Dibenzocinnoline | 217-66-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: Dibenzocinnoline
• 英文别名: phenanthro[9,10-c]pyridazine
• CAS: 217-66-3
• 化学式: C₁₆H₁₀N₂
• 分子量: 230.269
• InChiKey: QKHBRTOZTSOCKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9-溴菲 在 甲醇 、 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 亚硝酸特丁酯 、 乙醇 、 三氟化硼乙醚 、 水 、 硝酸 、 乙酸酐 、 铁粉 、 potassium carbonate 、 溶剂黄146 、 二异丙胺 作用下， 以 四氢呋喃 、 邻二氯苯 为溶剂， 反应 3.0h， 生成 Dibenzocinnoline
  参考文献：
  名称：

  菲-稠合的偶氮-烯-​​炔：二苯并[f,h]肉啉和二苯并[e,g]异吲唑衍生物的合成

  摘要：

  菲稠合的偶氮烯炔化合物的环化反应已经通过实验和计算进行了研究。实验结果表明，该系统易于二聚化，比以前研究的基于萘和苯的类似物更容易发生。计算表明，吡唑和芳烃稠合的吡唑通过“缩氨酸共轭”强烈稳定 5 位的卡宾，这表明在环化过程中卡宾/卡宾的稳定浓度足以二聚。

  DOI：

  10.1021/jo201378t

文献信息

• ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US20190031586A1

  公开（公告）日：2019-01-31

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  提供一种有机化合物，通过使用该有机化合物形成的三维有机结构、分离筛和具有该有机结构的光学层，以及具有光学层作为光学放大层的光学器件。该有机结构包括通过非共价键自组装的多个有机分子。每个单元有机分子具有芳香环，第一对取代基连接到芳香环的可取代位置的相邻位置，第二对取代基连接到芳香环的剩余可取代位置的相邻位置。单元有机分子通过范德华力相互作用、伦敦分散相互作用或氢键作用于第一和第二对取代基之间的π-π相互作用而自组装。
• COMPOUND HAVING DIAZATRIPHENYLENE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：HODOGAYA CHEMICAL CO., LTD.

  公开号：US20160064676A1

  公开（公告）日：2016-03-03

  A compound that emits fluorescence and delayed fluorescence is provided as a material for an organic electroluminescent device of high efficiency, and an organic photoluminescent device and an organic electroluminescent device of high efficiency and high luminance are provided using this compound. The compound of a general formula (1) having a diazatriphenylene ring structure is used as a constituent material of at least one organic layer in the organic electroluminescent device that includes a pair of electrodes, and one or more organic layers sandwiched between the pair of electrodes.

  提供了一种发射荧光和延迟荧光的化合物作为高效有机电致发光器件的材料，并且利用这种化合物提供了高效高亮度的有机荧光器件和有机电致发光器件。具有二氮杂三苯环结构的一般式（1）化合物被用作至少一个有机层的构成材料，在该有机层中包括一对电极和夹在一对电极之间的一个或多个有机层的有机电致发光器件中。
• Compound having diazatriphenylene ring structure, and organic electroluminescent device
  申请人：HODOGAYA CHEMICAL CO., LTD.

  公开号：US10032995B2

  公开（公告）日：2018-07-24

  A compound that emits fluorescence and delayed fluorescence is provided as a material for an organic electroluminescent device of high efficiency, and an organic photoluminescent device and an organic electroluminescent device of high efficiency and high luminance are provided using this compound. The compound of a general formula (1) having a diazatriphenylene ring structure is used as a constituent material of at least one organic layer in the organic electroluminescent device that includes a pair of electrodes, and one or more organic layers sandwiched between the pair of electrodes.

  提供了一种可发出荧光和延迟荧光的化合物作为高效率有机电致发光器件的材料，并使用该化合物提供了高效率和高亮度的有机光致发光器件和有机电致发光器件。具有重氮三亚苯环结构的通式（1）化合物被用作有机电致发光器件中至少一个有机层的组成材料，该器件包括一对电极，以及夹在这对电极之间的一个或多个有机层。
• Composition, compound, material for organic electroluminescence element, ink composition, organic electroluminescence element, and electronic device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10290815B2

  公开（公告）日：2019-05-14

  A composition or a compound suitable for use in forming the layer of organic EL device by a coating method, a material for organic electroluminescence devices including the composition or the compound, an ink composition including the composition or the compound, an organic electroluminescence device employing the composition or the compound, and an electronic device including the organic electroluminescence device are provided. The compound includes a nitrogen-containing hetero aromatic hydrocarbon group which has a substituent with a specific structure. The composition includes the compound.

  本发明提供了一种适用于通过涂层方法形成有机电致发光器件层的组合物或化合物、一种包括该组合物或化合物的有机电致发光器件材料、一种包括该组合物或化合物的油墨组合物、一种采用该组合物或化合物的有机电致发光器件以及一种包括该有机电致发光器件的电子器件。化合物包括含氮杂芳烃基团，该基团具有具有特定结构的取代基。组合物包括该化合物。
• Organic electroluminescence composition, material for organic electroluminescence element, solution of material for organic electroluminescence element, and organic electroluminescence element
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10833281B2

  公开（公告）日：2020-11-10

  An organic electroluminescence composition including two or more compounds each having a specific structure combining a hole transporting ability and an electron transporting ability; an organic electroluminescence composition including one or more compounds each having a specific structure combining a hole transporting ability and an electron transporting ability and a different compound having an electron transporting skeleton; and a material for organic electroluminescence devices, a solution of a material for organic electroluminescence devices and an organic electroluminescence device, each including the aromatic heterocyclic derivative.

  一种有机电致发光组合物，包括两种或多种化合物，每种化合物都具有结合空穴传输能力和电子传输能力的特定结构；一种有机电致发光组合物，包括一种或多种化合物，每种化合物都具有结合空穴传输能力和电子传输能力的特定结构，以及具有电子传输骨架的不同化合物；以及一种有机电致发光器件材料、一种有机电致发光器件材料的溶液和一种有机电致发光器件，每种材料都包括芳香杂环衍生物。