Ethyl O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1->3)-O-<(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1->6)>-O-(2,4-di-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4,6-tri-O-acetyl-1-thio-α-D-glucopyranoside | 154410-75-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Ethyl O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1->3)-O-<(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1->6)>-O-(2,4-di-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4,6-tri-O-acetyl-1-thio-α-D-glucopyranoside
• 英文别名: ethyl O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1<*>3)-O-<2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl-(1<*>6)>-O-(2,4-di-O-acetyl-β-D-glucopyranosyl)-(1<*>3)-2,4,6-tri-O-acetyl-1-thio-α-D-glucopyranoside
• CAS: 154410-75-0
• 化学式: C₅₂H₇₂O₃₃S
• 分子量: 1257.19
• InChiKey: FBFNCYROSQPJHZ-PGDTXRLYSA-N

物化性质

• 沸点：
  1008.5±65.0 °C(predicted)
• 密度：
  1.40±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  Ethyl O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1->3)-O-<(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1->6)>-O-(2,4-di-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4,6-tri-O-acetyl-1-thio-α-D-glucopyranoside 在 4 A molecular sieve 、 四乙基溴化铵 、 溴 、 氰化汞 作用下， 以 甲苯 为溶剂， 反应 2.33h， 生成 allyl O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1<*>3)-O-<2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl-(1<*>6)>-O-(2,4-di-O-acetyl-β-D-glucopyranosyl)-(1<*>3)-2,4,6-tri-O-acetyl-β-D-glucopyranoside
  参考文献：
  名称：

  Takeo, Kenichi; Kawaguchi, Masaki; Kitamura, Shinichi, Journal of Carbohydrate Chemistry, 1993, vol. 12, # 8, p. 1043 - 1056

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸酐 、 在 吡啶 作用下， 反应 1.0h， 生成 Ethyl O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1->3)-O-<(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1->6)>-O-(2,4-di-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4,6-tri-O-acetyl-1-thio-α-D-glucopyranoside
  参考文献：
  名称：

  Takeo, Kenichi; Kawaguchi, Masaki; Kitamura, Shinichi, Journal of Carbohydrate Chemistry, 1993, vol. 12, # 8, p. 1043 - 1056

  摘要：

  DOI：

文献信息

• Takeo, Kenichi; Nagayoshi, Kimiko; Nishimura, Kenichi, Journal of Carbohydrate Chemistry, 1994, vol. 13, # 8, p. 1159 - 1178
  作者：Takeo, Kenichi、Nagayoshi, Kimiko、Nishimura, Kenichi、Kitamura, Shinichi

  DOI：——

  日期：——