1-[4-(1-hydroxycyclohexyl)butyl]cyclohexanol | 74347-26-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-[4-(1-hydroxycyclohexyl)butyl]cyclohexanol
• 英文别名: 1.4-Bis-(1-hydroxy-cyclohexyl)-butan；1,1'-butanediyl-bis-cyclohexanol；1,1'-Butandiyl-bis-cyclohexanol；1-[4-(1-Hydroxycyclohexyl)butyl]cyclohexan-1-ol
• CAS: 74347-26-5
• 化学式: C₁₆H₃₀O₂
• 分子量: 254.413
• InChiKey: SFXADMRCZOXURG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-[4-(1-hydroxycyclohexyl)butyl]cyclohexanol 在 碘 作用下， 生成 1.4-Bis--butan
  参考文献：
  名称：

  PREPARATION AND DEHYDRATION OF DI-(1-HYDROXYCYCLOALKYL)-ALKANES

  摘要：

  不可用

  DOI：

  10.1139/v61-142
• 作为产物：
  描述：

  1,4-双(1-羟基环己基)-1,3-丁二炔 在 乙醚 、 铂 作用下， 生成 1-[4-(1-hydroxycyclohexyl)butyl]cyclohexanol
  参考文献：
  名称：

  Salkind; Aisikowitsch, Zhurnal Obshchei Khimii, 1937, vol. 7, p. 227,232

  摘要：

  DOI：

文献信息

• Monomer compositions, polymer concrete compositions containing them and their use
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0047120A1

  公开（公告）日：1982-03-10

  Monomer compositions comprising dicyclopentenyloxyalkyl acrylate or methacrylate and hydroxyalkyl methacrylate are used in polymer concrete compositions which additionally comprise inert inorganic aggregate material and polymerization catalyst comprising peroxide and aromatic amine, optionally with polyvalent metal complex or salt or hydroperoxide and polyvalent metal complex or salt. The polymer concrete may be used to form or patch previously formed or laid concrete floors and road oavements.

  由丙烯酸二环戊烯基氧基烷基酯或甲基丙烯酸酯和甲基丙烯酸羟烷基酯组成的单体组合物可用于聚合物混凝土组合物中，聚合物混凝土组合物还包括惰性无机骨料和由过氧化物和芳香胺组成的聚合催化剂，可选择与多价金属络合物或盐或过氧化氢和多价金属络合物或盐一起使用。 聚合物混凝土可用来铺设或修补先前铺设或修补过的混凝土地面和人行道。
• Coating, sealing or impregnant compositions
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0157596A2

  公开（公告）日：1985-10-09

  This invention concerns coating/sealer or impregnant compositions for substrates, for example cementitious substrates the compositions comprising (a) one or more dicyclopentenyl or dicyclopentenyloxy(C1-C4)alkyl acrylate or methacrylate, and (b) one or more drying oil fatty acid in an amount of at least percent by weight of the total of (a) and (b). Porous, e.g. cementitious, surfaces treated with the compositions of the invention exhibit improved water and crack resistance.

  本发明涉及用于基材（例如水泥基材）的涂层/密封剂或浸渍剂组合物，该组合物包含(a)一种或多种双环戊烯基或双环戊烯氧基(C1-C4)烷基丙烯酸酯或甲基丙烯酸酯，以及(b)一种或多种干燥油脂肪酸，其用量至少为(a)和(b)总用量的重量百分比。用本发明的组合物处理过的多孔（如水泥基）表面具有更好的耐水性和抗裂性。
• Liquid resin-forming composition and two-package system for providing the composition
  申请人：RHONE-POULENC SPECIALTY CHEMICALS CO.

  公开号：EP0667361A2

  公开（公告）日：1995-08-16

  A liquid resin-forming composition contains a polyether-ene such as a polyallyl glycidyl ether, a free radical-polymerizable monomer such as an acrylate ester, a free radical initiator such as an organic peroxide and/or an organic hydroperoxide and a promoter such as an amine and/or polyvalent metal carboxylate. Certain properties of the composition, specifically, its volatiles content, flash point and viscosity, can be such as to make the composition particularly useful for application to a solid permeable substrate such as a concrete structure where, upon curing, the resulting resin will heal and/or seal pores and/or small cracks in the substrate preventing or lessening its penetration by liquids.

  液态树脂成型组合物含有聚醚烯（如聚烯丙基缩水甘油醚）、可自由基聚合的单体（如丙烯酸酯）、自由基引发剂（如有机过氧化物和/或有机过氧化氢）以及促进剂（如胺和/或多价金属羧酸盐）。该组合物的某些特性，特别是挥发物含量、闪点和粘度，可以使该组合物特别适用于固体可渗透基材，如混凝土结构，固化后产生的树脂将愈合和/或密封基材上的孔隙和/或小裂缝，防止或减少液体的渗透。
• PROCESS FOR PRODUCING EPOXY COMPOUND, EPOXY RESIN COMPOSITION AND USE THEREOF, ULTRAVIOLET-CURABLE CAN COATING COMPOSITION, AND PROCESS FOR PRODUCING COATED METAL CAN
  申请人：DAICEL CHEMICAL INDUSTRIES, Ltd.

  公开号：EP1389615A1

  公开（公告）日：2004-02-18

  The invention I provides a method of producing an alicyclic epoxy compound having a specific structure, which comprises epoxidizing an alicyclic olefin compound having a specific structure by using an aliphatic percarboxylic acid having low water content. The alicyclic epoxy compound is useful for use in coatings, inks, adhesives, sealants, encapsulants, stabilizers or the like. The invention II provides an epoxy resin composition containing the alicyclic epoxy compound as a main component, and a photosemiconductor device comprising a photosemiconductor element encapsulated with the epoxy resin composition. The epoxy resin composition can be cured by heating, thereby obtaining a cured product having excellent moisture and heat resistance and transparency. The invention III provides: an ultraviolet rays-curable can-coating composition containing the alicyclic epoxy compound as a main component, which can be cured by ultraviolet irradiation, and can form a coating film having excellent film performances such as processability, adhesion, hardness and scratch resistance, particularly film appearance and retort resistance; and a process of producing a coated metal can using the composition.

  本发明一提供了一种生产具有特定结构的脂环族环氧化合物的方法，该方法包括使用含水量低的脂肪族过羧酸对具有特定结构的脂环族烯烃化合物进行环氧化。脂环族环氧化合物可用于涂料、油墨、粘合剂、密封剂、封装剂、稳定剂等。 本发明二提供了一种含有脂环族环氧化合物作为主要成分的环氧树脂组合物，以及一种光电半导体器件，该器件包括用环氧树脂组合物封装的光电半导体元件。环氧树脂组合物可以通过加热固化，从而获得具有优异的耐湿性、耐热性和透明度的固化产品。 本发明III提供了：一种紫外线固化罐涂层组合物，该组合物以脂环族环氧化合物为主要成分，可通过紫外线照射固化，并可形成具有优异涂膜性能（如加工性、附着力、硬度和抗划伤性）的涂膜，特别是涂膜外观和耐蒸煮性；以及一种使用该组合物生产涂层金属罐的工艺。
• HIGH-PURITY ALICYCLIC EPOXY COMPOUND, PROCESS FOR PRODUCING THE SAME, CURABLE EPOXY RESIN COMPOSITION, CURED ARTICLE THEREOF, AND USE
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1726588A1

  公开（公告）日：2006-11-29

  The present invention provides a high-purity alicyclic epoxy compound in which an alicyclic olefin compound is epoxidized with an aliphatic percarboxylic acid having substantially no water followed by the removal of a solvent to produce an alicyclic epoxy compound represented by the general formula (I) that is in turn subjected to purification by distillation to thereby the high-purity alicyclic epoxy compound wherein the concentration of high-molecular-weight components having an elution time shorter than that of the alicyclic epoxy compound in detection by a GPC analysis is 5.5% or less in terms of the area ratio, the concentration of impurities having a retention time shorter than that of the alicyclic epoxy compound in detection by a GC analysis is 19.5% or less in terms of the area ratio, the concentration of reactive intermediates is 4.5% or less in terms of the area ratio, and a color hue (APHA) is 60 or less; a process of efficiently producing the same by the use of a low-toxicity solvent; a curable resin composition using the same; a cured product; and applications.

  本发明提供了一种高纯度脂环族环氧化合物，其中脂环族烯烃化合物与基本上不含水分的脂族过羧酸发生环氧化反应，然后除去溶剂，生成通式(I)代表的脂环族环氧化合物。 其中，在 GPC 分析中，洗脱时间短于脂环族环氧化合物洗脱时间的高分子量组分的浓度（以面积比计）为 5.5% 或以下；在 GC 分析中，保留时间短于脂环族环氧化合物保留时间的杂质的浓度（以面积比计）为 19.5%或更低，反应性中间体的浓度为 4.5%或更低，色调（APHA）为 60 或更低；通过使用低毒性溶剂高效生产上述物质的工艺；使用上述物质的可固化树脂组合物；固化产品；以及应用。