trans-1-Methyl-cyclodecen-(1) | 66633-38-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: trans-1-Methyl-cyclodecen-(1)
• 英文别名: Cyclodecene, 1-methyl-, (E)-；1-methylcyclodecene
• CAS: 66633-38-3
• 化学式: C₁₁H₂₀
• 分子量: 152.28
• InChiKey: AAZWWRDLCYIVAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  环癸酮 在 二乙二醇二甲醚 、 氢溴酸 、 苯基锂 作用下， 以 乙醚 、 溶剂黄146 为溶剂， 生成 trans-1-Methyl-cyclodecen-(1)
  参考文献：
  名称：

  Addition Reactions with Methylenecyclodecane^1a,b

  摘要：

  DOI：

  10.1021/jo01056a049

文献信息

• Amine Oxides. VIII. Medium-sized Cyclic Olefins from Amine Oxides and Quaternary Ammonium Hydroxides^1,2
  作者：Arthur C. Cope、Engelbert Ciganek、Charles F. Howell、Edward E. Schweizer

  DOI：10.1021/ja01502a053

  日期：1960.9

  Thermal decompositions of the N-oxides derived from N,N-dimethyl-1-methylcycloalk,lamines II having eight-, nine- and ten-membered rings yield olefin mixtures containing 98.6, 94.0 and 97.5%, respectively, of 1-methylcycloalkenes. Considerable amounts of the trans isomers are formed from the nine- and ten-membered N-oxides. Pyrolyses of the corresponding quaternary hydroxides produce mixtures of methylenecycloalkanes and 1-methylcycloalkenes (predominantly cis), violation of the Hofmann rule being at a maximum in the decomposition of the nine-membered quaternary hydroxide. Importance of relative product stabilities and the operation of non-bonded interactions are discussed as possible explanations for the observed directions of elimination. Thermal decompositions of the N-oxides and quaternary hydroxides of dimethylcycloalkvimethylamines IV containing eight-, nine- and ten-membered rings proceed as expected with formation of the corresponding methylenecycloalkanes.
• A New Fragmentation Reaction. The Synthesis of 1-Methyl-trans,trans-1,6-cyclodecadiene
  作者：James A. Marshall、Gordon L. Bundy

  DOI：10.1021/ja00970a053

  日期：1966.9
• Addition Reactions with Methylenecyclodecane^1a,b
  作者：James G. Traynham、William C. Baird

  DOI：10.1021/jo01056a049

  日期：1962.9

表征谱图