(1E),(3E)-1,4-di(p-nitrophenyl)-1,3-tetrafluorobutadiene | 66286-65-5

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: (1E),(3E)-1,4-di(p-nitrophenyl)-1,3-tetrafluorobutadiene
• 英文别名: trans,trans-1,4-Bis-(p-nitrophenyl)-1,3-perfluorbutadien；trans,trans-1,4-Bis-(4-nitrophenyl)-1,3-perfluor-butadien；1-nitro-4-[(1E,3E)-1,2,3,4-tetrafluoro-4-(4-nitrophenyl)buta-1,3-dienyl]benzene
• CAS: 66286-65-5
• 化学式: C₁₆H₈F₄N₂O₄
• 分子量: 368.244
• InChiKey: UJVGCXVGONCIJK-WXUKJITCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  91.6
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  (Z)-p-nitro-β-iodo-α,β-difluorostyrene 在 铜 作用下， 生成 (1E),(3E)-1,4-di(p-nitrophenyl)-1,3-tetrafluorobutadiene
  参考文献：
  名称：

  Sevast'yan,A.P. et al., Journal of Organic Chemistry USSR (English Translation), 1978, vol. 14, p. 191 - 192

  摘要：

  DOI：

文献信息

• Sevast'yan,A.P. et al., Journal of Organic Chemistry USSR (English Translation), 1978, vol. 14, p. 191 - 192
  作者：Sevast'yan,A.P. et al.

  DOI：——

  日期：——
• Coupling routes to hexafluoro-1,3-butadiene, substituted-1,3-fluorine-containing butadienes and fluorinated polyenes
  作者：Donald J. Burton、Steven W. Hansen、Peter A. Morken、Kathryn J. MacNeil、Charles R. Davis、Ling Xue

  DOI：10.1016/j.jfluchem.2007.11.004

  日期：2008.5

  Hexafluoro-1,3-butadiene was readily prepared via a variety of self-coupling processes, such as Cu(0) mediated self-coupling of iodotrifluoroethene, Pd(0) catalyzed coupling of iodotrifluoroethene with the trifluorovinylzinc reagent, and CuBr(2) mediated coupling of the trifluorovinylzinc reagent. Perfluoro-2,3-dimethyl-1,3-butadiene was readily synthesized by the reaction of pentafluoropropenyl-2-zinc reagent with either CuBr(2) or FeCl(3). Alternatively, perfluoro-2,3-dimethyl-1,3-butadiene was prepared by oxidation of the pentafluoropropenyl-2-copper reagent with dioxygen. Cu(0) mediated coupling of an (E)-substituted alpha,beta-difluoro-beta-iodostyrene provided the first useful route to a (Z)(Z)-1,4-diaryl-1,3-tetrafluorobutadiene. Extension of the Cu(0) mediated coupling methodology to a perfluorodienyl iodide demonstrated a useful stereospecific route to perfluoropolyenes. (c) 2007 Elsevier B.V. All rights reserved.
• Fialkov,Yu.A. et al., Journal of Organic Chemistry USSR (English Translation), 1978, vol. 14, p. 939 - 946
  作者：Fialkov,Yu.A. et al.

  DOI：——

  日期：——