3-vinyl-1-adamantanol | 122661-63-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-vinyl-1-adamantanol
• 英文别名: 3-ethenyladamantan-1-ol
• CAS: 122661-63-6
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: VDKUZYVXEDAYGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-Hydroxy-1-(3-hydroxy-1-adamantyl)-ethan 在 白碳黑 硫酸 、 对苯二酚 作用下， 以 甲苯 为溶剂， 生成 3-vinyl-1-adamantanol
  参考文献：
  名称：

  Methods of acylating adamantane, tricyclo[5.2.1.02,6], and decalin compounds

  摘要：

  本发明的酰化剂包括（A）1,2-二羰基化合物或其羟基还原剂，（B）氧气，以及（C）至少选择自（c1）金属化合物和（C2）N-羟基邻苯二甲酰亚胺或另一种亚胺化合物的化合物。作为1,2-二羰基化合物或其羟基还原剂（A），可以使用双醋酸、2,3-丁二醇等。作为金属化合物（c1），可以采用乙酸钴或另一种钴化合物。通过将金刚烷衍生物或另一种具有亚甲基碳原子的化合物与酰化剂反应，可以高效地在亚甲基碳原子上引入酰基。

  公开号：

  US06429314B1

文献信息

• ACYLATING AGENTS, ACYLATION METHOD WITH THE USE OF THE SAME AND ADAMANTANE DERIVATIVES
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP0990634A1

  公开（公告）日：2000-04-05

  An acylating agent of the invention includes (A) a 1,2-dicarbonyl compound or its hydroxy reductant, (B) oxygen, and (C) at least one compound selected from (c1) a metallic compound and (C2) N-hydroxyphthalimide or another imide compound. As the 1,2-dicarbonyl compound or its hydroxy reductant (A), biacetyl, 2,3-butanediol or the like can be used. As the metallic compound (c1), cobalt acetate, or another cobalt compound, for example, can be employed. By reacting an adamantane derivative or another compound having a methine carbon atom with the acylating agent, an acyl group can be introduced to the methine carbon atom with efficiency.

  本发明的酰化剂包括(A)1,2-二羰基化合物或其羟基还原剂，(B)氧和(C)至少一种选自(c1)金属化合物和(C2)N-羟基邻苯二甲酰亚胺或另一种酰亚胺化合物的化合物。作为 1,2-二羰基化合物或其羟基还原剂 (A)，可以使用生物乙酰基、2,3-丁二醇或类似物。作为金属化合物（c1），可以使用醋酸钴或其他钴化合物等。将金刚烷衍生物或其他具有甲烷碳原子的化合物与酰化剂反应，可以有效地将酰基引入甲烷碳原子。
• Film touch sensor and structure including the same
  申请人：DONGWOO FINE-CHEM CO., LTD.

  公开号：US11180585B2

  公开（公告）日：2021-11-23

  A film touch sensor is prepared by performing a process in which a separation layer made of a specific component is formed on a carrier substrate, and an insulation film is formed on a transparent conductive film pattern, which is used as a planarization layer, an adhesive layer or a base layer.

  薄膜式触摸传感器的制备过程是：在载体基板上形成由特定成分制成的分离层，并在透明导电薄膜图案上形成绝缘膜，该图案用作平面化层、粘合层或基底层。
• High molecular compound, monomer compounds and photosensitive composition for photoresist, pattern forming method utilizing photosensitive composition, and method of manufacturing electronic components
  申请人：Kabushiki Kaisha Toshiba

  公开号：US20030235781A1

  公开（公告）日：2003-12-25

  Disclosed is a polymer compound for photoresist characterized in that the polymer compound is formed of a polymer compound having at least one skeleton represented by the following general formula (1), general formula (2A), general formula (2B) or general formula (2C): 1 (wherein R is an alicyclic skeleton; at least one of R x1 s is an electron-withdrawing group, the residual R x1 s being the same or different and being individually a hydrogen atom or monovalent organic group; with the proviso that R may contain a heteroatom, and that R and R x1 may be combined to form a ring; at least one of R x1 s is an electron-withdrawing group, the residual R x1 s being the same or different and being individually a hydrogen atom or monovalent organic group; R 2 s may be the same or different and are individually a hydrogen atom or monovalent organic group; and n is an integer ranging from 2 to 25; with the proviso that at least two carbon atoms selected from carbon atoms constituting R 2 and carbon atoms to which the R 2 s are connected may be combined to form a condensed ring).

  本发明公开了一种用于光刻胶的聚合物化合物，其特征在于该聚合物化合物是由至少一个骨架由以下通式(1)、通式(2A)、通式(2B)或通式(2C)表示的聚合物化合物形成的： 1 (其中 R 为脂环族骨架；R x1 中至少有一个是取电子基团，残余 R x1 s 相同或不同，且各自为氢原子或单价有机基团；但 R 可含有一个杂原子，且 R 和 R x1 可组合成一个环；R x1 中至少有一个是抽电子基团，残余的 R x1 s 相同或不同，且各自为氢原子或单价有机基团；R 2 s 可以相同或不同，且各自为氢原子或一价有机基团；n 为 2 至 25 之间的整数；但至少有两个碳原子选自构成 R 2 2 的碳原子和 R 2 s 连接的碳原子中选出的至少两个碳原子可结合形成一个缩合环）。
• Method for Inhibition of Potential-Dependent Cation Channel
  申请人：Takatoku Hiroko

  公开号：US20130045177A1

  公开（公告）日：2013-02-21

  An excellent potential-dependent cation channel inhibitor or an excellent masking agent is provided. Disclosed is a method for inhibiting a potential-dependent cation channel or a method for masking olfaction, both of which include administering an adamantane derivate represented by the following formula (1) or a salt thereof [wherein R′ and R 2 are identical with or different from each other, and each represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; and X represents —OH, —R 3 —OH (wherein R 3 represents an alkylene group having 1 to 6 carbon atoms), —NH 2 , —R 4 —NH 2 (wherein R 4 represents an alkylene group having 1 to 6 carbon atoms), —COOH, —R 5 —COOH (wherein R 5 represents an alkylene group having 1 to 6 carbon atoms), —CO-R 6 (wherein R 6 represents an alkyl group having 1 to 6 carbon atoms), —CO—R 7 —COO—R 8 (wherein R 7 represents an alkylene group having 1 to 6 carbon atoms, and R 8 represents an alkyl group having 1 to 6 carbon atoms), or —NHCO—R 9 (wherein R 9 represents an alkyl group having 1 to 6 carbon atoms)].
• FILM TOUCH SENSOR AND STRUCTURE INCLUDING THE SAME
  申请人：DONGWOO FINE-CHEM CO., LTD.

  公开号：US20210277156A1

  公开（公告）日：2021-09-09

  A film touch sensor is prepared by performing a process in which a separation layer made of a specific component is formed on a carrier substrate, and an insulation film is formed on a transparent conductive film pattern, which is used as a planarization layer, an adhesive layer or a base layer.