9-(5-(diphenylphosphoryl)pyridin-2-yl)-9H-carbazole | 1257083-16-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(5-(diphenylphosphoryl)pyridin-2-yl)-9H-carbazole
• 英文别名: 9-(5-Diphenylphosphorylpyridin-2-yl)carbazole；9-(5-diphenylphosphorylpyridin-2-yl)carbazole
• CAS: 1257083-16-1
• 化学式: C₂₉H₂₁N₂OP
• 分子量: 444.472
• InChiKey: VAWSUVNWDJPBES-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.9
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,5-二溴吡啶 在 copper(l) iodide 、 trans-1,2-cyclohexyldiamine 、 双氧水 、 异丙基氯化镁 、 caesium carbonate 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 二氯甲烷 、 水 为溶剂， 反应 5.0h， 生成 9-(5-(diphenylphosphoryl)pyridin-2-yl)-9H-carbazole
  参考文献：
  名称：

  Synthesis and Application of Pyridine-Based Ambipolar Hosts: Control of Charge Balance in Organic Light-Emitting Devices by Chemical Structure Modification

  摘要：

  We studied the influence of a pyridine moiety versus a phenyl moiety when introduced in the molecular design of an ambipolar host These pyridine-based host materials for organic light-emitting diodes (OLEDs) were synthesized in three to five steps from commercially available starting materials. The isomeric hosts have similar HOMO/LUMO energies; however, data from OLEDs fabricated using the above host materials demonstrate that small structural modification of the host results in significant changes in its carrier-transporting characteristics.

  DOI：

  10.1021/ol102444j

文献信息

• CN115490729
  申请人：——

  公开号：——

  公开（公告）日：——
• Synthesis and Application of Pyridine-Based Ambipolar Hosts: Control of Charge Balance in Organic Light-Emitting Devices by Chemical Structure Modification
  作者：Phillip K. Koech、Evgueni Polikarpov、James E. Rainbolt、Lelia Cosimbescu、James S. Swensen、Amber L. Von Ruden、Asanga B. Padmaperuma

  DOI：10.1021/ol102444j

  日期：2010.12.3

  We studied the influence of a pyridine moiety versus a phenyl moiety when introduced in the molecular design of an ambipolar host These pyridine-based host materials for organic light-emitting diodes (OLEDs) were synthesized in three to five steps from commercially available starting materials. The isomeric hosts have similar HOMO/LUMO energies; however, data from OLEDs fabricated using the above host materials demonstrate that small structural modification of the host results in significant changes in its carrier-transporting characteristics.