dimethyloctadecylfluorosilane | 80054-55-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: dimethyloctadecylfluorosilane
• 英文别名: octadecylfluorodimethylsilane；Silane, fluorodimethyloctadecyl-；fluoro-dimethyl-octadecylsilane
• CAS: 80054-55-3
• 化学式: C₂₀H₄₃FSi
• 分子量: 330.645
• InChiKey: NKPBVPYFLVCLFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.42
• 重原子数：
  22
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  二甲基十八烷基氯硅烷 在 氢氟酸 作用下， 生成 dimethyloctadecylfluorosilane
  参考文献：
  名称：

  Chemical characterization of bonded stationary phases for high-performance liquid chromatography using hydrofluoric acid digestion and gas chromatography

  摘要：

  DOI：

  10.1021/ac00285a014

文献信息

• Nucleophilic fluorination of alkoxysilane with alkali metal hexafluorophosphate—part 1
  作者：Omar Farooq

  DOI：10.1016/s0022-1139(97)00112-7

  日期：1997.12

  Alkali metal hexafluorophosphates were used to effect nucleophilic fluorination of a few selected alkoxysilanes both in the presence and absence of polar solvents. Near-quantitative yields of fluorinated silanes were obtained using both alkoxy-equivalent of the complex salt and fluoride equivalents of alkoxysilanes. Some of the intermediate fluorosilanes and fluorophosphorus compounds were identified and the mechanism of fluorination is proposed. (C) 1997 Elsevier Science S.A.
• Farooq, Omar, Journal of the Chemical Society. Perkin transactions I, 1998, # 4, p. 661 - 665
  作者：Farooq, Omar

  DOI：——

  日期：——
• Chemical characterization of bonded stationary phases for high-performance liquid chromatography using hydrofluoric acid digestion and gas chromatography
  作者：Steven D. Fazio、Sterling A. Tomellini、Shih Hsien. Hsu、Jonathan B. Crowther、Thomas V. Raglione、Thomas R. Floyd、Richard A. Hartwick

  DOI：10.1021/ac00285a014

  日期：1985.7.1