1,1,1-trifluoro-2,2-bis(p-tolyl)ethane | 384-95-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1,1,1-trifluoro-2,2-bis(p-tolyl)ethane
• 英文别名: 1,1,1-trifluoro-2,2-di-p-tolyl-ethane；1,1,1-Trifluor-2,2-di-p-tolyl-aethan；1,1,1-Trifluoro-2,2-bis(4-methylphenyl)ethane；1-methyl-4-[2,2,2-trifluoro-1-(4-methylphenyl)ethyl]benzene
• CAS: 384-95-2
• 化学式: C₁₆H₁₅F₃
• 分子量: 264.29
• InChiKey: RYEIJUCQNBAUHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 磷化氢 、 碘 、 溶剂黄146 作用下， 生成 1,1,1-trifluoro-2,2-bis(p-tolyl)ethane
  参考文献：
  名称：

  Synthesis and Biological Properties of Diaryl-(trifluoromethyl)-carbinols

  摘要：

  DOI：

  10.1021/ja01620a064

文献信息

• HOLLOW FIBER, DOPE SOLUTION COMPOSITION FOR FORMING A HOLLOW FIBER, AND METHOD FOR MANUFACTURING A HOLLOW FIBER USING THE SAME
  申请人：IUCF-HYU (Industry-University Cooperation Foundation Hanyang University)

  公开号：EP2281926A2

  公开（公告）日：2011-02-09

  Disclosed is a hollow fiber that includes a hollow positioned at the center of the hollow fiber, macropores positioned at adjacent to the hollow, and mesopores and picopores positioned at adjacent to macropores, and the picopores are three dimensionally connected to each other to form a three dimensional network structure. The hollow fiber includes a polymer derived from polyimide, and the polyimide includes a repeating unit obtained from aromatic diamine including at least one ortho-positioned functional group with respect to an amine group and dianhydride.

  本发明公开了一种中空纤维，该纤维包括位于中空纤维中心的中空、位于中空相邻位置的大孔、以及位于大孔相邻位置的中孔和微孔，微孔彼此三维连接以形成三维网络结构。中空纤维包括由聚酰亚胺衍生的聚合物，聚酰亚胺包括由芳香族二胺衍生的重复单元，芳香族二胺包括至少一个与胺基和二酸酐正交定位的官能团。
• CELL CULTURE SUBSTRATE CONTAINING FLUORINE-CONTAINING POLYMER ON SURFACE
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP3135752A1

  公开（公告）日：2017-03-01

  This invention provides a cell culture substrate comprising on its surface a fluorine-containing polymer that enables three-dimensional tissue culture. The cell culture substrate of the invention has a surface at least a part of which is composed of a resin composition comprising a fluorine-containing polymer having one or more fluorine atoms in a repeating unit and exhibits the oxygen gas permeability of 219 cm3 (STP)/(m2·24h·atm) or higher. Three-dimensional tissue can be formed via cell culture with the use of the cell culture substrate of the invention.

  本发明提供了一种细胞培养基质，其表面由含氟聚合物组成，可进行三维组织培养。本发明的细胞培养基底的表面至少有一部分是由树脂组合物构成的，该树脂组合物包括在重复单元中含有一个或多个氟原子的含氟聚合物，其氧气透过率为 219 cm3 (STP)/(m2-24h-atm) 或更高。使用本发明的细胞培养基底，可通过细胞培养形成三维组织。
• Condensations of aryl trifluoromethyl ketones with arenes in acidic media
  作者：Matthew J. O’Connor、Kenneth N. Boblak、Ashley D. Spitzer、Peter A. Gucciardo、Andrew M. Baumann、Joshua W. Peter、Connie Y. Chen、Ronald Peter、Adam A. Mitton、Douglas A. Klumpp

  DOI：10.1016/j.tetlet.2010.07.067

  日期：2010.9

  The chemistry of trifluoromethyl ketones has been studied. The work examines the condensation reactions of trifluoromethyl ketones with arenes in the superacid, including both synthetic and mechanistic aspects. (C) 2010 Elsevier Ltd. All rights reserved.
• Fluoroanalogs of DDT: Superacidic BF₃–H₂O Catalyzed Facile Synthesis of 1,1,1-Trifluoro-2,2-diarylethanes and 1,1-Difluoro-2,2-diarylethanes
  作者：G. K. Surya Prakash、Farzaneh Paknia、Thomas Mathew、Gzregorz Mlostoń、Jens P. Joschek、George A. Olah

  DOI：10.1021/ol201669a

  日期：2011.8.5

  The one-pot synthesis of 1,1,1-trifluoro- and 1,1-difluoro-2,2-diarylethanes from arenes and fluorinated hemiacetals in the BF3-H2O system is described. The reaction is simple, clean, and convenient, eliminating the use of organic solvents and other expensive acid systems. BF3-H2O is economic, is easy to prepare, and offers ample acidity required for this reaction.
• Retardation film, method for manufacturing retardation film, method for manufacturing laminated retardation film, optical film, and image display apparatus
  申请人：Shutou Shunsuke

  公开号：US20070134441A1

  公开（公告）日：2007-06-14

  The present invention provides a retardation film on which birefringent layers having different alignment directions can be formed directly. A surface of a polymer film showing birefringence is irradiated with polarized light so as to change an alignment direction of only the surface of the film to be different from an alignment direction of an inside of the film, thereby manufacturing a retardation film having the surface that is processed into an alignment surface. Since this film is a retardation film that also functions as an alignment film, if a liquid crystal layer is formed directly on the alignment surface and is aligned, the birefringent layer having the alignment direction that is different from the alignment direction of the retardation film can be formed on the retardation film.