methyl 4,6-O-benzylidene-2-deoxy-2-morpholino-α-D-altropyranoside | 1607435-20-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: methyl 4,6-O-benzylidene-2-deoxy-2-morpholino-α-D-altropyranoside
• CAS: 1607435-20-0
• 化学式: C₁₈H₂₅NO₆
• 分子量: 351.4
• InChiKey: CUSOSLDIDXAGNG-DXVYANPOSA-N

反应信息

• 作为反应物：
  描述：

  methyl 4,6-O-benzylidene-2-deoxy-2-morpholino-α-D-altropyranoside 在 偶氮二甲酸二异丙酯 、 三苯基膦 、 叠氮磷酸二苯酯 作用下， 以 四氢呋喃 为溶剂， 反应 24.33h， 以69%的产率得到methyl 3-azido-4,6-O-benzylidene-2,3-dideoxy-2-morpholino-α-D-mannopyranoside
  参考文献：
  名称：

  Preparation of new type of organocatalysts having a carbohydrate scaffold

  摘要：

  The synthesis of nine new, bifunctional organocatalysts having carbohydrate scaffolds has been accomplished. In these catalysts both of the catalytic amino and thiourea functions are directly attached to a carbohydrate core. The activities of the newly prepared catalysts were tested in a Michael addition. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2013.12.026
• 作为产物：
  描述：

  吗啉 、 甲基2,3-脱水-4,6-O-亚苄基-Alpha-D-吡喃糖苷 在 lithium perchlorate 作用下， 以 乙腈 为溶剂， 反应 24.0h， 以84%的产率得到methyl 4,6-O-benzylidene-2-deoxy-2-morpholino-α-D-altropyranoside
  参考文献：
  名称：

  Preparation of new type of organocatalysts having a carbohydrate scaffold

  摘要：

  The synthesis of nine new, bifunctional organocatalysts having carbohydrate scaffolds has been accomplished. In these catalysts both of the catalytic amino and thiourea functions are directly attached to a carbohydrate core. The activities of the newly prepared catalysts were tested in a Michael addition. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2013.12.026