4,7-bis[4-(trifluoromethyl)phenyl]-1,10-phenanthroline | 1349174-59-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 4,7-bis[4-(trifluoromethyl)phenyl]-1,10-phenanthroline
• CAS: 1349174-59-9
• 化学式: C₂₆H₁₄F₆N₂
• 分子量: 468.401
• InChiKey: KTRYUUDCXZSXDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  34
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  4,7-二氯-1,10-菲咯啉 、 对溴三氟甲苯 在 正丁基锂 、 zinc(II) chloride 、 四(三苯基膦)钯 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 12.0h， 以59%的产率得到4,7-bis[4-(trifluoromethyl)phenyl]-1,10-phenanthroline
  参考文献：
  名称：

  芳族硼酸与苯衍生物通过均相芳族取代进行铁催化的氧化偶联。

  摘要：

  Fe（OTf）（3）-1,10-菲咯啉使用t-BuOOt-Bu作为氧化剂催化芳基硼酸与苯衍生物的氧化偶联。该反应通过用芳基硼酸和t-BuO产生的芳基进行均相芳族取代而进行。

  DOI：

  10.1039/c1cc14694g
• 作为试剂：
  描述：

  苯 、 苯硼酸 在 iron(III) trifluoromethanesulfonate 、 二叔丁基过氧化物 、 4,7-bis[4-(trifluoromethyl)phenyl]-1,10-phenanthroline 作用下， 反应 24.0h， 以72%的产率得到联苯
  参考文献：
  名称：

  芳族硼酸与苯衍生物通过均相芳族取代进行铁催化的氧化偶联。

  摘要：

  Fe（OTf）（3）-1,10-菲咯啉使用t-BuOOt-Bu作为氧化剂催化芳基硼酸与苯衍生物的氧化偶联。该反应通过用芳基硼酸和t-BuO产生的芳基进行均相芳族取代而进行。

  DOI：

  10.1039/c1cc14694g

文献信息

• Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents
  作者：Zijia Wang、Motomu Kanai、Yoichiro Kuninobu

  DOI：10.1021/acs.orglett.7b00923

  日期：2017.5.5

  Iron-catalyzed acyloxyalkylation of styrene derivatives using hypervalent iodine reagents was achieved. The acyloxyalkylation reaction proceeded using various types of styrenes and hypervalent iodine reagents. The acyloxyalkylated products were obtained in moderate to good yields without loss of the functional groups. The reaction proceeded via the formation of radical species derived from hypervalent

  使用高价碘试剂实现了铁衍生物对苯乙烯衍生物的铁催化酰氧基烷基化。酰氧基烷基化反应使用各种类型的苯乙烯和高价碘试剂进行。以中等至良好的产率获得了酰氧基烷基化的产物，而没有损失官能团。反应通过脱羧形成衍生自高价碘试剂的自由基物质而进行。
• VERTICALLY PHASE-SEPARATING SEMICONDUCTING ORGANIC MATERIAL LAYERS
  申请人：Brown Christopher T.

  公开号：US20130009137A1

  公开（公告）日：2013-01-10

  Improved OLED devices and methods of making the same using vertical phase separation to simplify processing. Vertically phase separated material can include at least one lower first layer disposed on the electrode, and at least one upper second layer different from the first layer and disposed away from the electrode or optionally on one layer comprising at least one semiconducting organic material. The first layer can be enriched with at least one first semiconducting organic material (SOM 1) and the second layer can be enriched with at least one second semiconducting organic material (SOM 2) different from the SOM 1. The ink composition can be adapted so that the film vertically phase separates into the first and second layers. Compositions and devices are also embodied herein.
• US9397294B2
  申请人：——

  公开号：US9397294B2

  公开（公告）日：2016-07-19
• [EN] VERTICALLY PHASE-SEPARATING SEMICONDUCTING ORGANIC MATERIAL LAYERS<br/>[FR] COUCHES DE MATÉRIAU ORGANIQUE SEMI-CONDUCTEUR À SÉPARATION DE PHASE VERTICALE
  申请人：PLEXTRONICS INC

  公开号：WO2013006478A1

  公开（公告）日：2013-01-10

  Improved OLED devices and methods of making the same using vertical phase separation to simplify processing. Vertically phase separated material can include at least one lower first layer disposed on the electrode, and at least one upper second layer different from the first layer and disposed away from the electrode or optionally on one layer comprising at least one semiconducting organic material. The first layer can be enriched with at least one first semiconducting organic material (SOM 1) and the second layer can be enriched with at least one second semiconducting organic material (SOM 2) different from the SOM 1. The ink composition can be adapted so that the film vertically phase separates into the first and second layers. Compositions and devices are also embodied herein.
• Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution
  作者：Nanase Uchiyama、Eiji Shirakawa、Ryo Nishikawa、Tamio Hayashi

  DOI：10.1039/c1cc14694g

  日期：——

  Fe(OTf)(3)-1,10-phenanthroline catalyzes oxidative coupling of arylboronic acids with benzene derivatives using t-BuOOt-Bu as an oxidant. The reaction proceeds through homolytic aromatic substitution with aryl radicals generated from arylboronic acids and t-BuO .

  Fe（OTf）（3）-1,10-菲咯啉使用t-BuOOt-Bu作为氧化剂催化芳基硼酸与苯衍生物的氧化偶联。该反应通过用芳基硼酸和t-BuO产生的芳基进行均相芳族取代而进行。