2,5-bis(aminomethyl)bicyclo[2.2.1]heptane | 2916-26-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2,5-bis(aminomethyl)bicyclo[2.2.1]heptane
• 英文别名: 2,5-bisaminomethyl-bicyclo[2.2.1]heptane；2,5-bisaminomethylbicyclo[2.2.1]heptane；2,5-bis(aminomethyl)-bicyclo[2.2.1]heptane；2,5-bis(aminomethyl)bicyclo [2,2,1]heptane；2,5-norbornane-dimethaneamine；2,5-Bis-aminomethyl-bicyclo<2.2.1>heptan；Bicyclo[2.2.1]heptane-2,5-diyldimethanamine；[5-(aminomethyl)-2-bicyclo[2.2.1]heptanyl]methanamine
• CAS: 2916-26-9
• 化学式: C₉H₁₈N₂
• mdl: MFCD20547677
• 分子量: 154.255
• InChiKey: KEUCYUPOICDBOG-UHFFFAOYSA-N

物化性质

• 沸点：
  248.9±8.0 °C(Predicted)
• 密度：
  0.997±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,5-bis(aminomethyl)bicyclo[2.2.1]heptane 、 苯基缩水甘油醚 在 水杨酸 作用下， 以 乙腈 为溶剂， 以100%的产率得到1-[[5-[[Bis(2-hydroxy-3-phenoxypropyl)amino]methyl]-2-bicyclo[2.2.1]heptanyl]methyl-(2-hydroxy-3-phenoxypropyl)amino]-3-phenoxypropan-2-ol
  参考文献：
  名称：

  Alkoxylated amine and process therefor

  摘要：

  本发明公开了一种可用作汽车清漆和底漆组分的组合物。该组合物包括或是具有以下式子的烷氧基化胺物质(A)[N(R1H)2]pi，其中包括其异构体或混合物。本发明还公开了一种工艺，包括将胺物质与环氧化合物接触在足以生成烷氧基化胺的条件下。此外，本发明还公开了一种可用作涂层组分和底漆的组合物，包括烷氧基化胺和有机聚异氰酸酯。

  公开号：

  US20050159625A1
• 作为产物：
  描述：

  二聚环戊二烯 在 亚磷酸三苯酯 、 氨 、 氢气 、 高效阻聚剂N-NO 作用下， 以 甲醇 、 甲苯 为溶剂， 反应 19.0h， 生成 2,5-bis(aminomethyl)bicyclo[2.2.1]heptane
  参考文献：
  名称：

  PURIFICATION METHOD OF ALDEHYDE COMPOUND

  摘要：

  本发明的醛化合物的纯化方法包括以下步骤：通过向含有醛化合物的反应溶液中加入水和碱性化合物来中和反应溶液，以及蒸馏中和后的反应溶液。其中，该反应溶液是通过在8至10族金属化合物和磷化合物存在下，将以下式（a1）或（a2）所代表的化合物与氢气和一氧化碳反应而得到的。磷化合物由式（R1O）3P表示，碱性化合物是周期表上I族金属的碳酸盐和氢碳酸盐以及II族金属的碳酸盐和氢碳酸盐中至少选择一种。

  公开号：

  US20150291513A1

文献信息

• Compound having silsesquioxane skeleton and its polymer
  申请人：Inagaki Jyun-ichi

  公开号：US20050009982A1

  公开（公告）日：2005-01-13

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, and Q 2 is a group represented by Formula (2) wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, —CH═CR—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in Claim 1.

  本发明涉及一种由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是苯基，可能具有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己基、环己烯基或苯基，其中可选的氢原子可被卤素或具有1至5个碳原子的烷基取代；Q2是由式（2）表示的基团，其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己亚基、1,4-环己烯亚基、具有6至10个碳原子的缩合环基团，为二价基团，或1,4-苯亚基，Z0至Z3独立地为单键、—CH═CR—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。式（1）中的Y1是权利要求1中定义的基团。
• COMPOSITION CONTAINING VINYL-GROUP-CONTAINING COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20160046552A1

  公开（公告）日：2016-02-18

  A composition containing a novel vinyl-group-containing compound. This composition contains a vinyl-group-containing compound represented by general formula (1). In the formula: W 1 and W 2 represent a group represented by general formula (2) (where a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or —S—, R 1 is a single bond or a C1-4 alkylene group, R 2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer equal to 0 or higher), a group represented by general formula (4) (where the ring (Z), X, R 1 , R 2 , and m are as previously stated), a hydroxyl group, or a (meth)acryloyloxy group; rings (Y 1 , Y 2 ) are aromatic hydrocarbon rings; R represents a single bond or a specific divalent group; R 3a and R 3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; and n1 and n2 are integers of 0-4.

  这个组合物包含一种含有新颖乙烯基团的化合物。该组合物包含一个由通式（1）表示的含有乙烯基团的化合物。在该式中：W1和W2代表由通式（2）表示的一个基团（其中环（Z）是芳香烃环，X是一个单键或—S—，R1是一个单键或C1-4烷基基团，R2是特定的取代基团，如一价碳氢化合物，m是大于或等于0的整数），一个由通式（4）表示的基团（其中环（Z）、X、R1、R2和m如前述），一个羟基，或一个（甲基）丙烯酰氧基团；环（Y1、Y2）是芳香烃环；R代表一个单键或一个特定的二价基团；R3a和R3b代表氰基、卤素原子或一价碳氢基团；n1和n2是0-4的整数。
• PROCESS FOR PREPARING A CARBAMATE COMPOUND
  申请人：Yamamoto Yasuhito

  公开号：US20120302782A1

  公开（公告）日：2012-11-29

  There is provided a process for preparing a carbamate compound, which is easy and commercially advantageous in that a carbamate compound can be produced with high yield from an amine compound and a carbonate compound. A process for preparing a carbamate compound which comprises the step of reacting an amine compound which has at least one amino group per molecule wherein the amine compound is selected from the group consisting of an aliphatic amine which may be substituted by an alicyclic group or an aromatic group or which may be interrupted by an alicyclic group or an aromatic group, and an alicyclic amine which may be substituted by an aliphatic group, with a carbonate compound in the presence of at least one organic solvent selected from the group consisting of a saturated cyclic hydrocarbon, an unsaturated cyclic hydrocarbon, and a non-cyclic ether by using a hydrolase.

  提供了一种制备碳酸酯化合物的过程，该过程简单且具有商业优势，因为碳酸酯化合物可以从胺化合物和碳酸酯化合物高产率地生产出来。制备碳酸酯化合物的过程包括以下步骤：在至少每分子含有一个氨基团的胺化合物中选择一种胺化合物，所述胺化合物选自以下组合：可能被脂环族或芳香族取代的脂肪族胺或可能被脂环族或芳香族中断的脂肪族胺，以及可能被脂肪族取代的脂环族胺；将所述胺化合物与碳酸酯化合物在至少选择自饱和环烃、不饱和环烃和非环氧化物的有机溶剂中，在水解酶的作用下反应。
• Method for producing carbamates and method for producing isocyanates
  申请人：——

  公开号：US20030125579A1

  公开（公告）日：2003-07-03

  A method for producing carbamates that enables carbamates to be produced at low costs, with high selectivity and high yield, and in a simple manner, and a method for producing isocyanates that enables isocyanates industrially used to be produced by using the carbamates obtained by the carbamates producing method. Nonaromatic amine selected from the group consisting of aliphatic amine, alicyclic amine, and aralkyl amine is allowed to react with alkylaryl carbonate to thereby produce carbamates. Also, the carbamates thus obtained are thermally decomposed to thereby produce isocyanates. When carbamates are produced in this method, alkyl carbamates can be obtained with high selectivity and at high yield by using simple equipment. Also, when isocyanates are produced in this method, polyisocyanates used industrially as the raw material of polyurethane can be produced in a simple manner and with efficiency.

  一种生产氨基甲酸酯的方法，可以以低成本、高选择性和高收率、简单的方式生产氨基甲酸酯，以及一种生产异氰酸酯的方法，通过使用由氨基甲酸酯生产方法获得的氨基甲酸酯来工业化生产异氰酸酯。从脂肪胺、脂环胺和芳基胺组成的群体中选择非芳香族胺与烷基芳基碳酸酯反应，从而生产氨基甲酸酯。此外，通过热分解所获得的氨基甲酸酯可以生产异氰酸酯。在这种方法中生产氨基甲酸酯时，可以通过使用简单设备以高选择性和高收率获得烷基氨基甲酸酯。此外，在这种方法中生产异氰酸酯时，可以以简单方式和高效率生产作为聚氨酯原料的工业用多异氰酸酯。
• METHOD FOR TREATMENT OF ISOCYANATE RESIDUE, AND METHOD FOR TREATMENT OF CARBONATE
  申请人：Shimokawatoko Yoshiki

  公开号：US20120271067A1

  公开（公告）日：2012-10-25

  A method for treating an isocyanate residue, which comprises carrying out a thermal decomposition reaction of a carbamate that is produced by the reaction among an amine, urea and/or an N-unsubstituted carbamic acid ester and an alcohol to produce a decomposition solution, separating an isocyanate and the alcohol from the decomposition solution to produce the isocyanate residue, and bringing the isocyanate residue into contact with high-pressure/high-temperature water to decompose the isocyanate residue into an amine; and a method for treating a carbonate, which comprises bringing the carbonate into contact with high-pressure/high-temperature water to decompose the carbonate into an alcohol.

  一种处理异氰酸酯残留物的方法，包括进行热分解反应，将胺、尿素和/或一种未取代的N-氨基甲酸酯和醇反应生成的氨基甲酸酯分解为分解液，从分解液中分离出异氰酸酯和醇，产生异氰酸酯残留物，并将异氰酸酯残留物与高压/高温水接触以将异氰酸酯残留物分解为胺；以及一种处理碳酸盐的方法，包括将碳酸盐与高压/高温水接触以将碳酸盐分解为醇。