Acetic acid (2S,3S,4R,5R,6R)-5-((2S,3R,4R,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-3-acetylamino-tetrahydro-pyran-2-yloxy)-6-methoxy-2-methyl-4-((3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl ester | 101528-55-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Acetic acid (2S,3S,4R,5R,6R)-5-((2S,3R,4R,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-3-acetylamino-tetrahydro-pyran-2-yloxy)-6-methoxy-2-methyl-4-((3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl ester
• CAS: 101528-55-6
• 化学式: C₃₇H₅₃NO₂₃
• 分子量: 879.821
• InChiKey: JFKKIVCWULARBD-KDBFILCTSA-N

物化性质

• 沸点：
  850.0±65.0 °C(Predicted)
• 密度：
  1.36±0.1 g/cm3(Predicted)

反应信息

• 作为反应物：
  描述：

  Acetic acid (2S,3S,4R,5R,6R)-5-((2S,3R,4R,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-3-acetylamino-tetrahydro-pyran-2-yloxy)-6-methoxy-2-methyl-4-((3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl ester 在 sodium methylate 作用下， 以 甲醇 为溶剂， 以52%的产率得到methyl 2-O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-3-O-α-D-glucopyranosyl-α-L-rhamnopyranoside
  参考文献：
  名称：

  Wessel, Hans-Peter; Bundle, David R., Journal of the Chemical Society. Perkin transactions I, 1985, p. 2251 - 2260

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸酐 、 methyl 2-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-3-O-(α/β-D-glucopyranosyl)-α-L-rhamnopyranoside 以 吡啶 为溶剂， 反应 18.0h， 以90%的产率得到Acetic acid (2S,3S,4R,5R,6R)-5-((2S,3R,4R,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-3-acetylamino-tetrahydro-pyran-2-yloxy)-6-methoxy-2-methyl-4-((3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl ester
  参考文献：
  名称：

  Wessel, Hans-Peter; Bundle, David R., Journal of the Chemical Society. Perkin transactions I, 1985, p. 2251 - 2260

  摘要：

  DOI：