1,1,1,2,5,6,6,6-Octafluoro-3-iodo-2,5-bis(trifluoromethyl)hexane | 88562-42-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 英文名称: 1,1,1,2,5,6,6,6-Octafluoro-3-iodo-2,5-bis(trifluoromethyl)hexane
• CAS: 88562-42-9
• 化学式: C₈H₃F₁₄I
• 分子量: 491.994
• InChiKey: ZSSJJRCCIXTXHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  1,1,1,2,5,6,6,6-Octafluoro-3-iodo-2,5-bis(trifluoromethyl)hexane 在 氢氧化钾 作用下， 以 乙醇 为溶剂， 反应 2.0h， 以75%的产率得到(E)-1,1,1,2,5,6,6,6-octafluoro-2,5-bis(trifluoromethyl)hex-3-ene
  参考文献：
  名称：

  Arlen; Gauffreteau; Jenneaux, Bulletin de la Societe Chimique de France, 1985, vol. NO. 4, # 4, p. 562 - 567

  摘要：

  DOI：
• 作为产物：
  描述：

  4-碘-2-三氟甲基-1,1,1,2-四氟丁烷 在 氢氧化钾 作用下， 以 乙醇 为溶剂， 40.0~195.0 ℃ 、4.0 MPa 条件下， 反应 16.0h， 生成 1,1,1,2,5,6,6,6-Octafluoro-3-iodo-2,5-bis(trifluoromethyl)hexane
  参考文献：
  名称：

  Arlen; Gauffreteau; Jenneaux, Bulletin de la Societe Chimique de France, 1985, vol. NO. 4, # 4, p. 562 - 567

  摘要：

  DOI：

文献信息

• Production Processes and Systems, Compositions, Surfactants, Monomer Units, Metal Complexes, Phosphate Esters, Glycols, Aqueous Film Forming Foams, and Foam Stabilizers
  申请人：Jackson Andrew

  公开号：US20090137773A1

  公开（公告）日：2009-05-28

  Compositions and methods for making compositions such as RF(Rτ)nQ are provided. The RF group can include at least two —CF3 groups, the Rτ group can be a group having at least two carbons, n can be at least 1, and the Q group can include one or more atoms of the periodic table of elements. RF-intermediates (RF(RT)nQg); Surfactants (RF(RT)nQs); Foam stabilizers (RF(RT)IIQFS); Metal complexes (RF(RT)IIQMC); Phosphate ester (RF(RT)HQPE); Polymers (RF(RT)IIQMU); Monomers (RF(RT)IIQM); Urethanes (RF(Rτ)nQu); and/or Glycols (RF(RT)IIQH) and methods for making the same are provided.

  本发明提供了制备RF（Rτ）nQ等组合物的方法和组合物。其中，RF基团可以包括至少两个—CF3基团，Rτ基团可以是具有至少两个碳的基团，n可以至少为1，而Q基团可以包括元素周期表中的一个或多个原子。本发明还提供了RF中间体（RF（Rτ）nQg）；表面活性剂（RF（Rτ）nQs）；泡沫稳定剂（RF（Rτ）IIQFS）；金属配合物（RF（Rτ）IIQMC）；磷酸酯（RF（Rτ）HQPE）；聚合物（RF（Rτ）IIQMU）；单体（RF（Rτ）IIQM）；脲（RF（Rτ）nQu）；以及/或者乙二醇（RF（Rτ）IIQH）和制备它们的方法。
• RIESS, J.;JEANNEAUX, F.;LE, BLANC, M.;LANTZ, A.
  作者：RIESS, J.、JEANNEAUX, F.、LE, BLANC, M.、LANTZ, A.

  DOI：——

  日期：——
• ARLEN, CHRISTIAN;GAUFFRETEAU, YANNE, BULL. SOC. CHIM. FR., 1985, N 4, 562-567
  作者：ARLEN, CHRISTIAN、GAUFFRETEAU, YANNE

  DOI：——

  日期：——
• Compositions, Combustion Prevention Compositions, Methods for Preventing and/or Extinguishing Combustion, Combustion Prevention Systems, and Production Processes
  申请人：Hedrick Vicki

  公开号：US20070152200A1

  公开（公告）日：2007-07-05

  Compositions comprising are provided wherein R F is a fluorine containing moiety comprising (CF 3 ) 2 CFCH 2 (CF 3 )CH—, (CF 3 ) 2 CFCH 2 ((CF 3 ) 2 CF)CH—, (CF 3 ) 2 CFCH 2 ((CF 3 ) 2 CH)CH—, (CF 3 ) 2 CHCH 2 ((CF 3 ) 2 CF)CH—, ((CF 3 ) 2 CFCH 2 ) 2 CH—, (CF 3 ) 2 CFCH 2 CF—, (CF 3 ) 2 CF—, (CF 3 ) 2 CH—, CF 3 —, or C n F 2n+1 —, n being an integer from 2 to 20; R 1 is F or H; R 2 comprises (CF 3 ) 2 CF—, (CF 3 ) 2 CH—, CF 3 —, F, or H; and R 3 comprises (CF 3 ) 2 CF—, (CF 3 ) 2 CH—, CF 3 —, F, or H, such compositions can produced according to processes, and utilized to prevent combustion utilizing systems.
• Telomer compositions and production processes
  申请人：Ameduri Bruno

  公开号：US20080076892A1

  公开（公告）日：2008-03-27

  Telomer compositions are provided that can include at least one taxogen unit and a telogon unit, the taxogen unit being one or more of TFP, PFP, VDF, TFMA, PMVE, VF, TFE, CTFE, BrTFE, HFP, dichlorodifluoroethylene, chlorodifluoroethylene, bromodifluoroethylene, ethylenealkyl ether, ethylene, and propylene; the telogen unit being one or more of R F Q or R Cl Q, wherein the R F group can be an alkyl group having at least four fluorine atoms, the R Cl group can be —CCl 3 , and the Q group can be H, Br, or I. Chemical production processes are also provided that can include exposing a taxogen to a telogen to form a telomer.