1-<3,3-dimethylallyl)oxy>-2-propanol | 54605-37-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-<3,3-dimethylallyl)oxy>-2-propanol
• 英文别名: 3-(3'-Methylbut-2'-en-1'-oxy)-propan-2-ol；2-Hydroxy-propyl-3-methylbut-2-enylether；1-(3-methyl-but-2-enyloxy)-propan-2-ol；1-(3-Methylbut-2-enoxy)propan-2-ol
• CAS: 54605-37-7
• 化学式: C₈H₁₆O₂
• 分子量: 144.214
• InChiKey: FADJPUADLYMXMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-<3,3-dimethylallyl)oxy>-2-propanol 在 sodium dichromate 、 硫酸 作用下， 生成 1-(3-methyl-but-2-enyloxy)-propan-2-one
  参考文献：
  名称：

  乙炔基烯丙基醚的[2,3]适溶反应，一种制备某些2-羟基酮的新方法

  摘要：

  描述了新的[2] [3]σ重排，可将丙酮基烯丙基醚转化为3-羟基-5-烯-2-酮。

  DOI：

  10.1002/hlca.19740570721
• 作为产物：
  描述：

  异戊烯醇 、 methyloxirane 在 sodium 作用下， 生成 1-<3,3-dimethylallyl)oxy>-2-propanol
  参考文献：
  名称：

  乙炔基烯丙基醚的[2,3]适溶反应，一种制备某些2-羟基酮的新方法

  摘要：

  描述了新的[2] [3]σ重排，可将丙酮基烯丙基醚转化为3-羟基-5-烯-2-酮。

  DOI：

  10.1002/hlca.19740570721

文献信息

• PROCESS FOR PRODUCTION OF WATER&minus;SOLUBLE &lpar;METH&rpar;ACRYLIC POLYMERS, WATER&minus;SOLUBLE &lpar;METH&rpar;ACRYLIC POLYMERS, AND USE THEREOF
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1454928A1

  公开（公告）日：2004-09-08

  The present invention is a method of producing a (meth)acrylic acid based water-soluble polymer having a content of groups in neutralized state of not more than 90 mole percent, where the sum total of acid groups and groups in neutralized state contained in the (meth)acrylic acid based water-soluble polymer is taken as 100 mole percent, which comprises a photopolymerization step of polymerizing a monomer component by irradiating near-ultraviolet rays to a reaction mixture, the said reaction mixture comprising the monomer component, a photopolymerization initiator, a chain transfer agent and a polymerization solvent, the said monomer component containing not less than 50 mole percent of a (meth)acrylic acid monomer, with the whole monomer component subjected to polymerization being taken as 100 mole percent, and a concentration of the said monomer component in the reaction mixture at the time of polymerization being 40 to 97% by mass.

  本发明是一种生产(甲基)丙烯酸基水溶性聚合物的方法，该聚合物的中和基团含量不超过90摩尔％，其中(甲基)丙烯酸基水溶性聚合物所含酸性基团和中和基团的总和为100摩尔％，该方法包括光聚合步骤，即通过向反应混合物照射近紫外线使单体组分聚合、所述反应混合物包括单体组分、光聚合引发剂、链转移剂和聚合溶剂，所述单体组分中含有不少于 50 摩尔%的（甲基）丙烯酸单体，整个单体组分的聚合度为 100 摩尔%，聚合时所述单体组分在反应混合物中的浓度为 40% 至 97%（质量百分比）。
• KACHINSKY J. L. C.; SALOMON R. G., J. ORG. CHEM., 51,(1986) N 9, 1393-1401
  作者：KACHINSKY J. L. C.、 SALOMON R. G.

  DOI：——

  日期：——
• PROCESS FOR PRODUCTION OF WATER-SOLUBLE (METH)ACRYLIC POLYMERS, WATER-SOLUBLE (METH)ACRYLIC POLYMERS, AND USE THEREOF
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1454928B1

  公开（公告）日：2007-02-28
• Process for production of water-soluble (meth)acrylic polymers, water-soluble (meth) acrylic polymers, and use thereof
  申请人：——

  公开号：US20040110861A1

  公开（公告）日：2004-06-10

  The present invention is a method of producing a (meth)acrylic acid based water-soluble polymer having a content of groups in neutralized state of not more than 90 mole percent, where the sum total of acid groups and groups in neutralized state contained in the (meth)acrylic acid based water-soluble polymer is taken as 100 mole percent, which comprises a photopolymerization step of polymerizing a monomer component by irradiating near-ultraviolet rays to a reaction mixture, the said reaction mixture comprising the monomer component, a photopolymerization initiator, a chain transfer agent and a polymerization solvent, the said monomer component containing not less than 50 mole percent of a (meth)acrylic acid monomer, with the whole monomer component subjected to polymerization being taken as 100 mole percent, and a concentration of the said monomer component in the reaction mixture at the time of polymerization being 40 to 97% by mass.
• US4150000A
  申请人：——

  公开号：US4150000A

  公开（公告）日：1979-04-17