Bicyclo<2,2,1>hept-2-yl-methylisocyanat | 14370-51-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Bicyclo<2,2,1>hept-2-yl-methylisocyanat
• 英文别名: 2-isocyanatomethyl-norbornane；norbornan-2-ylmethyl isocyanate；2-(Isocyanatomethyl)bicyclo[2.2.1]heptane
• CAS: 14370-51-5
• 化学式: C₉H₁₃NO
• 分子量: 151.208
• InChiKey: XFYBHCVFEYLVFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  29.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Bicyclo<2,2,1>hept-2-yl-methylisocyanat 、 3-methyl-isoxazole-5-carboxylic acid 4-sulfamoyl-phenethylamide 在 potassium carbonate 作用下， 以 丁酮 为溶剂， 生成 3-methyl-isoxazole-5-carboxylic acid 4-[(norbornan-2-ylmethyl-carbamoyl)-sulfamoyl]-phenethylamide
  参考文献：
  名称：

  Pluempe; Horstmann; Puls, Arzneimittel-Forschung/Drug Research, 1974, vol. 24, # 0, p. 363 - 374

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(bicyclo[2.2.1]heptan-2-yl)acetamide 在 PTC sodium hydroxide 、 溴 作用下， 生成 Bicyclo<2,2,1>hept-2-yl-methylisocyanat
  参考文献：
  名称：

  通过两相霍夫曼反应合成脂族异氰酸酯

  摘要：

  描述了一种使用相转移催化剂通过两相霍夫曼反应制备脂族异氰酸酯的简便方法。

  DOI：

  10.1016/0040-4039(80)80008-6

文献信息

• PURIFICATION METHOD OF ALDEHYDE COMPOUND
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20150291513A1

  公开（公告）日：2015-10-15

  The purification method of an aldehyde compound of the present invention includes a step of neutralizing a reaction solution containing an aldehyde compound by adding water and a base compound to the reaction solution, and a step of distilling the neutralized reaction solution, in which the reaction solution is obtained by reacting a compound represented by the following Formula (a1) or (a2) with hydrogen and carbon monoxide in the presence of a metal compound of groups 8 to 10 and a phosphorus compound, the phosphorus compound is represented by Formula (R 1 O) 3 P, and the base compound is at least one kind selected from among carbonate and hydrogen carbonate of metals of group I on the periodic table and carbonate and hydrogen carbonate of metals of group II on the periodic table.

  本发明的醛化合物的纯化方法包括以下步骤：通过向含有醛化合物的反应溶液中加入水和碱性化合物来中和反应溶液，以及蒸馏中和后的反应溶液。其中，该反应溶液是通过在8至10族金属化合物和磷化合物存在下，将以下式（a1）或（a2）所代表的化合物与氢气和一氧化碳反应而得到的。磷化合物由式（R1O）3P表示，碱性化合物是周期表上I族金属的碳酸盐和氢碳酸盐以及II族金属的碳酸盐和氢碳酸盐中至少选择一种。
• SILANE-BASED COMPOUNDS AND PHOTOSENSITIVE RESIN COMPOSITION COMPRISING THE SAME
  申请人：CHO Changho

  公开号：US20130034814A1

  公开（公告）日：2013-02-07

  The present application relates to a new silane-based compound, a photosensitive resin composition including the same, and a photosensitive material including the same. The photosensitive resin composition including the silane-based compound according to the exemplary embodiment of the present application increases adhesion strength to a substrate, such that a developing property is excellent and there are no surface stains or defects during a subsequent process. Accordingly, a photosensitive material, a color filter and the like having excellent quality may be manufactured by using the photosensitive resin composition according to the exemplary embodiment of the present application.

  本申请涉及一种基于硅烷的新化合物，包括该化合物的感光树脂组合物，以及包括该化合物的感光材料。根据本申请示例实施方式的含硅烷基化合物的感光树脂组合物增加了与基材的粘附强度，使得显影性能优良，在随后的过程中没有表面污渍或缺陷。因此，通过使用根据本申请示例实施方式的感光树脂组合物可以制造出具有优良质量的感光材料、彩色滤光片等。
• CATALYSTS FOR THE SYNTHESIS OF OXAZOLIDINONE COMPOUNDS
  申请人：Covestro Deutschland AG

  公开号：US20170088659A1

  公开（公告）日：2017-03-30

  The present invention relates to a method for the production of oxazolidinone compounds with low colour intensity, comprising the step of reacting an isocyanate compound with an epoxide compound in the presence of a catalyst which is free of halide anions. The invention further relates to a method for the production of oligooxazolidinone and/or polyoxazolidinone compounds, comprising the step of reacting a polyisocyanate compound with a polyepoxide compound in the presence of said catalyst. The invention further relates to oligooxazolidinone and/or polyoxazolidinone compounds with low colour intensity, obtainable by a method according to the invention.

  本发明涉及一种生产低颜色强度的噁唑烷酮化合物的方法，包括在无卤化物阴离子的催化剂存在下，将异氰酸酯化合物与环氧化合物反应的步骤。该发明还涉及一种生产寡噁唑烷酮和/或聚噁唑烷酮化合物的方法，包括在所述催化剂存在下，将聚异氰酸酯化合物与聚环氧化合物反应的步骤。该发明还涉及通过本发明方法获得的低颜色强度的寡噁唑烷酮和/或聚噁唑烷酮化合物。
• SILANE-MODIFIED FORMAMIDES
  申请人：Covestro Deutschland AG

  公开号：US20160340372A1

  公开（公告）日：2016-11-24

  The invention relates to novel silane-modified formamide-polymers and/or pre-polymers for bonding and/or sealing diverse substrate materials, such as, for example metal, wood, glass and/or plastic. The invention also relates to a reactive single-component adhesive system comprising the claimed silane-modified formamide polymers.

  该发明涉及用于粘接和/或密封不同基材的新型硅烷改性甲酰胺聚合物和/或前聚物，例如金属、木材、玻璃和/或塑料。该发明还涉及一种包括所述硅烷改性甲酰胺聚合物的反应性单组分粘合系统。
• Functionalized Photoinitiators
  申请人：Dietliker Kurt

  公开号：US20080021126A1

  公开（公告）日：2008-01-24

  The invention relates to novel photoinitiators of formula (I) wherein each of the substituents is given the definition as set forth in the Specification and the claims. The photoinitiators can be used to prepare multifunctional photoinitiators.

  该发明涉及公式（I）中的新型光引发剂，其中每个取代基的定义如规范和索赔中所述。这些光引发剂可用于制备多功能光引发剂。