2,6-di-tert-butyl-9,10-bis(9-hexyloxy-9H-fluoren-9-yl)anthracene | 1242278-85-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2,6-di-tert-butyl-9,10-bis(9-hexyloxy-9H-fluoren-9-yl)anthracene
• 英文别名: 2,6-Ditert-butyl-9,10-bis(9-hexoxyfluoren-9-yl)anthracene；2,6-ditert-butyl-9,10-bis(9-hexoxyfluoren-9-yl)anthracene
• CAS: 1242278-85-8
• 化学式: C₆₀H₆₆O₂
• 分子量: 819.183
• InChiKey: BYHCZWKUMXLDLI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.5
• 重原子数：
  62
• 可旋转键数：
  16
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  溴己烷 、 9,9'-(2,6-di-tert-butylanthracene-9,10-diyl)bis(9H-fluoren-9-ol) 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以76%的产率得到2,6-di-tert-butyl-9,10-bis(9-hexyloxy-9H-fluoren-9-yl)anthracene
  参考文献：
  名称：

  C-9 Fluorenyl Substituted Anthracenes: A Promising New Family of Blue Luminescent Materials

  摘要：

  Syntheses, optical, and electrochemical properties of novel C-9 fluorenyl substituted anthracenes linked by a tetrahedral sp(3)-hybridized carbon atom are reported for blue light emitting materials. Remarkably, an unoptimized organic light-emitting diode based on 1-fold fluorene-functionalized anthracene 3 exhibits a radiance of 4100 cd/m(2) at 12 V and a maximum EL efficiency of 1.36 cd/A with color purity CIE x, y (0.157, 0.082), which is very close to the National Television System Committee standard blue.

  DOI：

  10.1021/ol101553a

文献信息

• C-9 Fluorenyl Substituted Anthracenes: A Promising New Family of Blue Luminescent Materials
  作者：Jing Wang、Wen Wan、Haizhen Jiang、Yan Gao、Xueyin Jiang、Huaping Lin、Weiming Zhao、Jian Hao

  DOI：10.1021/ol101553a

  日期：2010.9.3

  Syntheses, optical, and electrochemical properties of novel C-9 fluorenyl substituted anthracenes linked by a tetrahedral sp(3)-hybridized carbon atom are reported for blue light emitting materials. Remarkably, an unoptimized organic light-emitting diode based on 1-fold fluorene-functionalized anthracene 3 exhibits a radiance of 4100 cd/m(2) at 12 V and a maximum EL efficiency of 1.36 cd/A with color purity CIE x, y (0.157, 0.082), which is very close to the National Television System Committee standard blue.