10-(4-methylpentyl)-9(10H)-acridone | 1313737-00-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 10-(4-methylpentyl)-9(10H)-acridone
• 英文别名: 10-(4-Methylpentyl)acridin-9-one；10-(4-methylpentyl)acridin-9-one
• CAS: 1313737-00-6
• 化学式: C₁₉H₂₁NO
• 分子量: 279.382
• InChiKey: DKDYRJHCCTWQIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  10-(4-methylpentyl)-9(10H)-acridone 在 盐酸 、 锌 、 硝酸 作用下， 以 乙醇 、 水 为溶剂， 反应 20.0h， 以68%的产率得到N,N'-bis(4-methylpentyl)-9,9'-biacridinium dinitrate
  参考文献：
  名称：

  “Supramolecular Circuitry”: Three Chemiluminescent, Cucurbit[7]uril-Controlled On/Off Switches

  摘要：

  Three Cucurbit[7]uril-controlled chemiluminescent on/off switches based on the lucigenin motif have been synthesized. Light emission Is triggered upon addition of sodium peroxide, interrupted or dimmed in the presence of Cucurbit[7]uril, and restored upon injection of a competitive guest. The process, which can be mimicked by a simple resistor-capacitor circuit, is rationalized by examining the role of the macrocyclic host on the network of equilibria involved in the chemiluminescent process.

  DOI：

  10.1021/ol201403m
• 作为产物：
  描述：

  N,N'-bis(4-methylpentyl)-9,9'-biacridinium dinitrate 在 sodium peroxide 作用下， 以 水 为溶剂， 反应 2.0h， 生成 10-(4-methylpentyl)-9(10H)-acridone
  参考文献：
  名称：

  “Supramolecular Circuitry”: Three Chemiluminescent, Cucurbit[7]uril-Controlled On/Off Switches

  摘要：

  Three Cucurbit[7]uril-controlled chemiluminescent on/off switches based on the lucigenin motif have been synthesized. Light emission Is triggered upon addition of sodium peroxide, interrupted or dimmed in the presence of Cucurbit[7]uril, and restored upon injection of a competitive guest. The process, which can be mimicked by a simple resistor-capacitor circuit, is rationalized by examining the role of the macrocyclic host on the network of equilibria involved in the chemiluminescent process.

  DOI：

  10.1021/ol201403m

文献信息

• “Supramolecular Circuitry”: Three Chemiluminescent, Cucurbit[7]uril-Controlled On/Off Switches
  作者：Eric Masson、Yasser M. Shaker、Jean-Pierre Masson、Martin E. Kordesch、Citra Yuwono

  DOI：10.1021/ol201403m

  日期：2011.8.5

  Three Cucurbit[7]uril-controlled chemiluminescent on/off switches based on the lucigenin motif have been synthesized. Light emission Is triggered upon addition of sodium peroxide, interrupted or dimmed in the presence of Cucurbit[7]uril, and restored upon injection of a competitive guest. The process, which can be mimicked by a simple resistor-capacitor circuit, is rationalized by examining the role of the macrocyclic host on the network of equilibria involved in the chemiluminescent process.