Yb(Pdc)3(Phen) | 866957-44-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Yb(Pdc)3(Phen)
• 英文别名: Yb(III)((1,10-phenanthroline)(pyrrolidinedithiocarbamate)3
• CAS: 866957-44-0
• 化学式: C₂₇H₃₂N₅S₆Yb
• 分子量: 792.021
• InChiKey: CYXFGIHUTLYJSP-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Yb(Pdc)3(Phen) 、 氧气 以 neat (no solvent) 为溶剂， 生成 ytterbium(III) oxide
  参考文献：
  名称：

  Application of rotate-bomb calorimeter for determining the standard molar enthalpy of formation of Ln(Pdc)3(Phen)

  摘要：

  Thirteen solid ternary complexes Ln(Pdc)(3)(Phen) (Ln = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu;) have been synthesized in absolute ethanol by rare-earth element chloride low hydrate reacting with the mixed ligands of ammonium pyrrolidinedithiocarbamate (APdc) and 1,10-phenanthroline center dot H2O (o-Phen center dot H2O) in the ordinary laboratory atmosphere without any cautions against moisture or air sensitivity. IR spectra of the complexes showed that the Ln(3+) ion was coordinated with six sulfur atoms of three Pdc(-) and two nitrogen atoms of o-Phen center dot H2O. It was assumed that the coordination number of Ln(3+) is eight. The constant-volume combustion energies of the complexes, Delta U-c, were determined by a precise rotate-bomb calorimeter at 298.15 K. Their standard molar enthalpies of combustion, Delta H-c(m)o, and standard molar enthalpies of formation, Delta H-f(m)o were calculated.

  DOI：

  10.1134/s1070328407030116
• 作为产物：
  描述：

  邻菲罗啉 、 吡咯烷二硫代甲酸铵盐 、 ytterbium(III) chloride hexahydrate 以 乙醇 为溶剂， 生成 Yb(Pdc)3(Phen)
  参考文献：
  名称：

  Application of rotate-bomb calorimeter for determining the standard molar enthalpy of formation of Ln(Pdc)3(Phen)

  摘要：

  Thirteen solid ternary complexes Ln(Pdc)(3)(Phen) (Ln = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu;) have been synthesized in absolute ethanol by rare-earth element chloride low hydrate reacting with the mixed ligands of ammonium pyrrolidinedithiocarbamate (APdc) and 1,10-phenanthroline center dot H2O (o-Phen center dot H2O) in the ordinary laboratory atmosphere without any cautions against moisture or air sensitivity. IR spectra of the complexes showed that the Ln(3+) ion was coordinated with six sulfur atoms of three Pdc(-) and two nitrogen atoms of o-Phen center dot H2O. It was assumed that the coordination number of Ln(3+) is eight. The constant-volume combustion energies of the complexes, Delta U-c, were determined by a precise rotate-bomb calorimeter at 298.15 K. Their standard molar enthalpies of combustion, Delta H-c(m)o, and standard molar enthalpies of formation, Delta H-f(m)o were calculated.

  DOI：

  10.1134/s1070328407030116