dihydrosporogen AO-1 | 122605-15-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: dihydrosporogen AO-1
• 英文别名: (1aS,2S,6R,7R,7aR,7bR)-7,7a-dimethyl-1a-prop-1-en-2-yl-2,4,5,6,7,7b-hexahydronaphtho[1,2-b]oxirene-2,6-diol
• CAS: 122605-15-6
• 化学式: C₁₅H₂₂O₃
• 分子量: 250.338
• InChiKey: CHWPMFMUQATVNK-IUCIJCHOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  53
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  dihydrosporogen AO-1 、 苯甲酰氯 生成 [(1aS,2S,6R,7R,7aR,7bR)-2-benzoyloxy-7,7a-dimethyl-1a-prop-1-en-2-yl-2,4,5,6,7,7b-hexahydronaphtho[1,2-b]oxiren-6-yl] benzoate
  参考文献：
  名称：

  KONO, YOSHIKI;GARDNER, J. M.;SUZUKI, YOSHIKATSU;KONDO, HIDEAKI;TAKEUCHI, +, NIXON NOYAKU GAKKAJSI, 14,(1989) N, S. 223-228

  摘要：

  DOI：

文献信息

• Eremophilane-type sesquiterpenes from cultured lichen mycobionts of Sarcographa tricosa
  作者：Duy Hoang Le、Yukiko Takenaka、Nobuo Hamada、Takao Tanahashi

  DOI：10.1016/j.phytochem.2012.01.009

  日期：2013.7

  Spore-derived mycobionts of the crustose lichen Sarcographa tricosa were cultivated on a malt-yeast extract medium supplemented with 10% sucrose. Chemical investigation of the cultivated colonies led to isolation of three eremophilane-type sesquiterpenes, 3-epi-petasol (1), dihydropetasol (2) and sarcographol (3), together with six known eremophilanes and ergosterol peroxide. These structures were elucidated by spectroscopic and chemical methods. This is the first report of eremophilane-type sesquiterpenes from the cultured mycobionts of lichen. (C) 2012 Elsevier Ltd. All rights reserved.