3'-cyanopropyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside | 1048006-12-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3'-cyanopropyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside
• CAS: 1048006-12-7
• 化学式: C₁₈H₂₅NO₉S
• 分子量: 431.464
• InChiKey: GIOBHDOONWIBKH-ICUGJSFKSA-N

反应信息

• 作为反应物：
  描述：

  3'-cyanopropyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside 在 HOF* CH₃CN 作用下， 以 氯仿 为溶剂， 反应 0.03h， 以62%的产率得到3'-cyanopropyl 2,3,4,6-tetra-O-acetyl-1-sulfonyl-β-D-galactopyranoside
  参考文献：
  名称：

  Application of HOF·CH3CN to the synthesis of glycosyl sulfones

  摘要：

  A fast, complete and clean conversion of thioglycosides into glycosyl sull'ones under mild acidic conditions is described, using the HOF center dot CH3CN complex at room temperature. This methodology affords glycosyl sull'ones in high yields and in excellent purity. (c) 2008 Elsevier Ltd. All rights reserved,

  DOI：

  10.1016/j.tet.2008.05.033
• 作为产物：
  描述：

  2,3,4,6-四-O-乙酰基-1-硫代-BETA-D-吡喃半乳糖 、 alkaline earth salt of/the/ methylsulfuric acid 在 二乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 3'-cyanopropyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside
  参考文献：
  名称：

  Application of HOF·CH3CN to the synthesis of glycosyl sulfones

  摘要：

  A fast, complete and clean conversion of thioglycosides into glycosyl sull'ones under mild acidic conditions is described, using the HOF center dot CH3CN complex at room temperature. This methodology affords glycosyl sull'ones in high yields and in excellent purity. (c) 2008 Elsevier Ltd. All rights reserved,

  DOI：

  10.1016/j.tet.2008.05.033