nerol isopropyl ether | 83320-39-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: nerol isopropyl ether
• 英文别名: Nerol isopropylether；(2Z)-3,7-dimethyl-1-propan-2-yloxyocta-2,6-diene
• CAS: 83320-39-2
• 化学式: C₁₃H₂₄O
• 分子量: 196.333
• InChiKey: ITQOWFLOOIUZRC-LCYFTJDESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  橙花醇 、 异丙醇 在 氢气 作用下， 生成 香茅醇 、 nerol isopropyl ether
  参考文献：
  名称：

  碳载铱催化剂上柠檬醛的加氢

  摘要：

  柠檬醛（3,7-二甲基-2,6-辛二烯醛）的氢化在常压氢气压力和 70°C 下在具有不同金属负载量的 Sibunit（介孔碳）负载的铱催化剂上在间歇反应器中进行。主要产物为香叶醇和橙花醇的异丙醚（以2-丙醇为溶剂），还生成香叶醇、橙花醇、香茅醛二异丙基缩醛和香茅醛。金属颗粒尺寸由 CO 化学吸附确定，范围为 2 至 6 nm。加氢反应的周转频率随着金属粒径的增加而增加。图形摘要作为粒径函数的氢化反应的周转频率。

  DOI：

  10.1007/s10562-012-0809-1

文献信息

• Processes to form ethylene-based polymers using asymmetrical polyenes
  申请人：Dow Global Technologies LLC

  公开号：US10005863B2

  公开（公告）日：2018-06-26

  A process to form an ethylene-based polymer including polymerizing ethylene and at least one asymmetrical polyene comprising an “alpha, beta unsaturated-carbonyl end” (“α,β unsaturated-carbonyl end”) and a “C—C double bond end,” wherein the polymerization takes place in the presence of at least one free-radical initiator; and wherein the polymerization takes place in a reactor configuration comprising at least two reaction zones, reaction zone 1 and reaction zone i (i≥2), wherein reaction zone i is downstream from reaction zone 1.

  一种形成乙烯基聚合物的工艺，包括使乙烯和至少一种不对称聚烯聚合，该不对称聚烯包括 "α、β不饱和羰基端"（"α、β不饱和羰基端"）和 "C-C双键端"，其中聚合在至少一种自由基引发剂存在下进行；聚合在反应器配置中进行，反应器配置包括至少两个反应区，即反应区1和反应区i（i≥2），其中反应区i位于反应区1的下游。
• ETHYLENE-BASED POLYMERS AND PROCESSES FOR THE SAME
  申请人：Dow Global Technologies LLC

  公开号：US20150197590A1

  公开（公告）日：2015-07-16

  The invention provides an ethylene-based polymer formed from reacting at least the following: ethylene and at least one asymmetrical polyene, comprising an “alpha, beta unsaturated end” and a “C—C double bond end,” and wherein the reaction takes place in the presence of at least one free-radical initiator.
• Inhibitor Combination for Lithium Salt-Catalyzed Transesterification Process and Method for Removing Lithium Salt
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：US20160297736A1

  公开（公告）日：2016-10-13

  A process to form a composition comprising an asymmetrical polyene, the asymmetrical polyene comprising an “α,β unsaturated-carbonyl end” and a “C—C double bond end,” the process comprising: reacting an alkene- or polyene-containing alcohol with an alkyl ester of an α,β unsaturated carboxylic acid in the presence of at least the following components A) through C) to form a solution comprising an asymmetrical polyene: A) a lithium salt; B) a component selected from the group consisting of hydroquinone, an alkyl-substituted phenol, a substituted alkyl-substituted phenol, an alkyl-substituted hydroquinone, a substituted alkyl-substituted hydroquinone, and combinations thereof; and C) an N-oxyl-containing compound; wherein the “α,β unsaturated-carbonyl end” of the asymmetrical polyene is selected from the group consisting of structures a) through c), as described herein, and wherein the “C—C double bond end” of the asymmetrical polyene is selected from the group consisting of structures 1) through 17), as described herein.
• Processes to Form Ethylene-Based Polymers Using Asymmetrical Polyenes
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：US20160297904A1

  公开（公告）日：2016-10-13

  A process to form an ethylene-based polymer including polymerizing ethylene and at least one asymmetrical polyene comprising an “alpha, beta unsaturated-carbonyl end” (“α,β unsaturated-carbonyl end”) and a “C—C double bond end,” wherein the polymerization takes place in the presence of at least one free-radical initiator; and wherein the polymerization takes place in a reactor configuration comprising at least two reaction zones, reaction zone 1 and reaction zone i (i≧2), wherein reaction zone i is downstream from reaction zone 1.
• PROCESSES TO IMPROVE REACTOR STABILITY FOR THE PREPARATION OF ETHYLENE-BASED POLYMERS USING ASYMMETRICAL POLYENES
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：US20160304643A1

  公开（公告）日：2016-10-20

  The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene and at least one asymmetrical polyene, comprising an “alpha, beta unsaturated—carbonyl end” and a “C—C double bond end,” and wherein the polymerization takes place in the presence of at least one free-radical initiator, and wherein the polymerization takes place in a reactor configuration comprising at least two reaction zones, reaction zone 1 and reaction zone i (i≧2), wherein reaction zone i is downstream from reaction zone 1; and wherein at least one chain transfer agent (CTA) is added to the polymerization, and wherein the CTA is a saturated hydrocarbon or an unsaturated hydrocarbon.