N,N-双十三烷基十三烷-1-胺 | 5910-77-0

• 物质功能分类: 有机原料 - 氨基化合物
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N-双十三烷基十三烷-1-胺
• 中文别名: 乙酮,1-(2,5,6-三氯-1H-吲哚-3-基)-
• 英文名称: tri(tridecyl)amine
• 英文别名: N,N-ditridecyltridecan-1-amine；Tris(tridecyl)amine；N,N-di(tridecyl)tridecan-1-amine
• CAS: 5910-77-0
• 化学式: C₃₉H₈₁N
• 分子量: 564.079
• InChiKey: GDSGXRQXKTWBOS-UHFFFAOYSA-N

物化性质

• 熔点：
  26.85°C (estimate)
• 沸点：
  529.88°C (rough estimate)
• 密度：
  0.9133 (estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  18.6
• 重原子数：
  40
• 可旋转键数：
  36
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  氰十二烷 在 palladium on activated charcoal 氢气 作用下， 生成 N,N-双十三烷基十三烷-1-胺
  参考文献：
  名称：

  Kindler,K.; Luehrs,K., Justus Liebigs Annalen der Chemie, 1967, vol. 707, p. 26 - 34

  摘要：

  DOI：

文献信息

• ABUSE DETERRENT AND ANTI-DOSE DUMPING PHARMACEUTICAL SALTS USEFUL FOR THE TREATMENT OF ATTENTION DEFICIT/HYPERACTIVITY DISORDER
  申请人：King Clifford Riley

  公开号：US20120028960A1

  公开（公告）日：2012-02-02

  A pharmaceutical composition comprising a drug substance consisting essentially of a pharmaceutically acceptable organic acid addition salt of an amine containing pharmaceutically active compound wherein the amine containing pharmaceutical active compound is selected from the group consisting of racemic or single isomer ritalinic acid or phenethylamine derivatives and the drug substance has a physical form selected from amorphous and polymorphic.

  一种药物组合物，包括基本上由含有药用活性化合物的胺的药用可接受的有机酸加合盐组成的药物物质，其中含有药用活性化合物的胺被选择自光学异构体或单异构体利他林酸或苯乙胺衍生物的群体，并且该药物物质具有从无定形到多型的物理形式。
• PROCESS FOR PREPARING FORMIC ACID BY REACTING CARBON DIOXIDE WITH HYDROGEN
  申请人：Schaub Thomas

  公开号：US20120157711A1

  公开（公告）日：2012-06-21

  The present invention relates to a process for preparing formic acid by reacting carbon dioxide ( 1 ) with hydrogen ( 2 ) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where a tertiary amine having a boiling point which is at least 5° C. higher than that of formic acid is used and a reaction mixture comprising the polar solvent, the formic acid/amine adducts, the tertiary amine and the catalyst is formed in the reaction in the hydrogenation reactor (I) and is discharged from the reactor as output ( 3 ).

  本发明涉及一种制备甲酸的方法，通过在氢化反应器（I）中，在存在一种催化剂，该催化剂包含周期表第8、9或10族元素，一种含有每个分子至少12个碳原子的三级胺和一种极性溶剂，所述极性溶剂包括从甲醇、乙醇、丙醇和丁醇中选择的一种或多种单醇，将二氧化碳（1）与氢气（2）反应，形成甲酸/胺加合物作为中间体，随后进行热解离，其中使用沸点比甲酸高至少5°C的三级胺，反应混合物包括极性溶剂、甲酸/胺加合物、三级胺和催化剂，在氢化反应器（I）中形成，并作为输出（3）从反应器中排出。
• PROCESS FOR PREPARING FORMIC ACID BY REACTION OF CARBON DIOXIDE WITH HYDROGEN
  申请人：Schaub Thomas

  公开号：US20110319658A1

  公开（公告）日：2011-12-29

  A process for preparing formic acid by reaction of carbon dioxide ( 1 ) with hydrogen ( 2 ) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols and also water, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, with work-up of the output ( 3 ) from the hydrogenation reactor (I) in a plurality of process steps, where a tertiary amine-comprising stream ( 13 ) from the work-up is used as selective solvent for the catalyst, is proposed.

  一种制备甲酸的方法，通过在氢化反应器（I）中，在周期表第8、9或10族元素组成的催化剂存在下，将二氧化碳（1）与氢（2）反应，以及包含每个分子至少12个碳原子的三级胺和包括甲醇、乙醇、丙醇和丁醇中的一种或多种单醇以及水的极性溶剂，形成甲酸/胺加合物作为中间体，随后进行热解离，并通过多个工艺步骤处理来自氢化反应器（I）的产物（3），其中工艺步骤中使用来自工艺处理的三级胺组成流（13）作为催化剂的选择性溶剂。
• Process for Preparing Formic Acid by Reaction of Carbon Dioxide with Hydrogen
  申请人：Schaub Thomas

  公开号：US20120022290A1

  公开（公告）日：2012-01-26

  A process for preparing formic acid by reaction of carbon dioxide ( 1 ) with hydrogen ( 2 ) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where the work-up of the output ( 3 ) from the hydrogenation reactor (I) is carried out by addition of water so as to increase the distribution coefficient of the catalyst between the upper phase ( 4 ) and the lower phase.

  一种通过在氢化反应器（I）中，在元素8、9或10族的催化剂的存在下，将二氧化碳（1）与氢气（2）反应制备甲酸的方法，所述催化剂包括至少每分子含有12个碳原子的三级胺和由甲醇、乙醇、丙醇和丁醇中选择的一种或多种单醇组成的极性溶剂，以形成甲酸/胺加合物作为中间体，随后通过热解离合成甲酸，其中通过添加水进行氢化反应器（I）的产物（3）的处理，以增加催化剂在上相（4）和下相之间的分配系数。
• PROCESS FOR PREPARING FORMIC ACID
  申请人：Schneider Daniel

  公开号：US20130190532A1

  公开（公告）日：2013-07-25

  Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid, tertiary amine (I) and water is produced by combining tertiary amine (I) and a formic acid source in the presence of water, water and organic decomposition products of the tertiary amine (I) are removed and formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, wherein the stream comprising water and organic decomposition products of the tertiary amine (I) which have been separated off is separated into two liquid phases, the upper liquid phase is removed and the lower, water-comprising liquid phase is recirculated to the formic acid source.

  通过热分离获得甲酸的过程，其中包括甲酸和三级胺（I）的流体，通过将三级胺（I）和甲酸源在水的存在下结合以产生包含甲酸、三级胺（I）和水的液体流，去除水和三级胺（I）的有机分解产物，并通过蒸馏从所得液体流中去除甲酸，在蒸馏设备中分离出含有水和三级胺（I）的有机分解产物的流体，将分离出的上层液相移除，下层含水液相循环回甲酸源。