Bis-(2-hydroxyoctyl)-sulfid | 26073-89-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Bis-(2-hydroxyoctyl)-sulfid
• 英文别名: 1-(2-Hydroxyoctylsulfanyl)octan-2-ol
• CAS: 26073-89-2
• 化学式: C₁₆H₃₄O₂S
• 分子量: 290.511
• InChiKey: NDUBAHRRGMVVPL-UHFFFAOYSA-N

物化性质

• 沸点：
  426.7±20.0 °C(Predicted)
• 密度：
  0.960±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  65.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,2-环氧辛烷 在 三苯基硅烷硫醇 、 四丁基氟化铵 、 caesium carbonate 、 溶剂黄146 作用下， 生成 Bis-(2-hydroxyoctyl)-sulfid 、 1-巯基-2-苯基-2-羟基乙烷
  参考文献：
  名称：

  Triphenylsilanethiol: A solid H2S equivalent in the ring opening of epoxides

  摘要：

  Triphenylsilanethiol, a white crystalline solid, can be used in the opening of epoxides to form 8-hydroxymercaptans or beta-dihydroxysulfides.

  DOI：

  10.1016/s0040-4039(00)79156-8

文献信息

• P-MENTHANE-3,8-DIOL ISOMER MIXTURE, COOLING SENSATION COMPOSITION COMPRISING THE SAME, AND PRODUCT COMPRISING THE COOLING SENSATION COMPOSITION
  申请人：Komatsuki Yasuhiro

  公开号：US20140219931A1

  公开（公告）日：2014-08-07

  The present invention relates to a p-menthane-3,8-diol isomer mixture 50% by mass or more of which is constituted of (1S)-isomers and a cooling sensation composition containing this mixture. The present invention also relates to a flavor and/or fragrance composition, food, beverage, cosmetic, daily use product, oral cavity composition, or pharmaceutical containing the p-menthane-3,8-diol isomer mixture in an amount of 0.0001 to 90% by mass.

  本发明涉及一种p-薄荷烷-3,8-二醇异构体混合物，其中50%或更多的质量由(1S)-异构体构成，以及含有该混合物的冷感组合物。本发明还涉及一种口味和/或香料组合物、食品、饮料、化妆品、日常用品、口腔组合物或药物，其中p-薄荷烷-3,8-二醇异构体混合物的质量占0.0001至90%。
• P-MENTHANE-3,8-DIOL ISOMER MIXTURE, COMPOSITION COMPRISING THE SAME, AND PRODUCTS COMPRISING THE MIXTURE OR COMPOSITION
  申请人：TAKASAGO INTERNATIONAL CORPORATION

  公开号：US20130136704A1

  公开（公告）日：2013-05-30

  An object of the present invention is to provide a novel technology for preventing crystal precipitation of p-menthane-3,8-diol, and stable products utilizing this technology. Provided is a p-menthane-3,8-diol isomer mixture, wherein the mass ratio of cis isomers:trans isomers in terms of the relative configuration at Positions 3 and 4 is 55:45 to 45:55. Also provided are stable products and the like containing the p-menthane-3,8-diol isomer mixture.

  本发明的目的是提供一种防止对薄荷醇-3,8-二醇结晶沉淀的新技术，以及利用该技术稳定的产品。提供的是一种对薄荷醇-3,8-二醇异构体混合物，其中相对于3号和4号位置的相对构型的顺式异构体：反式异构体的质量比为55:45至45:55。还提供了含有对薄荷醇-3,8-二醇异构体混合物的稳定产品等。
• Pest repellent and pest repelling methods
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0888716A1

  公开（公告）日：1999-01-07

  This invention provides a pest repellent of the type which may be applied either directly to the skin or to another location, such as a building or plant, from which the pests are to be repelled. The repellent contains hyssop oil as an active ingredient, and is especially useful against bloodsucking insects such as mosquitoes and flies. The invention also provides pest repelling methods using hyssop or hyssop oil.

  本发明提供了一种害虫驱避剂，它可以直接涂抹在皮肤上，也可以涂抹在建筑物或植物等其他需要驱赶害虫的地方。这种驱虫剂含有牛膝草油作为活性成分，特别适用于蚊子和苍蝇等吸血昆虫。本发明还提供了使用牛膝草或牛膝草油的驱虫方法。
• Fabric protectant against pests
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP0937399A1

  公开（公告）日：1999-08-25

  A fabric protectant comprising a carrier and a plant oil selected from the group consisting of horseradish oil, bay oil, basil oil, calamus oil, ginger oil, palmarosa oil, cinnamon oil, ylang-ylang oil, perilla oil, valerian oil, clove oil, star anise oil, milfoil oil, fennel oil, oregano oil and angelica oil, efficaciously controls fabric-related pests. In addition, a method of protecting fabric which comprises dispersing, spraying, spreading and setting an effective amount of the plant oil selected from the group given above onto a fabric is an excellent method to control fabric-related pests.

  一种织物保护剂由载体和植物油组成，植物油选自辣根油、月桂油、罗勒油、菖蒲油、生姜油、香薷油、肉桂油、依兰油、紫苏油、缬草油、丁香油、八角茴香油、小米草油、茴香油、牛至油和当归油，可有效控制与织物有关的害虫。此外，一种保护织物的方法，包括在织物上分散、喷洒、涂抹和设置有效量的植物油，也是一种防治织物害虫的好方法。
• Fabric protectants against pests
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP0962140A1

  公开（公告）日：1999-12-08

  Fabric protectants are provided that efficaciously control pests that have a partiality of consuming fabric materials (e.g., certain moths). By providing for 2,3,5,6-tetrafluoro-4-methylbenzyl 3-(2-chloro-2-fluorovinyl)-2,2-dimethylcyclopropanecarboxylate, or an isomer thereof, as an active ingredient therein, a fabric protectant of the invention typically withholds the transfer of odors from the provided fabric protectant to the treated fabric material, restrains undesired alterations in the colors of fabric materials caused by the provided fabric protectant, controls said pests that have a partiality to consume such fabric materials with rapid action and provides a residual effect over such pests that are associated with fabric materials.

  所提供的织物保护剂能有效地控制偏食织物材料的害虫（如某些飞蛾）。通过提供 2,3,5,6-四氟-4-甲基苄基 3-(2-氯-2-氟乙烯基)-2,2-二甲基环丙烷羧酸酯或其异构体作为其中的活性成分，本发明的织物保护剂通常可以阻止气味从所提供的织物保护剂转移到经过处理的织物材料上、抑制由所提供的织物保护剂引起的织物材料颜色的不良变化，以快速作用控制偏爱食用此类织物材料的害虫，并对与织物材料相关的害虫提供残留效果。