6-bromo-12-methylindolo[1,2-f]phenanthridine | 1176869-95-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 6-bromo-12-methylindolo[1,2-f]phenanthridine
• 英文别名: 10-Bromo-18-methyl-14-azapentacyclo[12.7.0.02,7.08,13.015,20]henicosa-1(21),2,4,6,8(13),9,11,15(20),16,18-decaene；10-bromo-18-methyl-14-azapentacyclo[12.7.0.02,7.08,13.015,20]henicosa-1(21),2,4,6,8(13),9,11,15(20),16,18-decaene
• CAS: 1176869-95-6
• 化学式: C₂₁H₁₄BrN
• 分子量: 360.253
• InChiKey: BRBGYLCDBZTZTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  4.4
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trimethyl(5-(5,5-dimethyl-1,3-dioxan-2-yl)-thiophen-2-yl)stannane 、 6-bromo-12-methylindolo[1,2-f]phenanthridine 在 四(三苯基膦)钯 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以81%的产率得到6-(5-(5,5-dimethyl-1,3-dioxan-2-yl)thiophen-2-yl)-12-methylindolo[1,2-f]phenanthridine
  参考文献：
  名称：

  Synthesis and photovoltaic properties of novel organic sensitizers containing indolo[1,2-f]phenanthridine for solar cell

  摘要：

  Organic dyes containing indolo[1,2-f]phenanthridine unit are a promising new class of sensitizers for dye-sensitized solar cells, as a result of their broad and intense visible absorptions. Under standard global AM 1.5 solar condition, the JK-61 sensitized cell gave a short circuit photocurrent density (J(sc)) of 15.81 mA cm(-2), an open circuit voltage (V-oc) of 0.73 V, a fill factor of 0.72, corresponding to an overall conversion efficiency of 8.34%. (C) 2009 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2009.04.077
• 作为产物：
  描述：

  12-methylindolo[1,2-f]phenanthridine 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 为溶剂， 以84%的产率得到6-bromo-12-methylindolo[1,2-f]phenanthridine
  参考文献：
  名称：

  Synthesis and photovoltaic properties of novel organic sensitizers containing indolo[1,2-f]phenanthridine for solar cell

  摘要：

  Organic dyes containing indolo[1,2-f]phenanthridine unit are a promising new class of sensitizers for dye-sensitized solar cells, as a result of their broad and intense visible absorptions. Under standard global AM 1.5 solar condition, the JK-61 sensitized cell gave a short circuit photocurrent density (J(sc)) of 15.81 mA cm(-2), an open circuit voltage (V-oc) of 0.73 V, a fill factor of 0.72, corresponding to an overall conversion efficiency of 8.34%. (C) 2009 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2009.04.077

文献信息

• Synthesis and photovoltaic properties of novel organic sensitizers containing indolo[1,2-f]phenanthridine for solar cell
  作者：Chul Baik、Duckhyun Kim、Moon-Sung Kang、Kihyung Song、Sang Ook Kang、Jaejung Ko

  DOI：10.1016/j.tet.2009.04.077

  日期：2009.7

  Organic dyes containing indolo[1,2-f]phenanthridine unit are a promising new class of sensitizers for dye-sensitized solar cells, as a result of their broad and intense visible absorptions. Under standard global AM 1.5 solar condition, the JK-61 sensitized cell gave a short circuit photocurrent density (J(sc)) of 15.81 mA cm(-2), an open circuit voltage (V-oc) of 0.73 V, a fill factor of 0.72, corresponding to an overall conversion efficiency of 8.34%. (C) 2009 Published by Elsevier Ltd.