phosphonic and Phosphinic Acids and Their Derivatives
  作者：Igor V. Komarov、Aleksandr V. Strizhak、Mikhail Yu.Kornilov、Aleksandr N. Kostyuk、Andrey A. Tolmachev

  DOI：10.1080/00397919808004288

  日期：1998.7

  Synthetic approaches to 1H-imidazol-2-yl and 1H-benzoimidazol-2-yl phosphinic and phosphonic acids and their derivatives are reported, based on phosphorylation of N-protected heterocylcles by PhPOCl2 or MePOCl2. Reaction of N-alkylbenzoimidazoles with POCl3 did not lead to C-phosphorylated products in a reasonable yield, [2,2']-bis-benzoimidazolyles being formed instead.