1-methylcyclodecene | 13151-64-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 1-methylcyclodecene
• 英文别名: (Z)-1-methyl-cyclodecene；Cyclodecene, 1-methyl-；(1Z)-1-methylcyclodecene
• CAS: 13151-64-9
• 化学式: C₁₁H₂₀
• 分子量: 152.28
• InChiKey: AAZWWRDLCYIVAB-LUAWRHEFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-methylcyclodecene 生成 (Z)-2-Methyl-12-oxo-tridec-2-enoic acid ethyl ester
  参考文献：
  名称：

  Some deoxygenation reactions with low-valent titanium (titanium trichloride/lithium tetrahydroaluminate)

  摘要：

  DOI：

  10.1021/jo00411a001
• 作为产物：
  描述：

  环癸酮 在 二乙二醇二甲醚 、 氢溴酸 、 苯基锂 作用下， 以 乙醚 、 溶剂黄146 为溶剂， 生成 1-methylcyclodecene
  参考文献：
  名称：

  Addition Reactions with Methylenecyclodecane^1a,b

  摘要：

  DOI：

  10.1021/jo01056a049

文献信息

• η³-Allylpalladium Complexes from Medium-Ring Cycloalkenes
  作者：Jean-Marie Rosset、Matthew P. Glenn、John D. Cotton、Anthony C. Willis、Colin H. L. Kennard、Karl A. Byriel、Bruce H. Riches、William Kitching

  DOI：10.1021/om971132c

  日期：1998.5.1

  The dimeric eta(3)-allylpalladium chloride complexes formed from various cycloalkenes (C-7-C-13) and some methyl-and tert-butyl-substituted cycle alkenes have be en characterized by H-1 and C-13 NMR spectroscopy and in selected cases by X-ray crystallography. The formation of syn and anti isomers in the larger ring systems is demonstrated, and complexes with a rearranged ring system are formed from tert-butylcyclodecene and tert-butylcyclododecene. The sesquiterpene, carophyllene, is shown to form an eta(3)-allyl exocyclic complex, exclusively from the (E)-double bond. Cis and trans isomers, with respect to allyl group orientation in these halo-bridged dimers, have been identified by low-temperature (190K) NMR spectroscopy, and their interconversion (Delta G(double dagger) approximate to 11 kcal/mol) is considered to involve a "cubic" eta(3)-allylpalladium chloride tetramer.
• Amine Oxides. VIII. Medium-sized Cyclic Olefins from Amine Oxides and Quaternary Ammonium Hydroxides^1,2
  作者：Arthur C. Cope、Engelbert Ciganek、Charles F. Howell、Edward E. Schweizer

  DOI：10.1021/ja01502a053

  日期：1960.9

  Thermal decompositions of the N-oxides derived from N,N-dimethyl-1-methylcycloalk,lamines II having eight-, nine- and ten-membered rings yield olefin mixtures containing 98.6, 94.0 and 97.5%, respectively, of 1-methylcycloalkenes. Considerable amounts of the trans isomers are formed from the nine- and ten-membered N-oxides. Pyrolyses of the corresponding quaternary hydroxides produce mixtures of methylenecycloalkanes and 1-methylcycloalkenes (predominantly cis), violation of the Hofmann rule being at a maximum in the decomposition of the nine-membered quaternary hydroxide. Importance of relative product stabilities and the operation of non-bonded interactions are discussed as possible explanations for the observed directions of elimination. Thermal decompositions of the N-oxides and quaternary hydroxides of dimethylcycloalkvimethylamines IV containing eight-, nine- and ten-membered rings proceed as expected with formation of the corresponding methylenecycloalkanes.