6-硫基-2-己酮 | 408340-08-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 6-硫基-2-己酮
• 英文名称: 6-mercaptohexan-2-one
• 英文别名: 6-Sulfanylhexan-2-one
• CAS: 408340-08-9
• 化学式: C₆H₁₂OS
• 分子量: 132.227
• InChiKey: QGQSMYRKYYEGHB-UHFFFAOYSA-N

物化性质

• 沸点：
  226.6±23.0 °C(Predicted)
• 密度：
  0.952±0.06 g/cm3(Predicted)
• 保留指数：
  1014

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  18.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6-硫基-2-己酮 在 oxone||potassium monopersulfate triple salt 、 2,4,5,6-四(9H-咔唑-9-基)异酞腈 、 碘 、 lithium bromide 作用下， 以 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 反应 27.0h， 生成 2-methyl-2-(4-(phenethylthio)butyl)-2,3-dihydroquinazolin-4(1H)-one
  参考文献：
  名称：

  光氧化还原催化下无张力酮前体构建 C−S 和 C−Se 键

  摘要：

  已经开发出一种使用无张力甲基酮作为自由基前体的温和光催化脱酰策略来构建硫化物、二硫化物、硒化物、亚砜和砜。将此脱酰过程与 S N 2 或偶联反应相结合，为不对称或对称二硫化物提供了新颖且方便的模块化方法。

  DOI：

  10.1002/anie.202314790

文献信息

• PARTICLES CONTAINING PERFUME HAVING IMPROVED FRAGRANCE PROPERTIES
  申请人：Artiga Gonzalez Rene-Andres

  公开号：US20080207476A1

  公开（公告）日：2008-08-28

  A particle containing a carbonate, a sulfate, a perfume, and a layered silicate, the particle having a weight ratio of layered silicate to carbonate and sulfate combined of ≦1:2. The particles, having a desirable fragrance profile, are useful in detergents, fabric softeners, and textile treatments.
• CONSUMER PRODUCTS HAVING VARYING ODORS
  申请人：MEINE Georg

  公开号：US20080207481A1

  公开（公告）日：2008-08-28

  Conventional perfumed consumer products are characterized by a uniform odor throughout the entire product. Consumer products are described that comprise at least two differently smelling perfume oils which are not evenly distributed in the product in proportion to one another. This allows the consumer to produce, using one and the same product, a variety of odors during applications and overcome the monotony of the olfactory experience associated with conventional perfumed consumer products.
• CONSUMER PRODUCTS HAVING VARYING ODOR PATTERNS
  申请人：MEINE Georg

  公开号：US20080221003A1

  公开（公告）日：2008-09-11

  Consumer products having fragrance that can develop distinguishable odor patterns which are separately detectable. Scent dynamics allow the consumer with one and the same product to experience different scent experiences during a single application. The limited range and monotony of odor associated with the conventional perfumed consumer products is thereby completely broken.
• Liquid Support
  申请人：Artiga-Gonzalez Rene-Andres

  公开号：US20100022437A1

  公开（公告）日：2010-01-28

  Agglomerating carrier materials in the presence of a granulation liquid with a carbohydrate content and subsequent incorporation of a liquid, such as a perfume oil, yields fluid-containing particles that, even at an elevated liquid loading, exhibit very good powder properties and reliably retain the incorporated liquid even in aggressive solid matrices. These fluid-containing particles may be used, for example, for fragrancing purposes.
• Textile Scenting
  申请人：Striepling Gert-Lothar

  公开号：US20100047198A1

  公开（公告）日：2010-02-25

  A perfume-containing PIT emulsion which is suited to contribute to an excellent and long-lasting scenting of textiles during the use of a dryer. The PIT emulsion is simple for the user to handle and allows the user to better control the user's individual scent experience during the handling of textiles. The PIT emulsions can also be used for aroma therapy purposes and for the scenting of rooms. In addition, a kit made of detergents and the perfume-containing PIT emulsion, which enables the user to obtain optimal laundry scenting results.