Tetracyclo-<6.2.1.1^3,6,0^2,7>dodec-9-en-4-ol | 7388-87-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Tetracyclo-<6.2.1.1^3,6,0^2,7>dodec-9-en-4-ol
• 英文别名: 2-Hydroxy-1,2,3,4,4a,5,8,8a-octahydro-1,4,5,8-dimethanonaphthalin；1,2,3,4,4A,5,8,8A-Octahydro-1,4:5,8-dimethano-2-naphthol；tetracyclo[6.2.1.13,6.02,7]dodec-9-en-4-ol
• CAS: 7388-87-6
• 化学式: C₁₂H₁₆O
• 分子量: 176.258
• InChiKey: MFZJGMQSIBNILS-UHFFFAOYSA-N

物化性质

• 熔点：
  87-88 °C
• 沸点：
  285.7±39.0 °C(Predicted)
• 密度：
  1.205±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-Acetoxy-1,2,3,4,4a,5,8,8a-octahydro-1,4,5,8-dimethanonaphthalin 、 1,4-二氧六环 、 氢氧化钾 、 草酸二水合物 在 氮气 、 水 、 甲苯 作用下， 以 水 为溶剂， 反应 4.0h， 以to obtain 8-hydroxytetracyclo [4.4.0.12,5.17,10]dodec-3-ene of the following formula (14) at an yield of 95%的产率得到Tetracyclo-<6.2.1.1^3,6,0^2,7>dodec-9-en-4-ol
  参考文献：
  名称：

  US06180316B2

  摘要：

  公开号：

文献信息

• CYCLIC OLEFIN POLYMER, OPTICAL MATERIAL, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY
  申请人：WATANABE Saisuke

  公开号：US20080299329A1

  公开（公告）日：2008-12-04

  A cyclic olefin polymer is provided and includes a repeating unit represented by formula (1A) and a repeating unit represented by the formula (1B): R 1 and R 3 each independently represents a substituent, L 1 and L 2 each independently represents a single bond or a divalent linking group, m and p each independently represents an integer of 0 or 1, and n and q each independently represents an integer of 1 to 4; and A represents COOR 2 or OCOR 2 , and R 2 represents a linear alkyl group having a carbon number of 1 to 10. The cyclic olefin polymer has a copolymerization ratio of x and y satisfying 0.03≦y/(x+y)≦0.50, a number average molecular weight of from 70,000 to 300,000, and a weight average molecular weight of from 200,000 to 700,000.

  提供了一种环状烯烃聚合物，包括由公式（1A）表示的重复单元和由公式（1B）表示的重复单元：R1和R3各自独立地表示取代基，L1和L2各自独立地表示单键或二价连接基，m和p各自独立地表示0或1的整数，n和q各自独立地表示1到4的整数；A表示COOR2或OCOR2，R2表示具有1到10个碳原子的线性烷基。该环状烯烃聚合物具有x和y的共聚比满足0.03≦y/(x+y)≦0.50，数量平均分子量为70,000至300,000，重量平均分子量为200,000至700,000。
• PREPARATION OF KETONE CONTAINING CYCLIC COMPOUNDS
  申请人：SABIC Innovative Plastics IP B.V.

  公开号：EP1732969B1

  公开（公告）日：2011-02-23
• Cyclic Olefin-Based Polymer, and Optical Material, Polarizing Plate and Liquid Crystal Display Device Using the Same
  申请人：Suzuki Ryo

  公开号：US20090040436A1

  公开（公告）日：2009-02-12

  A cyclic olefin-based polymer containing a repeating unit represented by formula (1), an optical material containing the cyclic olefin-based polymer, a polarizing plate containing the optical material, and a liquid crystal display device containing the polarizing plate: in which R 1 represents a substituent; L represents a single bond or a divalent linking group, and forms an alcohol together with the —OH group; p represents an integer of 0 or 1; q represents an integer of from 0 to 3; r represents an integer of from 1 to 4; and R 1 and L may be combined with each other to form a 5- to 7-membered ring.
• US6080791A
  申请人：——

  公开号：US6080791A

  公开（公告）日：2000-06-27
• US7393907B2
  申请人：——

  公开号：US7393907B2

  公开（公告）日：2008-07-01