1-phenylbenzo[f]quinoline | 28707-28-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 1-phenylbenzo[f]quinoline
• 英文别名: 4-Phenyl-5,6-benzochinolin
• CAS: 28707-28-0
• 化学式: C₁₉H₁₃N
• 分子量: 255.319
• InChiKey: HYOBWXQMTIIKEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,2-二溴乙基苯 在 sodium azide 、 zinc trifluoromethanesulfonate 作用下， 以 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 反应 22.0h， 生成 1-phenylbenzo[f]quinoline
  参考文献：
  名称：

  通过C═C和C–N键断裂直接合成带有乙烯基叠氮化物的4-取代喹啉双合成子

  摘要：

  开发了前所未有的锌促进乙烯基叠氮化物选择性裂解的方法，用于合成4-取代的喹啉。在这种转化中，叠氮化乙烯通过一步一步的C═C和C–N键断裂与两个C═C键和一个C═N键形成，起到双重合成子的作用。该反应因其易于接近的底物，高步骤经济性，温和条件以及使用空气作为唯一氧化剂而受到赞赏。

  DOI：

  10.1021/acs.orglett.8b01718

文献信息

• Synthesis of substituted quinolines by the electrophilic cyclization of n-(2-alkynyl)anilines
  作者：Xiaoxia Zhang、Tuanli Yao、Marino A. Campo、Richard C. Larock

  DOI：10.1016/j.tet.2009.12.012

  日期：2010.2

  A wide variety of substituted quinolines are readily synthesized under mild reaction conditions by the 6-endo-dig electrophilic cyclization of N-(2-alkynyl)anilines by ICl, I2, Br2, PhSeBr, and p-O2NC6H4SCl. The reaction affords 3-halogen-, selenium- and sulfur-containing quinolines in moderate to good yields in the presence of various functional groups. Analogous quinolines bearing a hydrogen in the

  通过 ICl、I 2、Br 2、PhSeBr 和p -O 2 NC 6 H对N -(2-炔基)苯胺进行6-内位亲电环化，可以在温和的反应条件下轻松合成各种取代的喹啉。4 SCl。该反应在各种官能团存在下以中等至良好的产率提供含3-卤素、硒和硫的喹啉。通过Hg(OTf) 2催化这些相同的炔基苯胺的闭环，已经合成了在3-位带有氢的类似喹啉。
• Organic metal complex, and organic light emitting device and display apparatus using the same
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US10367156B2

  公开（公告）日：2019-07-30

  Provided is an organic metal complex having a structure represented by the following general formula (1): MLmL′n  (1) where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L′, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure MLm represents a structure represented by the following general formula (2): and a partial structure ML′n represents a structure including a monovalent bidentate ligand.

  本发明提供了一种具有以下通式 (1) 所代表结构的有机金属络合物： MLmL′n (1) 其中M 代表选自 Ir、Pt、Rh、Os 和 Zn 的金属原子；L 和 L′互不相同，各自代表双齿配体；m 代表 1 至 3 的整数，n 代表 0 至 2 的整数，条件是 m+n 为 3；部分结构 MLm 代表由以下通式（2）表示的结构： 而局部结构 ML′n 表示包括一价双叉配体的结构。
• ORGANIC METAL COMPLEX, AND ORGANIC LIGHT EMITTING DEVICE AND DISPLAY APPARATUS USING THE SAME
  申请人：Kamatani Jun

  公开号：US20100219407A1

  公开（公告）日：2010-09-02

  Provided is an organic metal complex having a structure represented by the following general formula (1): ML m L′ n (1) where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L′, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure ML m represents a structure represented by the following general formula (2): and a partial structure ML′ n represents a structure including a monovalent bidentate ligand.
• US9554442B2
  申请人：——

  公开号：US9554442B2

  公开（公告）日：2017-01-24
• [EN] ORGANIC METAL COMPLEX, AND ORGANIC LIGHT EMITTING DEVICE AND DISPLAY APPARATUS USING THE SAME<br/>[FR] COMPLEXE ORGANOMÉTALLIQUE ET DISPOSITIF ORGANIQUE ÉMETTANT DE LA LUMIÈRE ET APPAREIL D'AFFICHAGE UTILISANT CELUI-CI
  申请人：CANON KK

  公开号：WO2009060995A1

  公开（公告）日：2009-05-14

  Provided is an organic metal complex having a structure represented by the following general formula (1): MLmL'n (1) where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L', which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m + n is 3; a partial structure MLm represents a structure represented by the following general formula (2): and a partial structure ML'n represents a structure including a monovalent bidentate ligand.