3-ethenylcyclopropene | 61082-23-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 3-ethenylcyclopropene
• 英文别名: 3-Vinylcyclopropene；3-Vinylcyclopropen；Cyclopropene, 3-ethenyl-
• CAS: 61082-23-3
• 化学式: C₅H₆
• 分子量: 66.1026
• InChiKey: AFVXHPBHWSOYEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  5
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-ethenylcyclopropene 生成 环戊二烯
  参考文献：
  名称：

  Synthesis of alkenyl- and alkynylcyclopropenes

  摘要：

  Fluoride anion promoted dehalosilation of 2-(chlorocyclopropyl)trimethylsilanes in the gas-phase was used to prepare a variety of monosubstituted cyclopropenes containing additional unsaturations. The cyclopropylsilanes were constructed easily from common intermediates.

  DOI：

  10.1016/0040-4039(95)00634-o
• 作为产物：
  描述：

  ((1S,3S)-2-Chloro-3-vinyl-cyclopropyl)-trimethyl-silane 在 四丁基氟化铵 作用下， 25.0 ℃ 、4.0 Pa 条件下， 生成 3-ethenylcyclopropene
  参考文献：
  名称：

  Synthesis of alkenyl- and alkynylcyclopropenes

  摘要：

  Fluoride anion promoted dehalosilation of 2-(chlorocyclopropyl)trimethylsilanes in the gas-phase was used to prepare a variety of monosubstituted cyclopropenes containing additional unsaturations. The cyclopropylsilanes were constructed easily from common intermediates.

  DOI：

  10.1016/0040-4039(95)00634-o

文献信息

• X-ray Crystal Structure of 3-Vinylcyclopropene. Gas Phase Synthesis of Simple Cyclopropenes
  作者：Roland Boese、Dieter Blaeser、W. E. Billups、Michael M. Haley、Weimei Luo、Benny E. Arney

  DOI：10.1021/jo00105a032

  日期：1994.12

  The vacuum gas-phase elimination of beta-halocyclopropylsilanes over solid fluoride has been used to synthesize cyclopropenes for structural characterization by X-ray crystallography.