2,2,3,3-四甲基-9-十四烷基-1,4,8,11-四氧杂环十四烷 | 151460-00-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2,2,3,3-四甲基-9-十四烷基-1,4,8,11-四氧杂环十四烷
• 英文名称: 2,2,3,3-tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane
• CAS: 151460-00-3
• 化学式: C₂₈H₅₆O₄
• 分子量: 456.75
• InChiKey: AGCBIBHANSJWDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  32
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,2-十六烷二醇 在 sodium hydroxide 、 sodium tetrahydroborate 、 三氟化硼乙醚 、 双氧水 、 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 122.5h， 生成 2,2,3,3-四甲基-9-十四烷基-1,4,8,11-四氧杂环十四烷
  参考文献：
  名称：

  Design and synthesis of highly selective ionophores for lithium ion based on 14-crown-4 derivatives for an ion-selective electrode

  摘要：

  Highly Li+-selective ionophores based on 14-crown-4 derivatives were designed and synthesized, and the relationship of their molecular structures and ion selectivities was investigated in order to obtain a highly Li+-selective electrode. The ion selectivities were examined with 11 kinds of 14-crown-4 derivatives, which were prepared according to the proposed two types of Li+ ionophore models. Excellent Li+-selective ionophores were obtained by introducing a bulky ''block'' subunit into the ethano-bridge section of the base crown ring, which effectively prevents the formation of a 2:1 or 3:1 sandwich-type complex consisting of the crown ether and cations larger than Li+. The best Li+/Na+ selectivity (more than 1000) was obtained for the electrode using the 14-crown-4 derivative with a bulky decalin subunit. These results offer the general ion selectivity features of 14-crown-4-based compounds.

  DOI：

  10.1021/ac00071a012

文献信息

• Method and apparatus for controlling concentration of water treatment chemicals
  申请人：——

  公开号：US20040262233A1

  公开（公告）日：2004-12-30

  A water-soluble lithium salt is added as a tracer substance along with a water treatment chemical to water to be treated. The concentration of lithium ions is electrochemically or optically measured using a lithium ion sensitive substance, so as to perform concentration control of the water treatment chemical added to water to be treated. An ion selective electrode, ion selective field effect transistor, or ion optode may be employed to perform the electrochemical or optical measurement using a lithium ion sensitive substance.
• US5790627A
  申请人：——

  公开号：US5790627A

  公开（公告）日：1998-08-04
• US7105095B2
  申请人：——

  公开号：US7105095B2

  公开（公告）日：2006-09-12
• Design and synthesis of highly selective ionophores for lithium ion based on 14-crown-4 derivatives for an ion-selective electrode
  作者：Koji. Suzuki、Hiroyuki. Yamada、Kazunari. Sato、Kazuhiko. Watanabe、Hideaki. Hisamoto、Yoshito. Tobe、Kazuya. Kobiro

  DOI：10.1021/ac00071a012

  日期：1993.12.1

  Highly Li+-selective ionophores based on 14-crown-4 derivatives were designed and synthesized, and the relationship of their molecular structures and ion selectivities was investigated in order to obtain a highly Li+-selective electrode. The ion selectivities were examined with 11 kinds of 14-crown-4 derivatives, which were prepared according to the proposed two types of Li+ ionophore models. Excellent Li+-selective ionophores were obtained by introducing a bulky ''block'' subunit into the ethano-bridge section of the base crown ring, which effectively prevents the formation of a 2:1 or 3:1 sandwich-type complex consisting of the crown ether and cations larger than Li+. The best Li+/Na+ selectivity (more than 1000) was obtained for the electrode using the 14-crown-4 derivative with a bulky decalin subunit. These results offer the general ion selectivity features of 14-crown-4-based compounds.