2-(3,7-dimethyl-octa-2,6-dienyl)-4-methoxy-phenol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-(3,7-dimethyl-octa-2,6-dienyl)-4-methoxy-phenol
• 英文别名: 2-(3,7-Dimethylocta-2,6-dienyl)-4-methoxyphenol
• 化学式: C₁₇H₂₄O₂
• 分子量: 260.376
• InChiKey: MABMJUYMGMQGEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  芳樟醇 、 4-甲氧基苯酚 在 aluminum oxide 作用下， 以 1,2-二氯乙烷 为溶剂， 以33 %的产率得到2-(3,7-dimethyl-octa-2,6-dienyl)-4-methoxy-phenol
  参考文献：
  名称：

  [EN] PROCESSES FOR THE PREPARATION OF ORTHO-ALLYLATED HYDROXY PHENYL COMPOUNDS
  [FR] PROCÉDÉS DE PRÉPARATION DE COMPOSÉS HYDROXYPHÉNYLE ORTHO-ALLYLÉS

  摘要：

  The present application describes process for preparing an ortho-allylated hydroxy aryl compounds such as compounds of Formula (I) by reacting an allylic alcohol with a hydroxy aryl compound in the presence of aluminum compound selected from alumina and aluminum alkoxides and in a non-protic solvent wherein at least one carbon atom ortho to the hydroxy group in the hydroxy aryl compound is unsubstituted.

  公开号：

  WO2022266765A1

文献信息

• [EN] PROCESSES FOR THE PREPARATION OF ORTHO-ALLYLATED HYDROXY PHENYL COMPOUNDS<br/>[FR] PROCÉDÉS DE PRÉPARATION DE COMPOSÉS HYDROXYPHÉNYLE ORTHO-ALLYLÉS
  申请人：[en]MCMASTER UNIVERSITY

  公开号：WO2022266765A1

  公开（公告）日：2022-12-29

  The present application describes process for preparing an ortho-allylated hydroxy aryl compounds such as compounds of Formula (I) by reacting an allylic alcohol with a hydroxy aryl compound in the presence of aluminum compound selected from alumina and aluminum alkoxides and in a non-protic solvent wherein at least one carbon atom ortho to the hydroxy group in the hydroxy aryl compound is unsubstituted.