5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-pentacosafluorohexadecanol | 129794-51-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-pentacosafluorohexadecanol
• 英文别名: 5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-Pentacosafluorohexadecan-1-ol；5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-pentacosafluorohexadecan-1-ol
• CAS: 129794-51-0
• 化学式: C₁₆H₉F₂₅O
• 分子量: 692.207
• InChiKey: DMDABWSXLNELDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  42
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-pentacosafluorohexadecanol 在 硫酸 、 氢溴酸 、 四丁基硫酸氢铵 作用下， 以 水 、 苯 为溶剂， 反应 16.0h， 以47%的产率得到5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-pentacosafluorohexadecyl bromide
  参考文献：
  名称：

  液晶kagome。

  摘要：

  DOI：

  10.1002/anie.200802957
• 作为产物：
  描述：

  在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 10.0h， 以6.68 g的产率得到5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-pentacosafluorohexadecanol
  参考文献：
  名称：

  液晶kagome。

  摘要：

  DOI：

  10.1002/anie.200802957

文献信息

• LEATHERY SHEET OBJECT, PROCESS FOR PRODUCING THE SAME, AND URETHANE COMPOUND MODIFIED WITH FLUORINATED SIDE CHAIN
  申请人：Teijin Cordley Limited

  公开号：EP1514968A1

  公开（公告）日：2005-03-16

  A leather-like sheet material comprising a sheet material composed of a fiber aggregate and a elastic polymer, the sheet material containing a fluorine-containing side-chain-modified urethane compound which satisfies the following requirements (i) to (iii), (i) said urethane compound containing a urethane-bond-containing compound having a molecular weight of 500 to 5,000 and fluorine-containing side chains having a molecular weight of 200 to 1,000 each, 3 to 12 such fluorine-containing side chains bonding to the urethane-bond-containing compound, (ii) said urethane compound having a fluorine content of 20 to 60 % by weight as a fluorine atom, and (iii) said urethane compound having 6 to 36 urethane bonds per molecule. The present invention provides a process for the production of the above leather-like sheet material, a modified urethane compound satisfying the above requirements (i) to (iii) for use in the process, and a process for the production of the modified urethane compound. According to the present invention, the leather-like sheet material is excellent in water repellency from a cut cross section and water resistance.

  一种仿皮革片状材料，包括由纤维集合体和弹性聚合物组成的片状材料，片状材料含有一种含氟侧链改性聚氨酯化合物，该化合物满足以下要求(i)至(iii)、 (i) 所述聚氨酯化合物含有分子量为 500 至 5000 的含氨基甲酸乙酯键化合物和分子量为 200 至 1000 的含氟侧链，其中 3 至 12 条含氟侧链与含氨基甲酸乙酯键化合物键合、 (ii) 所述聚氨酯化合物中氟原子的含量为 20%至 60%（按重量计），以及 (iii) 所述氨基甲酸乙酯化合物每个分子具有 6 至 36 个氨基甲酸乙酯键。 本发明提供了一种生产上述仿皮革片状材料的工艺、一种满足上述要求(i)至(iii)的用于该工艺的改性聚氨酯化合物，以及一种生产该改性聚氨酯化合物的工艺。 根据本发明，仿皮片状材料从切割截面看具有优异的防水性和耐水性。
• Hoepken, Jens; Faulstich, Sabine; Moeller, Martin, Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 1992, vol. 210, p. 59 - 74
  作者：Hoepken, Jens、Faulstich, Sabine、Moeller, Martin

  DOI：——

  日期：——
• LEATHERY SHEET OBJECT AND PROCESS FOR PRODUCING THE SAME
  申请人：Teijin Cordley Limited

  公开号：EP1514968B1

  公开（公告）日：2008-12-17
• Leathery sheet object, process for producing the same, and urethane compound modified with flurinated side chain
  申请人：Mimura Masahisa

  公开号：US20050090169A1

  公开（公告）日：2005-04-28

  A leather-like sheet material comprising a sheet material composed of a fiber aggregate and a elastic polymer, the sheet material containing a fluorine-containing side-chain-modified urethane compound which satisfies the following requirements (i) to (iii), (i) said urethane compound containing a urethane-bond-containing compound having a molecular weight of 500 to 5,000 and fluorine-containing side chains having a molecular weight of 200 to 1,000 each, 3 to 12 such fluorine-containing side chains bonding to the urethane-bond-containing compound, (ii) said urethane compound having a fluorine content of 20 to 60 by weight as a fluorine atom, and (iii) said urethane compound having 6 to 36 urethane bonds per molecule. The present invention provides a process for the production of the above leather-like sheet material, a modified urethane compound satisfying the above requirements (i) to (iii) for use in the process, and a process for the production of the modified urethane compound. According to the present invention, the leather-like sheet material is excellent in water repellency from a cut cross section and water resistance.
• Liquid-Crystalline Kagome
  作者：Benjamin Glettner、Feng Liu、Xiangbing Zeng、Marko Prehm、Ute Baumeister、Martin Walker、Martin A. Bates、Peter Boesecke、Goran Ungar、Carsten Tschierske

  DOI：10.1002/anie.200802957

  日期：2008.11.10