(Cyclohex-2-ene-1,1-diyl)dimethanol | 212377-81-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (Cyclohex-2-ene-1,1-diyl)dimethanol
• 英文别名: [1-(hydroxymethyl)cyclohex-2-en-1-yl]methanol
• CAS: 212377-81-6
• 化学式: C₈H₁₄O₂
• 分子量: 142.2
• InChiKey: QBRPPCVQOLMIJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (Cyclohex-2-ene-1,1-diyl)dimethanol 、 甲苯 、 原碳酸四乙酯 在 对甲苯磺酸 、 乙醇 、 三乙胺 、 magnesium sulfate 、 crude material 、 silica gel 、 ether hexanes 、 ethyl ether hexanes 、 8,10,19,20-tetraoxatrispiro[5.2.2.5.2.2]henicosa-2,14-diene 作用下， 以 乙醇 、 水 为溶剂， 反应 20.58h， 以The desired product 8,10,19,20-tetraoxatrispiro[5.2.2.5.2.2]henicosa-2,14-diene 2 (DCH) was obtained as white crystals in 80% yield的产率得到8,10,19,20-tetraoxatrispiro[5.2.2.5.2.2]henicosa-2,14-diene
  参考文献：
  名称：

  Photopolymerizable vinyl ether based monomeric formulations and polymerizable compositions which may include certain novel spiroorthocarbonates

  摘要：

  提供了光聚合组成物，其为乙烯醚、含有碘离子盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组成物还可以包括环氧化合物、多元醇、螺环正噻碳酸酯。本发明的一种实施例是由乙烯醚、螺环正噻碳酸酯和光引发剂体系组成的可聚合组成物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇和光引发剂体系组成的可聚合组成物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇、螺环正噻碳酸酯和光引发剂体系组成的可聚合组成物。此外，本发明的另一种实施例是某些新型螺环正噻碳酸酯化合物。这些新型螺环正噻碳酸酯化合物中至少包括一个环氧基团作为取代基。

  公开号：

  US06458865B2

文献信息

• Curable composition
  申请人：CIBA-GEIGY AG

  公开号：EP0462060A2

  公开（公告）日：1991-12-18

  A heat-curable composition comprising: a) an epoxide resin; and b) as curing agent, at least one aromatic amine derivative having the formula I: in which A is an n-valent aromatic residue and n is a number ranging from 2 to 400, and A is connected to a moiety CO-O- via aromatic carbon atoms. Most of the compounds of formula I are new.

  一种热固性组合物，包括：a）环氧树脂；和b）作为固化剂，至少一种具有公式I的芳香胺衍生物：其中A是n价芳香残基，n是2至400之间的数字，并且A通过芳香碳原子连接到一个CO-O-基团。公式I的大多数化合物是新的。
• PHOTOPOLYMERIZABLE VINYL ETHER BASED MONOMERIC FORMULATIONS AND POLYMERIZABLE COMPOSITIONS WHICH MAY INCLUDE CERTAIN NOVEL SPIROORTHOCARBONATES
  申请人：——

  公开号：US20020013380A1

  公开（公告）日：2002-01-31

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光聚合组合物，其为乙烯醚、包括碘化物盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组合物还可以包括环氧化合物、多元醇、螺环正交碳酸酯。本发明的一种实施例是由乙烯醚、螺环正交碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇、螺环正交碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施例是某些新型螺环正交碳酸酯化合物。这些新型螺环正交碳酸酯化合物中，每个化合物都包括至少一个环氧基团作为取代基。
• Novel spiroorthocarbonates
  申请人：The Curators of the University of Missouri

  公开号：US20030119931A1

  公开（公告）日：2003-06-26

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光固化组合物，它们是乙烯醚、包含碘鎓盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组合物还可以包括环氧化物、多元醇、螺内酯碳酸酯。本发明的一种实施方式是由乙烯醚、螺内酯碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施方式是由乙烯醚、环氧化物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施方式是由乙烯醚、环氧化物、多元醇、螺内酯碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施方式是一些新型螺内酯碳酸酯化合物。这些新型螺内酯碳酸酯化合物中的每一种都包括至少一个环氧基团作为取代基。
• Photopolymerizable vinyl ether based monomeric formulations and polymerizable compositions which may include certain novel spiroorthocarbonates
  申请人：Curators of the University of Missouri

  公开号：US06458865B2

  公开（公告）日：2002-10-01

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光聚合组成物，其为乙烯醚、含有碘离子盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组成物还可以包括环氧化合物、多元醇、螺环正噻碳酸酯。本发明的一种实施例是由乙烯醚、螺环正噻碳酸酯和光引发剂体系组成的可聚合组成物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇和光引发剂体系组成的可聚合组成物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇、螺环正噻碳酸酯和光引发剂体系组成的可聚合组成物。此外，本发明的另一种实施例是某些新型螺环正噻碳酸酯化合物。这些新型螺环正噻碳酸酯化合物中至少包括一个环氧基团作为取代基。
• ADVANCED POLY EPOXY ESTER RESIN COMPOSITIONS
  申请人：Jin Xin

  公开号：US20130178591A1

  公开（公告）日：2013-07-11

  A poly epoxy ester resin composition of the following chemical structure: where n is a number from 2 to about 3000; each m independently has a value of 0 or 1; each R 0 is independently —H or —CH 3 ; each R 1 is independently —H or a C 1 to C 6 alkylene radical (saturated divalent aliphatic hydrocarbon radical), Ar is a divalent aryl group or heteroarylene group;_and X is cycloalkylene group, including substituted cycloalkylene group, where the substitute group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substitute group, for example, a halogen, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.

  以下是化学结构式为的聚合物环氧酯树脂组成：其中n为2至约3000的数字；每个m独立地具有值为0或1；每个R0独立地为—H或—CH3；每个R1独立地为—H或C1到C6的烷基基团（饱和二价脂肪族碳氢基团），Ar为二价芳基基团或杂芳基基团；X为环烷基团，包括取代环烷基团，其中取代基团包括烷基、环烷基、芳基或芳基烷基团或其他取代基团，例如卤素、硝基、阻塞异氰酸酯或烷氧基团；环烷基和烷基团的组合以及烷基和环烷基团之间带有桥接基团。