isobornyl acrylate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: isobornyl acrylate
• 英文别名: [(1S,4R)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl] prop-2-enoate
• 化学式: C₁₃H₂₀O₂
• 分子量: 208.301
• InChiKey: PSGCQDPCAWOCSH-NDAPUWOLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetraethylammonium bis[α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O]phenyldimethylsilylsilicate 、 isobornyl acrylate 在 [Ir(dF(CF₃)ppy)₂(dtbbpy)](PF₆) 作用下， 以 甲醇 、 丙酮 为溶剂， 以89 %的产率得到(1S,2S,4S)-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl 3-(dimethyl(phenyl)silyl)propanoate
  参考文献：
  名称：

  使用五配位甲硅烷基硅酸盐作为甲硅烷基自由基前体的光催化 C-Si 键形成：使用旧试剂的合成技巧

  摘要：

  通过揭示 Martin 的螺硅烷衍生的五配位甲硅烷基硅酸盐作为甲硅烷基自由基前体的反应性，揭示了可见光诱导的光催化 C-Si 形成策略。已经证明了广谱烯烃和炔烃的氢化硅烷化，以及杂芳烃的 C-H 硅烷化。值得注意的是，Martin 的螺硅烷非常稳定，可以通过简单的后处理过程回收。此外，使用水作为溶剂或低能量绿色 LED 作为替代能源，反应进行得很好。

  DOI：

  10.1021/acs.orglett.3c00096

文献信息

• Vitamin B₁₂‐Photocatalyzed Cyclopropanation of Electron‐Deficient Alkenes Using Dichloromethane as the Methylene Source**
  作者：John Hayford G. Teye‐Kau、Mayokun J. Ayodele、Spencer P. Pitre

  DOI：10.1002/anie.202316064

  日期：2024.1.8

  We report a vitamin B12-photocatalyzed strategy for the cyclopropanation of electron-deficient alkenes using dichloromethane (CH2Cl2) as the methylene source. The reaction has excellent functional group tolerance, is highly chemoselective, and the scope can be extended to other 1,1-dichloroalkanes for the preparation of D2-cyclopropyl and methyl-substituted cyclopropyl adducts, all of which are important

  我们报告了一种使用二氯甲烷 (CH 2 Cl 2 ) 作为亚甲基源进行缺电子烯烃环丙烷化的维生素 B 12光催化策略。该反应具有优异的官能团耐受性，化学选择性高，范围可扩展到其他1,1-二氯烷烃，用于制备D 2 -环丙基和甲基取代环丙基加合物，这些都是医学化学中重要的电子等排体。
• ULTRAVIOLET-CURABLE PRESSURE-SENSITIVE SILICONE ADHESIVE COMPOSITION AND CURED OBJECT OBTAINED THEREFROM
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3636723A1

  公开（公告）日：2020-04-15

  An ultraviolet-curable pressure-sensitive silicone adhesive composition which comprises: 100 parts of an organopolysiloxane (A) having, in the molecule, two groups represented by general formula (1) (wherein R1 represents a C1-20 monovalent hydrocarbon group, R2 represents an oxygen atom, etc., R3 represents an acryloyloxyalkyl group, etc., p and a respectively indicate numbers satisfying 0 ≤ p ≤ 10 and 1 ≤ a ≤ 3); 1-500 parts of a monofunctional (meth)acrylate compound (B) containing no siloxane structure and/or a polyfunctional (meth)acrylate compound (C) containing no siloxane structure; 1-5,000 parts of an oranopolysiloxane resin (D) comprising R43SiO1/2 units (a) (wherein R4 represents a C1-10 monovalent hydrocarbon group) and Si04/2 units (b), the (a)/(b) molar ratio being (0.6-1.2)/1; and 0.01-20 parts of a photopolymerization initiator (E). This composition has satisfactory applicability and curability and gives a cured object which, when used as a temporary fixer, has excellent tackiness and strength.

  一种紫外线固化压敏型硅胶粘合剂组合物，它包括100 份的有机聚硅氧烷（A），其分子中有两个由通式（1）表示的基团 (其中 R1 代表 C1-20 单价烃基，R2 代表氧原子等，R3 代表丙烯酰氧基烷基等、p 和 a 分别表示满足 0≤p≤10 和 1≤a≤3 的数字）；1-500 份不含硅氧烷结构的单官能度（甲基）丙烯酸酯化合物（B）和/或不含硅氧烷结构的多官能度（甲基）丙烯酸酯化合物（C）；1-5,000 份包含 R43SiO1/2 单元(a)（其中 R4 代表 C1-10 单价烃基）和 Si04/2 单元(b)的兰聚硅氧烷树脂 (D)，(a)/(b)摩尔比为 (0.6-1.2）/1；以及 0.01-20 份的光聚合引发剂（E）。这种组合物具有令人满意的适用性和固化性，其固化物在用作临时固定剂时，具有极佳的粘性和强度。
• Ultraviolet-curable pressure-sensitive silicone adhesive composition and cured object obtained therefrom
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US11124680B2

  公开（公告）日：2021-09-21

  An ultraviolet-curable pressure-sensitive silicone adhesive composition which comprises: 100 parts of an organopolysiloxane (A) having, in the molecule, two groups represented by general formula (1) (wherein R1 represents a C1-20 monovalent hydrocarbon group, R2 represents an oxygen atom, etc., R3 represents an acryloyloxyalkyl group, etc., p and a respectively indicate numbers satisfying 0≤p≤10 and 1≤a≤3); 1-500 parts of a monofunctional (meth)acrylate compound (B) containing no siloxane structure and/or a polyfunctional (meth)acrylate compound (C) containing no siloxane structure; 1-5,000 parts of an oranopolysiloxane resin (D) comprising R43SiO1/2 units (a) (wherein R4 represents a C1-10 monovalent hydrocarbon group) and SiO4/2 units (b), the (a)/(b) molar ratio being (0.6-1.2)/1; and 0.01-20 parts of a photopolymerization initiator (E). This composition has satisfactory applicability and curability and gives a cured object which, when used as a temporary fixer, has excellent tackiness and strength.

  一种紫外线固化压敏型硅胶粘合剂组合物，它包括100 份的有机聚硅氧烷（A），其分子中有两个由通式（1）表示的基团 (其中 R1 代表 C1-20 单价烃基，R2 代表氧原子等，R3 代表丙烯酰氧基烷基等、p 和 a 分别表示满足 0≤p≤10 和 1≤a≤3 的数字）；1-500 份不含硅氧烷结构的单官能度（甲基）丙烯酸酯化合物 (B) 和/或不含硅氧烷结构的多官能度（甲基）丙烯酸酯化合物 (C)；1-5,000 份包含 R43SiO1/2 单元(a)（其中 R4 代表 C1-10 单价烃基）和 SiO4/2 单元(b)的兰聚硅氧烷树脂 (D)，(a)/(b)摩尔比为 (0.6-1.2）/1；以及 0.01-20 份的光聚合引发剂（E）。这种组合物具有令人满意的适用性和固化性，其固化物在用作临时固定剂时，具有极佳的粘性和强度。
• THERMOSETTING COMPOSITION, METHOD FOR MANUFACTURING MOLDED ARTICLE USING THE SAME, AND CURED PRODUCT
  申请人：IDEMITSU KOSAN CO.,LTD.

  公开号：US20210171683A1

  公开（公告）日：2021-06-10

  A thermosetting composition comprising the following components (A-1), (A-2), (B), and (C), and having the viscosity of 5 to 200 Pa·s at a shear rate of 10 s −1 at 25° C., and having the viscosity of 1 to 50 Pa·s at a shear rate of 100 s −1 at 25° C., as measured by JIS K7117-2: (A-1) an acrylate compound or a methacrylate compound in which a substituted or unsubstituted alicyclic hydrocarbon group including 6 or more ring carbon atoms is ester-bonded, (A-2) a compound represented by the following formula (I-1), (B) a spherical silica, (C) a white pigment.
• [EN] QUANTUM DOT FILM COMPRISING QUANTUM DOT COMPOSITE, AND WAVELENGTH CONVERSION SHEET FOR DISPLAY<br/>[FR] FILM À POINTS QUANTIQUES COMPRENANT UN COMPOSITE DE POINTS QUANTIQUES, ET FEUILLE DE CONVERSION DE LONGUEUR D'ONDE POUR AFFICHAGE<br/>[KO] 양자점 복합체를 포함하는 양자점 필름, 및 디스플레이용 파장변환 시트
  申请人：INNO QD CO LTD

  公开号：WO2021034104A1

  公开（公告）日：2021-02-25

  본 발명은 매트릭스 수지 내 양자점을 균일하게 분산시켜 양자점 효율이 향상되고, 캡슐화를 통해 양자점의 열화를 방지할 수 있는 양자점 복합체 및 이를 포함하는 양자점 필름, 및 디스플레이용 파장변환 시트에 관한 것이다.