| 1148107-16-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1148107-16-7
• 化学式: C₁₃H₂₅IO₄
• 分子量: 372.244
• InChiKey: FJNNDTNSJJDVAV-UHFFFAOYSA-N

物化性质

• 沸点：
  349.1±42.0 °C(predicted)
• 密度：
  1.37±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  、 在 正丁基锂 、 四甲基乙二胺 作用下， 以 苯 、 四氢呋喃 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  A selective resin for trans-diequatorial-1,2-diols

  摘要：

  A selective resin for linking trans-diequatorial-1,2-diols to solid support is described. This linking was carried out under mild and aprotic conditions involving the use of trimethylsilyl methyl ether in the presence of trimethylsilyl trifluoromethanesulfonate. Cleavage from the resin was also carried out under mild conditions by treatment with dichloromethane/trifluoroacetic acid/water (21:20:1). The usefulness of the described cyclohexane-1,2-diketone resin 7 in quinic acid chemistry was also studied. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.01.157
• 作为产物：
  描述：

  在 咪唑 、 碘 、 三苯基膦 作用下， 以92%的产率得到
  参考文献：
  名称：

  A selective resin for trans-diequatorial-1,2-diols

  摘要：

  A selective resin for linking trans-diequatorial-1,2-diols to solid support is described. This linking was carried out under mild and aprotic conditions involving the use of trimethylsilyl methyl ether in the presence of trimethylsilyl trifluoromethanesulfonate. Cleavage from the resin was also carried out under mild conditions by treatment with dichloromethane/trifluoroacetic acid/water (21:20:1). The usefulness of the described cyclohexane-1,2-diketone resin 7 in quinic acid chemistry was also studied. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.01.157