2,5,2',5'-tetraphenyl-4,4'-biimidazole | 1382490-21-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2,5,2',5'-tetraphenyl-4,4'-biimidazole
• 英文别名: 5-(2,4-diphenyl-1H-imidazol-5-yl)-2,4-diphenyl-1H-imidazole
• CAS: 1382490-21-2
• 化学式: C₃₀H₂₂N₄
• 分子量: 438.531
• InChiKey: MOWLOCCPXUJZAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  34
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  57.4
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-benzylidene-phenyl-(5-phenyl-isoxazol-3-yl)methanamine 在 potassium tert-butylate 、 ammonium acetate 作用下， 以 溶剂黄146 、 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 生成 2,5,2',5'-tetraphenyl-4,4'-biimidazole
  参考文献：
  名称：

  Synthesis of Tetrasubstituted 4,4′-Biimidazoles

  摘要：

  Highly substituted 4,4'-biimidazoles were synthesized, in good to excellent yields, through a multicomponent imidazole ring synthesis by using imidazol-4-yl-ethane-1,2-diones as starting materials. The obtained compounds were preliminarily tested as chromogenic and fluorescent sensors for heavy metals.

  DOI：

  10.1021/ol3013414

文献信息

• Synthesis of Tetrasubstituted 4,4′-Biimidazoles
  作者：Annamaria Martorana、Andrea Pace、Silvestre Buscemi、Antonio Palumbo Piccionello

  DOI：10.1021/ol3013414

  日期：2012.7.6

  Highly substituted 4,4'-biimidazoles were synthesized, in good to excellent yields, through a multicomponent imidazole ring synthesis by using imidazol-4-yl-ethane-1,2-diones as starting materials. The obtained compounds were preliminarily tested as chromogenic and fluorescent sensors for heavy metals.